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公开(公告)号:GR71206B
公开(公告)日:1983-04-11
申请号:GR800163172
申请日:1980-10-17
Applicant: HOECHST AG
Inventor: FISCHER HANNES , PLUM HELMUT
IPC: C08F2/00 , C08F2/02 , C08F20/00 , C08F20/26 , C08F20/32 , C08F220/00 , C08F220/04 , C08F220/06 , C08F220/10 , C08F220/28 , C08F220/32 , C08G18/62 , C09D175/04
Abstract: A process for the preparation of copolymers containing hydroxyl groups by radical reaction of (A) 10 to 30% by weight of at least one glycidyl ester containing 12 to 14 carbon atoms, of an aliphatic saturated monocarboxylic acid with a tertiary or quaternary alpha -carbon atom; and (B) 90 to 70% by weight of at least two unsaturated copolymerisable monomers, at least one of which contains at least one carboxyl group, wherein component (A) is introduced first to a reaction zone and is then reacted at a temperature of at least 140 DEG C. with component (B) and a radical initiator, the component (B) containing a monomer having carboxyl groups, wherein for the preparation of low-viscosity copolymers component (A) is reacted at 140 to 200 DEG C. by substance polymerisation until a degree of reaction of at least 95% is achieved, the component (B) containing at least 3.3% by weight of the monomer having carboxyl groups, and an article coated with a product of said process.
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公开(公告)号:CA1177198A
公开(公告)日:1984-10-30
申请号:CA362662
申请日:1980-10-17
Applicant: HOECHST AG
Inventor: FISCHER HANNES , PLUM HELMUT
IPC: C08F2/00 , C08F2/02 , C08F20/00 , C08F20/26 , C08F20/32 , C08F220/00 , C08F220/04 , C08F220/06 , C08F220/10 , C08F220/28 , C08F220/32 , C08G18/62 , C09D175/04 , C08G65/00 , B32B15/08 , B32B17/10 , C08G18/28
Abstract: A process for the preparation of copolymers containing hydroxyl groups by radical reaction of A) 10 to 30 % by weight of at least one glycidyl ester containing 12 to 14 carbon atoms, of an aliphatic saturated monocarboxylic acid with a tertiary or quaternary .alpha.-carbon atom; and B) 90 to 70 % by weight of at least two unsaturated copolymerisable monomers, at least one of which contains at least one carboxyl group, wherein component A) is introduced first to a reaction zone and is then reacted at a temperature of at least 140.degree.C with component B) and a radical initiator, the component B) containing a monomer having carboxyl groups, wherein for the preparation of low-viscosity copolymers component A) is reacted at 140 to 200.degree.C by substance polymerisation until a degree of re-action of a least 95 % is achieved, the component B) containing at least 3.3 % by weight of the monomer having carboxyl groups, and an article coated with a product of said process.
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公开(公告)号:CA1172798A
公开(公告)日:1984-08-14
申请号:CA361525
申请日:1980-10-03
Applicant: HOECHST AG
Inventor: FISCHER HANNES , ZIMMERMANN ROLF
IPC: C09J133/04 , C08F220/12 , C09J133/06 , C09J3/14 , C09J5/06
Abstract: : A hot melt adhesive having a good thermal stability under load, based on a copolymer of a predominant proportion of acrylates or methacrylates, a minor proportion of acrylic or methacrylic acid amides and further based on acrylic or methacrylic acid compounds, characterised in that the copolymer comprises a) 85 to 95% by weight of alkyl acrylates and/or methacrylates with 1 to 12 carbon atoms in the alkyl radical, b) 3 to 10% by weight of acrylamide and/or methacryl amide, c) 0.2 to 5 % by weight of one or more olefinically unsaturated mono- or dicarboxylic acids with up to 5 carbon atoms, the sum of components a) to c) amounting to 100%, at a and a process for preparing a multi-layer article, containing said adhesives.
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公开(公告)号:CA1174790A
公开(公告)日:1984-09-18
申请号:CA384398
申请日:1981-08-21
Applicant: HOECHST AG
Inventor: RITZ JUERGEN , FISCHER HANNES , PLUM HELMUT
IPC: C08F20/00 , C08F20/26 , C08F222/10 , C08L75/00 , C09D133/14 , C09D167/07 , C09J133/04 , C08G63/42 , C08G18/42
Abstract: : Process for the manufacture of hardenable copolymers by the polymerisation of unsaturated esters with unsaturated polymerisable monomers containing no free COOH groups, wherein an olefinically unsaturated diester containing OH groups is used as the unsaturated ester, said diester being obtained by reacting olefinically unsaturated dicarboxylic acids or the anhydrides thereof with a polyhydric alcohol and a monoepoxide compound in one or more steps, characterised in that the copolymerisation of the diesters with monomers which contain no free COOH groups is carried out in the presence of copolymerisable monomers containing free COOH groups, and the use of the copolymers as hardenable binders for lacquers and/or coating compositions.
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公开(公告)号:AU535337B2
公开(公告)日:1984-03-15
申请号:AU6349980
申请日:1980-10-17
Applicant: HOECHST AG
Inventor: FISCHER HANNES , PLUM HELMUT
IPC: C08F2/00 , C08F2/02 , C08F20/00 , C08F20/26 , C08F20/32 , C08F220/00 , C08F220/04 , C08F220/06 , C08F220/10 , C08F220/28 , C08F220/32 , C08G18/62 , C09D175/04 , C08F212/08 , C08F220/18 , C08F220/26 , C08G18/02
Abstract: A process for the preparation of copolymers containing hydroxyl groups by radical reaction of (A) 10 to 30% by weight of at least one glycidyl ester containing 12 to 14 carbon atoms, of an aliphatic saturated monocarboxylic acid with a tertiary or quaternary alpha -carbon atom; and (B) 90 to 70% by weight of at least two unsaturated copolymerisable monomers, at least one of which contains at least one carboxyl group, wherein component (A) is introduced first to a reaction zone and is then reacted at a temperature of at least 140 DEG C. with component (B) and a radical initiator, the component (B) containing a monomer having carboxyl groups, wherein for the preparation of low-viscosity copolymers component (A) is reacted at 140 to 200 DEG C. by substance polymerisation until a degree of reaction of at least 95% is achieved, the component (B) containing at least 3.3% by weight of the monomer having carboxyl groups, and an article coated with a product of said process.
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公开(公告)号:AU534756B2
公开(公告)日:1984-02-16
申请号:AU6293580
申请日:1980-10-03
Applicant: HOECHST AG
Inventor: FISCHER HANNES , ZIMMERMANN ROLF
IPC: C09J133/04 , C08F220/12 , C09J133/06 , C08F220/18 , C09J3/14
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