PRODUCTION OF QUATERNARY PHOSPHONIUM HYDROXIDES

    公开(公告)号:CA1102824A

    公开(公告)日:1981-06-09

    申请号:CA307183

    申请日:1978-07-11

    Applicant: HOECHST AG

    Abstract: PRODUCTION OF QUATERNARY PHOSPHONIUM HYDROXIDES Quaternary phosphonium hydroxides of the general formula: (I) in which R stands either for hydrogen or an aliphatic or aromatic hydrocarbon having 1 to 12 carbon atoms and n stands for 1 or 2, are made by reacting a di- or trimethylphosphine in an aqueous medium with an epoxide of the general formula (II) in which R has the meaning given above, More specifically a pH-value of ?12 is established in the aqueous medium by means of a base and the starting materials are mixed in said medium.

    PRODUCTION OF ALKYL PHOSPHINES
    7.
    发明专利

    公开(公告)号:CA1071655A

    公开(公告)日:1980-02-12

    申请号:CA302736

    申请日:1978-05-05

    Applicant: HOECHST AG

    Abstract: PRODUCTION OF ALKYL PHOSPHINES Alkyl phosphines are made. To this end, phosphorus in vapor form is reacted with steam and an alkyl amine at elevated temperature in contact with a carbon catalyst placed in a reactor, the reactants being used individually or in admixture with one another.

    PRODUCTION OF METHYLPHOSPHINE OXIDES

    公开(公告)号:CA1041547A

    公开(公告)日:1978-10-31

    申请号:CA219248

    申请日:1975-02-03

    Applicant: HOECHST AG

    Abstract: PRODUCTION OF METHYLPHOSPHINE OXIDES Methylphosphine oxides of the general formula (I) (I) are produced from hydroxymethylphosphines of the general formula (II) (II) in which formulae R and R' each stand for identical or different alkyl-, cycloalkyl-, aralkyl- or aryl groups having from 1 to 18 carbon atoms, or carrying substituents being inert under the reaction conditions. The methylphosphine oxides are more particularly produced by subjecting the hydroxymethylphosphines to a rearrangement reaction with the aid of radical-yielding compounds.

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