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    Process for polymerizing {60 -olefins
    1.
    发明授权
    Process for polymerizing {60 -olefins 失效
    聚合{60-烯烃的方法

    公开(公告)号：US3676415A

    公开(公告)日：1972-07-11

    申请号：US3676415D

    申请日：1969-06-25

    Applicant: HOECHST AG

    Inventor： DIEDRICH BERND ,  KEIL KARL DIETHER ,  RUST KURT

    IPC: C07F7/00 ,  C08F10/02 ,  C08F1/56 ,  C08F3/06

    CPC classification number: C07F7/006 ,  C08F10/02 ,  Y10S526/901 ,  C08F4/654

    Abstract: The invention provides a process for homopolymerizing or copolymerizing ethylene in the presence of mixed catalysts comprising as component A the reaction products of specific tetravalent titanium compounds with halogen-free magnesium compounds containing 0.1 to 2 moles of OH groups per gram-atom of magnesium and as component B an organo-aluminum compound. Under a pressure below 20 atmospheres the yields are so high per unit of catalyst that the residues thereof need not be removed from the polymer. It is possible to produce polymers having a very narrow distribution of molecular weight and very good color and corrosion values.

    Abstract translation: 本发明提供了一种在混合催化剂存在下均匀聚合或共聚乙烯的方法，其包含特定四价钛化合物与每克原子镁含0.1至2摩尔OH基的无卤镁化合物的反应产物作为组分A， 组分B为有机铝化合物。 在低于20个大气压的压力下，每单位催化剂的产率如此之高，使其残余物不需要从聚合物中除去。 可以生产具有非常窄的分子量分布和非常好的颜色和腐蚀值的聚合物。

    Process for the polymerization of mono-olefins
    2.
    发明授权
    Process for the polymerization of mono-olefins 失效
    单烯烃聚合方法

    公开(公告)号：US3865902A

    公开(公告)日：1975-02-11

    申请号：US34985073

    申请日：1973-04-10

    Applicant: HOECHST AG

    Inventor： GORDON WOLFGANG ,  RUST KURT ,  SCHROTT ERWIN

    IPC: C08F2/00 ,  C08F2/34 ,  C08F4/00 ,  C08F4/60 ,  C08F10/00 ,  C08F1/56 ,  C08F1/40 ,  C08F3/10

    CPC classification number: C08F10/00 ,  Y10S526/903 ,  C08F4/6491 ,  C08F4/6495

    Abstract: The object of the invention is a process for the preparation of olefin polymers using a modified Ziegler catalyst. As modifications compounds are used which contain as the only functional groups one or two tertiary carboxylic acid amide groups or a urea grouping four times substituted at the nitrogen atoms. Polymers are obtained which confer special mechanical properties on the molded articles prepared therefrom.

    Abstract translation: 本发明的目的是使用改性齐格勒催化剂制备烯烃聚合物的方法。 作为修饰化合物，其含有作为唯一官能团的一个或两个叔羧酸酰胺基团或在氮原子上四次取代的脲基团。 获得的聚合物对由其制备的模塑制品赋予特殊的机械性能。

    Process for polymerizing {60 -olefins
    3.
    发明授权
    Process for polymerizing {60 -olefins 失效
    聚合{60-烯烃的方法

    公开(公告)号：US3676414A

    公开(公告)日：1972-07-11

    申请号：US3676414D

    申请日：1969-06-25

    Applicant: HOECHST AG

    Inventor： DIEDRICH BERND ,  KEIL KARL DIETHER ,  RUST KURT

    IPC: C08F2/00 ,  C08F10/02 ,  C08F1/56 ,  C08F3/06

    CPC classification number: C08F10/02 ,  C08F4/654

    Abstract: The invention provides a process for homopolymerizing or copolymerizing ethylene in the presence of mixed catalysts comprising as component A the reaction products of specific tetravalent titanium compounds with chlorine-containing magnesium compounds containing at least 1.5 moles of OH groups per gramatom of magnesium and as component B an organo-aluminum compound. Under a pressure below 20 atmospheres the yields are so high per unit of catalyst that the residues thereof need not be removed from the polymer. It is possible to produce polymers having a very narrow distribution of molecular weight and very good color and corrosion values.

    Abstract translation: 本发明提供了一种在混合催化剂存在下均匀聚合或共聚乙烯的方法，所述混合催化剂包含特定四价钛化合物与每克原子镁至少含有1.5摩尔OH基团的含氯化合物的反应产物作为组分A， 组分B为有机铝化合物。 在低于20个大气压的压力下，每单位催化剂的产率如此之高，使其残余物不需要从聚合物中除去。 可以生产具有非常窄的分子量分布和非常好的颜色和腐蚀值的聚合物。

    PROCESS FOR PREPARING A CATALYST
    8.
    发明专利
    PROCESS FOR PREPARING A CATALYST 未知

    公开(公告)号：HU171453B

    公开(公告)日：1978-01-28

    申请号：HUHO001802

    申请日：1975-05-20

    Applicant: HOECHST AG

    Inventor： RUST KURT ,  SCHROTT ERWIN ,  STRAMETZ HELMUT ,  KABLITZ HANS J

    IPC: C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00 ,  C08F4/42

    Abstract: A catalyst of high activity and stereospecificity in alpha -olefin polymerization is obtained when titanium trichloride, prepared from titanium tetrachloride by reduction with an aluminum alkyl halide, is thermally treated, first with an ether in the presence of a cyclopolyene and the solid reaction product is then treated with an aluminum alkyl halide in the presence of a small amount of a cyclopolyene and/or an olefin. With the catalyst obtained high space-time yields of alpha -olefin polymers and copolymers can be produced.

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