Abstract:
A novel oligo-p-phenylene-unit-containing polymer containing at least one structural element of the general formula (AkB)n in which the symbols and indices have the following meanings: A is the same as or different from (a), B is the same as or different from (b), Y is the same as or different from (E)-CR9=CR10, -C C- or -CHR?11-CHR12; R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12¿ are mutually independently the same or different in the individual structural elements, H is a straight-chained or branched alkyl chain with 1 to 22 C atoms, in which one or more non-adjacent CH¿2? groups may also be substituted by -O-, -S-, -SO2-, -COOC-, -OOC- and/or phenylene, aryl or aryloxy groups, in which the aromatic in said groups may be substituted by C1-C22 alkyl, C1-C22 alkoxy, Br, Cl, F and/or CN, Br, Cl, F, CN or alkoxycarbonyl with 2 to 23 atoms, k is 1 to 25 and n is 1 to 200, is suitable for use as electroluminescent material.
Abstract:
Cyclo-olefin copolymers (COC) with a soln. viscosity ( eta ) of more than 0.25 dl/g (in decalin at 135 degrees C) (I) contain polymerised units of (A) cyclic olefin(s), (B) opt. acyclic olefin(s) and (C) units contg. functional units which are (a) derived from a cyclic olefin and contain hetero atom(s) attached directed to a ring atom, or (b) derived from a cyclic or acyclic olefin and contain gp(s), with two heteroatoms attached to the same C atom, or (c) derived from a cyclic or acyclic olefin and contain aldehyde gp(s)., or (d) derived from a cyclic or acyclic olefin and contain gp(s). with an N atom attached to C via a double bond. If the functional units (C) are derived from a cyclic olefin, exactly two adjacent C atoms of this gp. are built into the main polymer chain. Also claimed are (i) the prodn. of (I) by reacting a double bond-contg. COC (II) in inert solvent with ozone; (ii) coating materials contg. (I), opt. together with binders, paint additives, pigments and/of fillers; and (iii) adhesion promoters contg. (I).
Abstract:
A semipermeable membrane is described which comprises a homogeneously miscible polymer blend of an aromatic polyamide and polyvinylpyrrolidone. The aromatic polyamide is in particular formed of recurrent units of the formula I: (I) wherein E1 and E2 are identical or different and are selected from the groupings -AR1-, and -AR1-X-AR2, where AR1 and Ar2 are the same or different 1,2-phenylene, 1,3-phenylene or 1,4-phenylene groups which may be substituted by (C1-C6)-alkyl, (C1-C6)-alkoxy, -CF3 or halogen and X denotes a) a direct bond or one of the following divalent groups: -O-, -C(CF3)2-, -SO2-, -C(R1)2-, with R1 being hydrogen, (C1-C6)-alkyl or fluoroalkyl having from 1 to 4 carbon atoms in the alkyl group or -Z-AR1-Z-, where Z is one of the groups -O- and -C(CH3)2 or -O-Ar1-Y-Ar2-O-, where Y has the meaning given under Xa) above. The membrane has pronouned hydrophilic properties and is moreover stable to hydrolyzing agents and oxidants and to the action of heat. It is also resistant to organic solvents and microorganisms and exhibits low adsorption of proteins. A process for producing the membrane and a process for modifying the retention capacity thereof are also described. The membrane is produced by spreading a solution of the homogeneously miscible polymer blend on a planar substrate and precipitating the blend. Retention capacity is modified by heat treatment.
Abstract:
A semipermeable membrane is described which comprises a homogeneously miscible polymer blend of an aromatic polyamide and polyvinylpyrrolidone. The aromatic polyamide is in particular formed of recurrent units of the formula I: (I) wherein E1 and E2 are identical or different and are selected from the groupings -AR1-, and -AR1-X-AR2, where AR1 and Ar2 are the same or different 1,2-phenylene, 1,3-phenylene or 1,4-phenylene groups which may be substituted by (C1-C6)-alkyl, (C1-C6)-alkoxy, -CF3 or halogen and X denotes a) a direct bond or one of the following divalent groups: -O-, -C(CF3)2-, -SO2-, -C(R1)2-, with R1 being hydrogen, (C1-C6)-alkyl or fluoroalkyl having from 1 to 4 carbon atoms in the alkyl group or -Z-AR1-Z-, where Z is one of the groups -O- and -C(CH3)2 or -O-Ar1-Y-Ar2-O-, where Y has the meaning given under Xa) above. The membrane has pronouned hydrophilic properties and is moreover stable to hydrolyzing agents and oxidants and to the action of heat. It is also resistant to organic solvents and microorganisms and exhibits low adsorption of proteins. A process for producing the membrane and a process for modifying the retention capacity thereof are also described. The membrane is produced by spreading a solution of the homogeneously miscible polymer blend on a planar substrate and precipitating the blend. Retention capacity is modified by heat treatment.
Abstract:
A semipermeable membrane is described which comprises a homogeneously miscible polymer blend of an aromatic polyamide and polyvinylpyrrolidone. The aromatic polyamide is in particular formed of recurrent units of the formula I: (I) wherein E1 and E2 are identical or different and are selected from the groupings -AR1-, and -AR1-X-AR2, where AR1 and Ar2 are the same or different 1,2-phenylene, 1,3-phenylene or 1,4-phenylene groups which may be substituted by (C1-C6)-alkyl, (C1-C6)-alkoxy, -CF3 or halogen and X denotes a) a direct bond or one of the following divalent groups: -O-, -C(CF3)2-, -SO2-, -C(R1)2-, with R1 being hydrogen, (C1-C6)-alkyl or fluoroalkyl having from 1 to 4 carbon atoms in the alkyl group or -Z-AR1-Z-, where Z is one of the groups -O- and -C(CH3)2 or -O-Ar1-Y-Ar2-O-, where Y has the meaning given under Xa) above. The membrane has pronouned hydrophilic properties and is moreover stable to hydrolyzing agents and oxidants and to the action of heat. It is also resistant to organic solvents and microorganisms and exhibits low adsorption of proteins. A process for producing the membrane and a process for modifying the retention capacity thereof are also described. The membrane is produced by spreading a solution of the homogeneously miscible polymer blend on a planar substrate and precipitating the blend. Retention capacity is modified by heat treatment.
Abstract:
WO 92/09648 PCT/EP91/02112 of the disclosure: Thermoplastically processable aromatic polyether amide Thermoplastically processable aromatic polyether amide of the formula (I) (I) in which the symbols Ar, Ar', Ar1, Ar2, R, R', Y, x, y and z have the following meanings: Ar is a divalent, substituted or unsubstituted, aromatic or heteroaromatic radical or a group -Ar*-Q-Ar*-in which Q is a bond or an -O-, -C(CH3)2, -CO-, -S-, -SO- or -SO2-bridge and Ar* is an aromatic radical. The carbonyl groups of the Ar radical are on non-adjacent ring carbon atoms. A is up to three different radicals. Ar' has the meaning given for Ar or is an Ar-Z-Ar group. In this case, Z is a -C(CH3)2- or -O-Ar*-O-bridge. Y is a -C(CH3)2-, -SO2-, -S- or a -C(CF3)2-bridge and has up to two different meanings in the same polymer. Ar1 and Ar2 are identical or different from one another and are each a substituted or unsubstituted para- or meta-arylene radical. The sum of the mole fractions x, y and z is one. The sum of x and z may not be equal to y and x can assume the value zero. In a preferred embodiment, z is greater than x.
Abstract:
The separation of organometallic compounds and/or metal carbonyls from their solutions in organic media is effected according to the invention with the aid of semipermeable membranes of an aromatic polyamide.