Abstract:
Phosphonic or phosphinic acid esters containing in the alcohol moiety a carbamate group are obtained by trans-esterifying an alkyl or alkenyl phosphonate or phosphinate with an alkanol carrying in terminal position a carbamate group and reacting the so-obtained phosphonate or phosphinate with a component carrying one to three active vinyl or propenyl groups, such as acrylonitrile, divinylsulfone or tris-acryloyl-hexahydro-1,3,5triazine. The products are useful for rendering fibrous materials flame-retardant or flame-proof. They may be used directly or after reacting them with formaldehyde.
Abstract:
CELLULOSE FIBER MATERIASL ARE RENDERED FLAME PROOF AND FAST TO WASHING BY (A) IMPREGNATION WITH AQUEOUS BATH CONTAINING PHOSPHORIC ACID ESTERS WITH N-METHYLOL GROUPS AND, OPTIONALLY, AMINOPLAST PRECONDENSATES AND/OR AMINOPLAST CONDENSATION CATALYSTS, AND (B) SUBSEQUENT HEAT TREATMENT.
Abstract:
Condensation products of dialkylphosphites or alkylphosphonites and phosphorus containing polyols are capable of rendering fibrous materials flame-proof or flame-retardant. The flame-proof finish is fast to washing and dry-cleaning and is effective on natural and synthetic fibrous material.
Abstract:
FIBROUS MATERIALS ESSENTIALLY CONSISTING OF MIXTURE OF POLYESTERS AND CELLULOSE ARE RENDERED FIRE-PROOF BY TREATMENT WITH THE AMMONIUM SALT OF BIS-(HYDROXYMETHYL)PHOSPHINIC ACID. THIS TREATMENT IMPROVES, FURTHERMORE, THE SOFT HANDLE OF THE GOODS.
Abstract:
1364700 Derivatives of urethanoalkyl phosphonic acid esters FARBWERKE HOECHST AG 25 Aug 1971 [29 Aug 1970] 39846/71 Addition to 1311906 Heading C2P [Also in Division D1] Novel compounds of the general formula wherein each of R, R 1 and R 11 are alkyl, preferably C 1 -C 4 alkyl, and Y is H or a methylol group, are obtained by reacting a compound of the formula with formaldehyde. The products are useful as flame-proofing agents for cellulosic fibrous materials. The compounds (II) may be obtained by reacting a compound with phosgene to form and then treating the latter with ammonia, or by reacting III with chlorosulphonyl isocyanate and then hydrolysing the main reaction product.