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1.发明授权Alpha-hydroxyacrylic acid/acrylic acid-copolymers and a process for making them 失效α-羟基丙烯酸/丙烯酸共聚物及其制备方法
公开(公告)号：US3890291A
公开(公告)日：1975-06-17
申请号：US47227774
申请日：1974-05-22
Applicant: HOECHST AG
Inventor： VOGT WILHELM , AUER EBERHARD , LENZ GUNTER , MERKENICH KARL , HENNING KLAUS
IPC: C08F8/00 , B01J45/00 , C08F8/12 , C08F8/26 , C08F20/00 , C08F20/02 , C08F220/00 , C08F220/04 , C08F220/06 , C08F15/14
CPC classification number: C08F8/12 , C08F8/26 , C08F220/04 , C08F220/06
Abstract: Copolymers made from Alpha -hydroxyacrylic acid and acrylic acid. The copolymers contain between 9 and 85 mol percent of acrylic acid and have a specific viscosity within the range 0.05 to 1.0, determined on a 1 weight percent solution of the copolymers in aqueous 2N-sodium hydroxide solution, at 20*C.
Abstract translation: 由α-羟基丙烯酸和丙烯酸制成的共聚物。 共聚物含有9至85摩尔％的丙烯酸，其比粘度在0.05至1.0的范围内，在共聚物在2N-氢氧化钠水溶液中的1重量％溶液在20℃下测定。
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公开(公告)号：US3892674A
公开(公告)日：1975-07-01
申请号：US29104372
申请日：1972-09-21
Applicant: HOECHST AG
Inventor： KANDLER JOACHIM , MERKENICH KARL , HENNING KLAUS , VOGT WILHELM , AUER EBERHARD , GLASER HERMANN
CPC classification number: C11D3/2093
Abstract: Water-soluble salts of acid carboxylic acid esters of bivalent aliphatic or olefinically unsaturated carboxylic acids or hydroxycarboxylic acids and at least trihydric aliphatic alcohols are used as builders for detergent and cleansing agents. Each hydroxylic group of the alcohol or optionally of the carboxylic acid has a carboxylic acid-molecule attached thereto.
Abstract translation: 使用二价脂族或烯属不饱和羧酸或羟基羧酸和至少三元脂肪醇的酸性羧酸酯的水溶性盐作为洗涤剂和清洁剂的助洗剂。 醇或任选的羧酸的每个羟基具有与其连接的羧酸分子。
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3.发明授权Detergent composition containing, as a builder, the sodium salt of glycerol tricitrate 失效洗涤剂组合物，作为建筑物，甘油三醇的盐
公开(公告)号：US3859224A
公开(公告)日：1975-01-07
申请号：US29104472
申请日：1972-09-21
Applicant: HOECHST AG
Inventor： KANDLER JOACHIM , MERKENICH KARL , HENNING KLAUS , VOGT WILHELM , AUER EBERHARD , GLASER HERMANN
CPC classification number: C11D3/2093
Abstract: Water-soluble salts of acid carboxylic acid esters of at least trivalent aliphatic or olefinically unsaturated carboxylic acids or hydroxycarboxylic acids and at least trihydric aliphatic alcohols are used as builders for detergent and cleansing agents. Each hydroxylic group of the alcohol and optionally of the carboxylic acid has a carboxylic acid-molecule attached thereto.
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公开(公告)号：DK148039C
公开(公告)日：1985-07-08
申请号：DK330476
申请日：1976-07-22
Applicant: HOECHST AG
Inventor： HENNING KLAUS , KANDLER JOACHIM
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公开(公告)号：DK146781B
公开(公告)日：1984-01-02
申请号：DK451776
申请日：1976-10-07
Applicant: HOECHST AG
Inventor： HENNING KLAUS , KANDLER JOACHIM
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Patent Agency Ranking
公开(公告)号：FI55215B
公开(公告)日：1979-02-28
申请号：FI239972
申请日：1972-08-31
Applicant: HOECHST AG
Inventor： KANDLER JOACHIM , MERKENICH KARL , HENNING KLAUS , VOGT WILHELM , AUER EBERHARD , GLASER HERMANN
Abstract: Water-soluble salts of acid carboxylic acid esters of bivalent aliphatic or olefinically unsaturated carboxylic acids or hydroxycarboxylic acids and at least trihydric aliphatic alcohols are used as builders for detergent and cleansing agents. Each hydroxylic group of the alcohol or optionally of the carboxylic acid has a carboxylic acid-molecule attached thereto.
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公开(公告)号：NO139226B
公开(公告)日：1978-10-16
申请号：NO334872
申请日：1972-09-19
Applicant: HOECHST AG
Inventor： KANDLER JOACHIM , MERKENICH KARL , HENNING KLAUS , VOGT WILHELM , AUER EBERHARD , GLASER HERMANN
Abstract: Water-soluble salts of acid carboxylic acid esters of bivalent aliphatic or olefinically unsaturated carboxylic acids or hydroxycarboxylic acids and at least trihydric aliphatic alcohols are used as builders for detergent and cleansing agents. Each hydroxylic group of the alcohol or optionally of the carboxylic acid has a carboxylic acid-molecule attached thereto.
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公开(公告)号：NO139225B
公开(公告)日：1978-10-16
申请号：NO332672
申请日：1972-09-18
Applicant: HOECHST AG
Inventor： KANDLER JOACHIM , MERKENICH KARL , HENNING KLAUS , VOGT WILHELM , AUER EBERHARD , GLASER HERMANN
Abstract: 1397957 Detergents containing builders HOECHST AG 14 Sept 1972 [24 Sept 1971] 42706/72 Heading C5D [Also in Division C2] Builders for detergent and cleansing agents comprise water-soluble salts of acid carboxylic acid esters prepared by reacting at least trivalent, 6-10C, aliphatic olefinically unsaturated carboxylic acids or hydroxy-carboxylic acids with aliphatic alcohols (3-6 OH groups), and in which each hydroxylic group of the alcohol and optionally the hydroxycarboxylic acid is esterified with a carboxylic acid molecule. Citric, aconitic, tricarballylic, dihydroxy-tricarballylic, nitrotriacetic and ethylenediamine-tetracetic acids may be used with glycerol, erythritol, pentaerythritol, mannitol, sorbitol or sugar alcohol (4-6 C) and the salts are of alkali metal or ammonium ion. A proportion of 10-80% by weight of salts may be used and then ion-active and/or non-ionic tensides and further conventional additives may be present. Examples describe the use of builders prepared from glycerol, sorbitol or pentaerythritol with nitric acid used with dodecylbenzene sulphonate, tallow fatty alcohol and hardened tallow soap, and also with additional magnesium silicate, sodium silicate, sodium perborate, sodium sulphate and tylose in detergent wash liquors.
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公开(公告)号：FI53834C
公开(公告)日：1978-08-10
申请号：FI239872
申请日：1972-08-31
Applicant: HOECHST AG
Inventor： KANDLER JOACHIM , MERKENICH KARL , HENNING KLAUS , VOGT WILHELM , AUER EBERHARD , GLASER HERMANN
Abstract: 1397957 Detergents containing builders HOECHST AG 14 Sept 1972 [24 Sept 1971] 42706/72 Heading C5D [Also in Division C2] Builders for detergent and cleansing agents comprise water-soluble salts of acid carboxylic acid esters prepared by reacting at least trivalent, 6-10C, aliphatic olefinically unsaturated carboxylic acids or hydroxy-carboxylic acids with aliphatic alcohols (3-6 OH groups), and in which each hydroxylic group of the alcohol and optionally the hydroxycarboxylic acid is esterified with a carboxylic acid molecule. Citric, aconitic, tricarballylic, dihydroxy-tricarballylic, nitrotriacetic and ethylenediamine-tetracetic acids may be used with glycerol, erythritol, pentaerythritol, mannitol, sorbitol or sugar alcohol (4-6 C) and the salts are of alkali metal or ammonium ion. A proportion of 10-80% by weight of salts may be used and then ion-active and/or non-ionic tensides and further conventional additives may be present. Examples describe the use of builders prepared from glycerol, sorbitol or pentaerythritol with nitric acid used with dodecylbenzene sulphonate, tallow fatty alcohol and hardened tallow soap, and also with additional magnesium silicate, sodium silicate, sodium perborate, sodium sulphate and tylose in detergent wash liquors.
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公开(公告)号：FI53834B
公开(公告)日：1978-05-02
申请号：FI239872
申请日：1972-08-31
Applicant: HOECHST AG
Inventor： KANDLER JOACHIM , MERKENICH KARL , HENNING KLAUS , VOGT WILHELM , AUER EBERHARD , GLASER HERMANN
Abstract: 1397957 Detergents containing builders HOECHST AG 14 Sept 1972 [24 Sept 1971] 42706/72 Heading C5D [Also in Division C2] Builders for detergent and cleansing agents comprise water-soluble salts of acid carboxylic acid esters prepared by reacting at least trivalent, 6-10C, aliphatic olefinically unsaturated carboxylic acids or hydroxy-carboxylic acids with aliphatic alcohols (3-6 OH groups), and in which each hydroxylic group of the alcohol and optionally the hydroxycarboxylic acid is esterified with a carboxylic acid molecule. Citric, aconitic, tricarballylic, dihydroxy-tricarballylic, nitrotriacetic and ethylenediamine-tetracetic acids may be used with glycerol, erythritol, pentaerythritol, mannitol, sorbitol or sugar alcohol (4-6 C) and the salts are of alkali metal or ammonium ion. A proportion of 10-80% by weight of salts may be used and then ion-active and/or non-ionic tensides and further conventional additives may be present. Examples describe the use of builders prepared from glycerol, sorbitol or pentaerythritol with nitric acid used with dodecylbenzene sulphonate, tallow fatty alcohol and hardened tallow soap, and also with additional magnesium silicate, sodium silicate, sodium perborate, sodium sulphate and tylose in detergent wash liquors.
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