公开(公告)号：CA2032372C

公开(公告)日：1997-09-23

申请号：CA2032372

申请日：1990-12-14

Applicant: HOECHST AG

Inventor： FELL BERNHARD ,  BAHRMANN HELMUT ,  PAPADOGIANAKIS GEORGIOS

IPC: B01J31/02 ,  B01J31/28 ,  C07B61/00 ,  C07C45/50 ,  C07C47/02

Abstract: The invention relates to the preparation of aldehydes by hydroformylation of olefinically unsaturated compounds. The reaction is carried out in the presence of a catalyst system which contains rhodium and an ammonium salt, which is soluble in organic media, of a sulfonated phosphorous acid triester.

公开(公告)号：PL311251A1

公开(公告)日：1996-05-13

申请号：PL31125195

申请日：1995-11-06

Applicant: HOECHST AG

Inventor： BAHRMANN HELMUT ,  LAPPE PETER ,  FELL BERNHARD ,  LECKEL DIETER ,  SCHOBBEN CHRISTIAN

IPC: B01J31/24 ,  C07B61/00 ,  C07C67/313 ,  C07C67/347 ,  C07C69/66 ,  C07C69/716

Abstract: A method for the prepn. of di- or polyformyl carboxylic acid esters - comprises the reaction of an ester of a polyunsatd. fatty acid and a low mol. wt. monoalcohol with carbon monoxide and hydrogen at 100 - 180 degrees C and 5 - 35 MPa, in the presence of an aq. soln. contg. rhodium phosphine complex catalysts and a solvent.

公开(公告)号：FI955328A0

公开(公告)日：1995-11-06

申请号：FI955328

申请日：1995-11-06

Applicant: HOECHST AG

Inventor： BAHRMANN HELMUT ,  LAPPE PETER ,  FELL BERNHARD ,  LECKEL DIETER ,  SCHOBBEN CHRISTIAN

IPC: B01J31/24 ,  C07B61/00 ,  C07C67/313 ,  C07C67/347 ,  C07C69/66 ,  C07C69/716 ,  C07C

Abstract: A method for the prepn. of di- or polyformyl carboxylic acid esters - comprises the reaction of an ester of a polyunsatd. fatty acid and a low mol. wt. monoalcohol with carbon monoxide and hydrogen at 100 - 180 degrees C and 5 - 35 MPa, in the presence of an aq. soln. contg. rhodium phosphine complex catalysts and a solvent.

公开(公告)号：CA2032371C

公开(公告)日：1995-04-04

申请号：CA2032371

申请日：1990-12-14

Applicant: HOECHST AG

Inventor： BAHRMANN HELMUT ,  FELL BERNHARD ,  PAPADOGIANAKIS GEORGIS

IPC: C07B61/00 ,  C07C45/49 ,  C07C45/50 ,  C07F9/141 ,  C07F9/145 ,  C07F9/6574 ,  C08K5/51 ,  C10M137/02 ,  C10N30/10 ,  C10N70/00 ,  C07F9/547

Abstract: The invention relates to the preparation of phosphites which are stable to hydrolysis from organic phosphites or phosphorus-halogen compounds and an ammonium salt of a hydroxysulfonic acid which is insoluble in water and soluble in an organic solvent.

公开(公告)号：CA2131337A1

公开(公告)日：1995-03-10

申请号：CA2131337

申请日：1994-09-01

Applicant: HOECHST AG

Inventor： FELL BERNHARD ,  HERMANNS PETER

IPC: B01J31/24 ,  B01J23/42 ,  C07B61/00 ,  C07C27/20 ,  C07C29/141 ,  C07C29/16 ,  C07C29/17 ,  C07C31/125 ,  C07C45/49 ,  C07C45/50 ,  C07C47/02 ,  C07C47/12 ,  C07C47/21 ,  C07C49/203 ,  C07C31/135

Abstract: of the disclosure 1,3-Butadiene is hydroformylated at 60 to 150.degree.C and 1 to 20 MPa in the presence of an aqueous solution which contains, as catalyst, at least one water-soluble rhodium compound and at least one water-soluble organic phosphine. A pH of 8 to 11 is maintained in the aqueous catalyst solution to increase the selectivity of the reaction with respect to the formation of n-C5 aldehydes and secondary products of the n-C5 aldehydes.

公开(公告)号：PL315833A1

公开(公告)日：1997-03-03

申请号：PL31583396

申请日：1996-08-26

Applicant: HOECHST AG

Inventor： BAHRMANN HELMUT ,  LAPPE PETER ,  FELL BERNHARD ,  XIA M SC ZHIGAO ,  KANAGASABAPATHY SUBBA

IPC: B01J31/28 ,  B01J31/20 ,  B01J31/24 ,  B01J31/40 ,  B01J35/12 ,  B01J38/00 ,  C07B61/00 ,  C07C45/50 ,  C07C47/02 ,  C07C67/313 ,  C07C67/347 ,  C07C69/73

Abstract: The characteristic features in the hydroformylation of olefinically unsatd. cpds. to give prods. non- (or only slightly)-soluble in water are that (i) the olefinic cpd. is in homogeneous phase in a polar organic solvent in presence of a catalyst system comprising (a) an Rh carbonyl cpd. and (b) a solvent- and also water-soluble salt of a sulphonated or carboxylated organic mono- or poly-phosphine; (ii) reaction is at 60-180 degrees C/2-35 MPa with CO and H2; and (iii) prod. recovery is by distilling off the organic solvent and separating off the catalyst system from the distn. residue using water.

公开(公告)号：CA2184053A1

公开(公告)日：1997-03-03

申请号：CA2184053

申请日：1996-08-23

Applicant: HOECHST AG

Inventor： BAHRMANN HELMUT ,  LAPPE PETER ,  WIEBUS ERNST ,  FELL BERNHARD ,  HERMANNS PETER

IPC: B01J31/02 ,  B01J31/04 ,  B01J31/24 ,  C07B61/00 ,  C07C45/49 ,  C07C45/50 ,  C07C47/21

Abstract: The characteristic features in the prepn. of pentenals are that: (i) 1,3-butadiene is dissolved in an inert medium; and then (ii) hydroformylation is effected at 100-180 degrees C/5-35 MPa in presence of an aq. soln. contg. an Rh/phosphine complex (opt. together with further phosphine) as catalyst.

公开(公告)号：CA2184048A1

公开(公告)日：1997-03-03

申请号：CA2184048

申请日：1996-08-23

Applicant: HOECHST AG

Inventor： BAHRMANN HELMUT ,  LAPPE PETER ,  FELL BERNHARD ,  XIA ZHIGAO ,  KANAGASABAPATHY SUBBA

IPC: B01J31/28 ,  B01J31/20 ,  B01J31/24 ,  B01J31/40 ,  B01J35/12 ,  B01J38/00 ,  C07B61/00 ,  C07C45/50 ,  C07C47/02 ,  C07C67/313 ,  C07C67/347 ,  C07C69/73 ,  C07C47/28 ,  C07C67/38 ,  C07C69/716 ,  C07C69/738

Abstract: The characteristic features in the hydroformylation of olefinically unsatd. cpds. to give prods. non- (or only slightly)-soluble in water are that (i) the olefinic cpd. is in homogeneous phase in a polar organic solvent in presence of a catalyst system comprising (a) an Rh carbonyl cpd. and (b) a solvent- and also water-soluble salt of a sulphonated or carboxylated organic mono- or poly-phosphine; (ii) reaction is at 60-180 degrees C/2-35 MPa with CO and H2; and (iii) prod. recovery is by distilling off the organic solvent and separating off the catalyst system from the distn. residue using water.

公开(公告)号：AU671763B2

公开(公告)日：1996-09-05

申请号：AU7166094

申请日：1994-09-05

Applicant: HOECHST AG

Inventor： FELL BERNHARD ,  HERMANNS PETER

IPC: B01J31/24 ,  B01J23/42 ,  C07B61/00 ,  C07C27/20 ,  C07C29/141 ,  C07C29/16 ,  C07C29/17 ,  C07C31/125 ,  C07C45/49 ,  C07C45/50 ,  C07C47/02 ,  C07C47/12 ,  C07C47/21 ,  C07C49/203 ,  C07C45/73 ,  C07C45/72 ,  C07C47/30

Abstract: 1,3-Butadiene is hydroformylated at 60 to 150 DEG C and 1 to 20 MPa in the presence of an aqueous solution which comprises at least one water-soluble rhodium compound and at least one water-soluble organic phosphine, this solution acting as the catalyst. To increase the selectivity of the reaction with regard to the formation of n-C5-aldehydes and subsequent products of the n-C5-aldehydes, a pH of 8 to 11 is maintained in the aqueous catalyst solution.

公开(公告)号：ZA959323B

公开(公告)日：1996-05-29

申请号：ZA959323

申请日：1995-11-03

Applicant: HOECHST AG

Inventor： BAHRMANN HELMUT ,  LAPPE PETER ,  FELL BERNHARD ,  LECKEL DIETER ,  SCHOBBEN CHRISTIAN

IPC: B01J31/24 ,  C07B61/00 ,  C07C67/313 ,  C07C67/347 ,  C07C69/66 ,  C07C69/716 ,  C07C ,  B01J

Abstract: A method for the prepn. of di- or polyformyl carboxylic acid esters - comprises the reaction of an ester of a polyunsatd. fatty acid and a low mol. wt. monoalcohol with carbon monoxide and hydrogen at 100 - 180 degrees C and 5 - 35 MPa, in the presence of an aq. soln. contg. rhodium phosphine complex catalysts and a solvent.