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公开(公告)号:AU598231B2
公开(公告)日:1990-06-21
申请号:AU6872787
申请日:1987-02-12
Applicant: HOECHST AG
Inventor: WALZ GERD , HONEL MICHAEL , BRINDOPKE GERHARD , SPRENGER WALTER , FINKE MANFRED , LENZ RUDIGER
IPC: C07D317/36 , C07C67/00 , C07C239/00 , C07C269/00 , C07C271/20 , C07D303/28 , C08G18/06 , C08G18/32 , C08G18/64 , C08G18/70 , C08G18/80 , C08G18/83 , C08G59/02 , C08G59/40 , C08G71/04 , C09D5/44 , C09D175/04 , C09D175/12 , C08L75/12 , C08L75/04 , C07C87/14 , C07C91/12 , C09D3/72 , C07C101/24
Abstract: Amino-urethanes (I) claimed are of formula R3-N(Re)-A-R1-NH-C(O)-O-CH2-CH(OH)-CH2- R-CH2-CH(OH)-CH2-O-C(O)-NH- R1-A-N(R2)R3 R is residue of a diglycidyl ether or ester, or 2-18 alkylene gp.; R1 is opt. branched 2-18C alkylene; R2 is H, 1-8Calkyl, or 1-8C hydroxyalkyl; R3 is R2, or R3 with R2 can form cyclic ring, or, if R2 is H then R3 can be at least one gp. of formula (a) -C(O)-O-CH2-CH(R4)-CH2- (R-CH2-CH(R4)-CH2-OmB-(R4)n R4 is OH or -CONH-PI-NHCO R6; B is residue of a polyol; m is 1-3; n is 1-6; and PI is residue of a polyisocyanate and R6 is residue of (cylco)aliphatic, or alkylaromatic alcohol, an aminoalcohol, ketoxime, or a CH- or NH- acidic cpd.: b) R3 is gp. of formula (I) R5 is H or R4; R7 is 1-8Calkyl; and s is 1-6; c) -C(O)-NH-PI-NH-C(O)-O-B-d)R8-CHOH-CH2-O-CO-; e) R8-CHOH-CH2-; R8 is H, 1-18C alkyl, or residue of a glycidyl ester or ether; or f) PI'NHCO- PI' is residue of a partly capped polyisocyanate; and A 75 chemical bond or -R1NH)r-R1NH- r is 0-6. Prodn. of a (I) by heating an at least bifunctional 2-oxo-1,3-dioxolan (II) and a prim polyamine at 20-150 deg.C is claimed. Structural formulae are given for pref. R, viz. residues of a bisphenol diglycidyl ether opt. linked by residues of a diamine, diol, dicarboxylic acid, di-isocyanate, etc. Pref. (II) is bicyclic carbonate of specified formuls esp. derived from polyglycidyl ether of a polyphenol, or a epoxide-cyclic carbonate.
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公开(公告)号:CA2026454A1
公开(公告)日:1991-03-31
申请号:CA2026454
申请日:1990-09-28
Applicant: HOECHST AG
Inventor: HONEL MICHAEL , WALZ GERD , ZIEGLER PETER , KUBILLUS UWE
IPC: C09D7/12 , C08G59/50 , C08L63/00 , C08L101/00 , C09D5/02 , C09D5/44 , C09D163/00 , C09D201/00
Abstract: - ? - HOE 89/F 322 Use of crosslinked polymer microparticles in paints as filler substitute and/or as crosslinking filler The invention relates to the use of crosslinked polymer microparticles having an average particle size of at most 5 .mu.m and a glass transition temperature (Tg) of at least +30.degree.C in aqueous paint preparations as filler and/or as partial substitute of white pigments, in particular of titanium dioxide. Among other things, the corresponding paints show increased spreading power, less tendency for sedimentation and reduced crater formation.
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公开(公告)号:MX173127B
公开(公告)日:1994-02-02
申请号:MX522587
申请日:1987-02-13
Applicant: HOECHST AG
Inventor: SPRENGER WALTER , FINKE MANFRED , LENZ RUDIGER , WALZ GERD , HONEL MICHAEL , BRINDOPKE GERHARD
IPC: C07C67/00 , C07D317/36 , C07C239/00 , C07C269/00 , C07C271/20 , C07D303/28 , C08G18/06 , C08G18/32 , C08G18/64 , C08G18/70 , C08G18/80 , C08G18/83 , C08G59/02 , C08G59/40 , C08G71/04 , C09D5/44 , C09D175/04 , C09D175/12
Abstract: Amino-urethanes (I) claimed are of formula R3-N(Re)-A-R1-NH-C(O)-O-CH2-CH(OH)-CH2- R-CH2-CH(OH)-CH2-O-C(O)-NH- R1-A-N(R2)R3 R is residue of a diglycidyl ether or ester, or 2-18 alkylene gp.; R1 is opt. branched 2-18C alkylene; R2 is H, 1-8Calkyl, or 1-8C hydroxyalkyl; R3 is R2, or R3 with R2 can form cyclic ring, or, if R2 is H then R3 can be at least one gp. of formula (a) -C(O)-O-CH2-CH(R4)-CH2- (R-CH2-CH(R4)-CH2-OmB-(R4)n R4 is OH or -CONH-PI-NHCO R6; B is residue of a polyol; m is 1-3; n is 1-6; and PI is residue of a polyisocyanate and R6 is residue of (cylco)aliphatic, or alkylaromatic alcohol, an aminoalcohol, ketoxime, or a CH- or NH- acidic cpd.: b) R3 is gp. of formula (I) R5 is H or R4; R7 is 1-8Calkyl; and s is 1-6; c) -C(O)-NH-PI-NH-C(O)-O-B-d)R8-CHOH-CH2-O-CO-; e) R8-CHOH-CH2-; R8 is H, 1-18C alkyl, or residue of a glycidyl ester or ether; or f) PI'NHCO- PI' is residue of a partly capped polyisocyanate; and A 75 chemical bond or -R1NH)r-R1NH- r is 0-6. Prodn. of a (I) by heating an at least bifunctional 2-oxo-1,3-dioxolan (II) and a prim polyamine at 20-150 deg.C is claimed. Structural formulae are given for pref. R, viz. residues of a bisphenol diglycidyl ether opt. linked by residues of a diamine, diol, dicarboxylic acid, di-isocyanate, etc. Pref. (II) is bicyclic carbonate of specified formuls esp. derived from polyglycidyl ether of a polyphenol, or a epoxide-cyclic carbonate.
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公开(公告)号:ES2021286B3
公开(公告)日:1991-11-01
申请号:ES87101797
申请日:1987-02-10
Applicant: HOECHST AG
Inventor: WALZ GERD , HONEL MICHAEL , BRINDOPKE GERHARD , SPRENGER WALTER , FINKE MANFRED , LENZ RUDIGER
IPC: C07D317/36 , C07C67/00 , C07C239/00 , C07C269/00 , C07C271/20 , C07D303/28 , C08G18/06 , C08G18/32 , C08G18/64 , C08G18/70 , C08G18/80 , C08G18/83 , C08G59/02 , C08G59/40 , C08G71/04 , C09D5/44 , C09D175/04 , C09D175/12
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公开(公告)号:AU6872787A
公开(公告)日:1987-08-20
申请号:AU6872787
申请日:1987-02-12
Applicant: HOECHST AG
Inventor: WALZ GERD , HONEL MICHAEL , BRINDOPKE GERHARD , SPRENGER WALTER , FINKE MANFRED , LENZ RUDIGER
IPC: C07D317/36 , C07C67/00 , C07C239/00 , C07C269/00 , C07C271/20 , C07D303/28 , C08G18/06 , C08G18/32 , C08G18/64 , C08G18/70 , C08G18/80 , C08G18/83 , C08G59/02 , C08G59/40 , C08G71/04 , C09D5/44 , C09D175/04 , C09D175/12 , C07C91/12 , C09D3/72 , C08L75/12 , C08L75/04 , C07C87/14 , C07C1/24
Abstract: Amino-urethanes (I) claimed are of formula R3-N(Re)-A-R1-NH-C(O)-O-CH2-CH(OH)-CH2- R-CH2-CH(OH)-CH2-O-C(O)-NH- R1-A-N(R2)R3 R is residue of a diglycidyl ether or ester, or 2-18 alkylene gp.; R1 is opt. branched 2-18C alkylene; R2 is H, 1-8Calkyl, or 1-8C hydroxyalkyl; R3 is R2, or R3 with R2 can form cyclic ring, or, if R2 is H then R3 can be at least one gp. of formula (a) -C(O)-O-CH2-CH(R4)-CH2- (R-CH2-CH(R4)-CH2-OmB-(R4)n R4 is OH or -CONH-PI-NHCO R6; B is residue of a polyol; m is 1-3; n is 1-6; and PI is residue of a polyisocyanate and R6 is residue of (cylco)aliphatic, or alkylaromatic alcohol, an aminoalcohol, ketoxime, or a CH- or NH- acidic cpd.: b) R3 is gp. of formula (I) R5 is H or R4; R7 is 1-8Calkyl; and s is 1-6; c) -C(O)-NH-PI-NH-C(O)-O-B-d)R8-CHOH-CH2-O-CO-; e) R8-CHOH-CH2-; R8 is H, 1-18C alkyl, or residue of a glycidyl ester or ether; or f) PI'NHCO- PI' is residue of a partly capped polyisocyanate; and A 75 chemical bond or -R1NH)r-R1NH- r is 0-6. Prodn. of a (I) by heating an at least bifunctional 2-oxo-1,3-dioxolan (II) and a prim polyamine at 20-150 deg.C is claimed. Structural formulae are given for pref. R, viz. residues of a bisphenol diglycidyl ether opt. linked by residues of a diamine, diol, dicarboxylic acid, di-isocyanate, etc. Pref. (II) is bicyclic carbonate of specified formuls esp. derived from polyglycidyl ether of a polyphenol, or a epoxide-cyclic carbonate.
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