Abstract:
THE IMPACT STRENGTH OF THERMOPLASTIC POLYACETALS IS IMPROVED BY ADMIXING SMALL AMOUNTS OF POLYMERS WHICH HAVE A SOFTENING TEMPERATURE BELOW THE CRYSTALLITE MELTING POINT OF THE POLYACETAL AND A SECOND ORDER TRANSITION TEMPERATURE WITHIN THE RANGE OF FROM -120* TO +30*C. AND WHICH ARE PRESENT IN THE MIXTURE IN THE FORM OF PARTICLES OF DIAMETERS WITHIN THE RANGE OF FROM 0.1 TO 5 MICRONS. THE POLYACETALS SO MODIFIED ARE SUITABLE FOR THE MANUFACTURE OF FINISHED OR SEMI-FINISHED PRODUCTS.
Abstract:
A catalyst for the polymerization of 1-olefins is prepared by reacting a chromate ester fixed on a carrier selected from the group consisting of oxides of silicon, oxides of aluminum, and mixtures of said oxides, in the absence of an unsaturated polymerizable hydrocarbon, with an aluminum-organic compound and subsequently activating with aluminum-organic compound. No washing liquids that have to be worked up are obtained and the polymers, obtained in a high yield have a broad molecular weight distribution and contain only a small proportion of high molecular constituents. The films made therefrom are practically free from specks.
Abstract:
A catalyst for the polymerization of 1-olefins is prepared by successively applying a chromate ester and a titanium ester to a carrier containing silicon dioxide, in the absence of an unsaturated polymerizable hydrocarbon, and activating with an aluminum-organic compound. In the manufacture of the catalyst no washing liquids are obtained from which metal compounds would have to be separated. In the presence of hydrogen the catalyst gives a high yield of polymers with broad molecular weight distribution and a small content of high molecular constituents. The films made therefrom are practically free from specks.
Abstract:
A catalyst for the polymerization of 1-olefins is prepared by successively applying a chromate ester and a titanium ester to a carrier containing silicon dioxide, in the absence of an unsaturated polymerizable hydrocarbon, and activating with an aluminum-organic compound. In the manufacture of the catalyst no washing liquids are obtained from which metal compounds would have to be separated. In the presence of hydrogen the catalyst gives a high yield of polymers with broad molecular weight distribution and a small content of high molecular constituents. The films made therefrom are practically free from specks.
Abstract:
A catalyst for the polymerization of 1-olefins is prepared by reacting a chromate ester fixed on a carrier selected from the group consisting of oxides of silicon, oxides of aluminum, and mixtures of said oxides, in the absence of an unsaturated polymerizable hydrocarbon, with an aluminum-organic compound and subsequently activating with aluminum-organic compound. No washing liquids that have to be worked up are obtained and the polymers, obtained in a high yield have a broad molecular weight distribution and contain only a small proportion of high molecular constituents. The films made therefrom are practically free from specks.