Abstract:
THE INVENTION RELATES TO A PROCESS OF RECOVERING ANTIMONY PENTACHLORIDE FROM CATALYST SOLUTIONS USED FOR THE FLUORINATION OF CHLORINE CONTAINING HYDROCARBONS. THE PROCESS IS BASED UPON A THERMAL DECOMPOSITION OF ANTIMONY PENTACHLORIDE INTO ANTIMONY TRICHLORIDE AND CHLORINE AT A TEMPERATURE OF 60* TO 300*C. THE ORGANIC IMPURITIES ARE EXTRACTED FROM THE PRECIPITATED ANTIMONY TRICHLORIDE BY MEANS OF HALOGENATED HYDROCARBONS. THE REMAINING ANTIMONY TRICHLORIDE IS REOXIDATED WITH CHLORINE-WHICH MAY BE RECYCLED FROM THE STEP OF THE THERMAL DECOMPOSITION-AT AT TEMPERATURE OF FROM 60* TO 150* C. AND A PRESSURE OF ZERO TO FIVE ATMOSPHERES TO YIELD ANTIMONY PENTACHLORIDE WHICH IS REFINED BY DISTILLATION.
Abstract:
To produce N2O, ammonium nitrate is decomposed in an aqueous, chloride-containing solution in nitric acid while an ammonia atmosphere is maintained above the reaction mixture. The preferred temperature range of the solution is 110 DEG -125 DEG C. The atmosphere of ammonia is maintained by introducing at least part of the required ammonia into the gas volume of the reaction vessel. The decomposition of the ammonium nitrate and the formation of N2O is enhanced by the presence of catalytically active ions of manganese, copper, cerium, lead, bismuth, cobalt and nickel; manganese, especially in its bivalent form, being preferred.
Abstract:
1415684 Metal oxido compounds HOECHST AG 9 Oct 1972 [7 Oct 1971] 46535/72 Heading C1A [Also in Divisions C6-C7] A crystalline oxido compound of ruthenium and/or iridium with gallium, indium, thallium, copper, zinc or cobalt is formed by heating a mixture or solution comprising thermally decomposable compounds of the relevant metals at a temperature below 900‹ C. in the presence or air or oxygen. Suitable decomposable compounds include the formates, acetates, oxalates, tartrates, oleates, citrates, stearates, naphthenates and resinates of any of the above metals and the chlorides, nitrosochlorides, nitrosonitrates, complex compounds and carbonyls of ruthenium and iridium.
Abstract:
The preparation of condensed aluminum phosphates containing phosphorus pentoxide and aluminum trioxide in a molar ratio within the range of from 1.1 : 1 to 3 : 1 is carried out by reacting water-soluble alkali metal polyphosphates with water-soluble aluminum salts and water and subjecting them to a heat treatment.