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公开(公告)号:CA1063588A
公开(公告)日:1979-10-02
申请号:CA221177
申请日:1975-02-28
Applicant: HOECHST AG
Inventor: RUST KURT , SCHROTT ERWIN , STRAMETZ HELMUT , WALTER DIETER , KABLITZ HANS-JURGEN
Abstract: of the disclosure: A catalyst of high activity and stereospecificity in .alpha.-olefin polymerization is obtained when titanium trichloride, prepared from titanium tetrachloride by reduction with an aluminum alkyl halide, is treated first with an ether and then, without separation of the ether, with an aluminum alkyl halide, optionally in the presernce of a small amount of a cyclo polyene and/or an olefin. With the catalyst obtained high spacetime yields of .alpha.-olefin polymers and copolymers can be produced.
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公开(公告)号:CA1074775A
公开(公告)日:1980-04-01
申请号:CA221176
申请日:1975-02-28
Applicant: HOECHST AG
Inventor: RUST KURT , SCHROTT ERWIN , STRAMETZ HELMUT , KABLITZ HANS-JURGEN
Abstract: Process for the manufacture of a catalyst A catalyst of high activity and stereospecificity in .alpha.-olefin polymerization is obtained by subjecting titanium Trichloride, obtained by reduction of titanium tetrachloride with aluminum alkyl halides, to two thermal treatments, the second thermal treatment being carried out in the presence of a dialkyl ether and optionally of a cyclopolyene, and optionally subjecting the treated product to an after-treat-ment with an aluminum alkyl halide, optionally in the presence of a small amount of a cyclopolyene and/or an olefin.
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公开(公告)号:AU7863575A
公开(公告)日:1976-09-02
申请号:AU7863575
申请日:1975-02-27
Applicant: HOECHST AG
Inventor: RUST KURT , SCHROTT ERWIN , STRAMETZ HELMUT , WALTER DIETER , KABLITZ HANS-JURGEN
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公开(公告)号:AU8744682A
公开(公告)日:1983-02-24
申请号:AU8744682
申请日:1982-08-20
Applicant: HOECHST AG
Inventor: KABLITZ HANS-JURGEN , STRAMETZ HELMUT
IPC: C08F6/02 , C08F6/24 , C08F110/06
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公开(公告)号:AU7863675A
公开(公告)日:1976-09-02
申请号:AU7863675
申请日:1975-02-27
Applicant: HOECHST AG
Inventor: RUST KURT , SCHROTT ERWIN , STRAMETZ HELMUT , KABLITZ HANS-JURGEN
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公开(公告)号:AU554147B2
公开(公告)日:1986-08-07
申请号:AU8744682
申请日:1982-08-20
Applicant: HOECHST AG
Inventor: KABLITZ HANS-JURGEN , STRAMETZ HELMUT
IPC: C08F6/02 , C08F6/24 , C08F110/06
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公开(公告)号:CA1064010A
公开(公告)日:1979-10-09
申请号:CA221178
申请日:1975-02-28
Applicant: HOECHST AG
Inventor: RUST KURT , SCHROTT ERWIN , STRAMETZ HELMUT , KABLITZ HANS-JURGEN
Abstract: Process for the manufacture of a catalyst of the disclosure: A catalyst of high activity and stereospecificity in .alpha.-olefin, polymerization is obtained when titanium trichloride, prepared from titanium tetrachloride by reduction with an aluminum alkyl halide, is thermally treated, first with an ether in the presence of a cyclopolyene and the solid reaction product is then treated with an aluminum alkyl halide in the presence of a small amount of a cyclopolyene and/or an olefin. With the catalyst obtained high spacetime yields of .alpha.-olefin polymers and copolymers can be produced.
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公开(公告)号:AU7863775A
公开(公告)日:1976-09-02
申请号:AU7863775
申请日:1975-02-27
Applicant: HOECHST AG
Inventor: RUST KURT , SCHROTT ERWIN , STRAMETZ HELMUT , KABLITZ HANS-JURGEN
Abstract: A catalyst of high activity and stereospecificity in alpha -olefin polymerization is obtained when titanium trichloride, prepared from titanium tetrachloride by reduction with an aluminum alkyl halide, is thermally treated, first with an ether in the presence of a cyclopolyene and the solid reaction product is then treated with an aluminum alkyl halide in the presence of a small amount of a cyclopolyene and/or an olefin. With the catalyst obtained high space-time yields of alpha -olefin polymers and copolymers can be produced.
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