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    PRODUCTION OF DECYL ALCOHOL ISOMER MIXTURE
    1.
    发明专利
    PRODUCTION OF DECYL ALCOHOL ISOMER MIXTURE 失效

    公开(公告)号：JPH11222450A

    公开(公告)日：1999-08-17

    申请号：JP32797798

    申请日：1998-11-18

    Applicant: HOECHST AG

    Inventor： BAHRMANN HELMUT DR ,  GREB WOLFGANG ,  HEYMANNS PETER ,  LAPPE PETER ,  SZAMEITAT JUERGEN ,  MUELLER THOMAS DR ,  WIEBUS ERNST

    IPC: B01J31/24 ,  C07B61/00 ,  C07C27/22 ,  C07C29/141 ,  C07C29/17 ,  C07C31/125 ,  C07C45/50 ,  C07C45/74 ,  C07C47/21 ,  C07C67/08 ,  C07C69/80

    Abstract: PROBLEM TO BE SOLVED: To provide a hydroformylation method for producing a decyl alcohol isomer mixture in which the hydroformylation of butadiene to provide an aldehyde mixture, the separation of the obtained aldehyde mixture from the reaction product, the condensation of the aldehyde mixture and the separation of an aldol mixture, during the formation of the aldol mixture, and the hydrogenation of the aldol mixture to provide a decyl alcohol isomer mixture are included, and by which the butadiene can be industrially readily converted to a desired alcohol. SOLUTION: Butadiene is subjected to hydroformylation in the presence of water and water-soluble rhodium-, alkyl- or aryl-diphosphine-complex as a catalyst at 70-150 deg.C under 0.4-30 MPa pressure. The volume ratio of the aqueous phase to the organic phase is (0.1-100):1, the rhodium concentration in the aqueous catalytic solution is 20-2,000 ppm, and the phosphine of 4-100 mol per mol rhodium is used.

    3.
    发明专利
    未知

    公开(公告)号：BR9703064A

    公开(公告)日：1998-11-10

    申请号：BR9703064

    申请日：1997-05-06

    Applicant: HOECHST AG

    Inventor： LAPPE PETER ,  MUELLER THOMAS ,  BAHRMANN HELMUT

    IPC: C07C45/50 ,  C07F9/50

    Abstract: Ammonium diphosphine-carboxylates, -sulphonates or -phosphonates of formula (I) are new (where, R1 = COO , SO3 , PO3 or 2-aminoethane bisphosphonate Ä-NH-CH2-CH(PO3 )2Ü group; R2 = linear alkylene with 1-8 carbon (C) atoms, 2-6 C alkylene containing oxygen, 3-10 C cycloalkylene or a group of formulae(II), (III), (IV) or (V); at least one of a, b, c, d, e, f, g, h, k, l = 1, otherwise 0; x = 0 or 1; R3, R4 = 4-26 C alkyl, optionally substituted 6-10 C aryl or 6-10 C cycloalkyl or benzyl and R3 may also = H).

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