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公开(公告)号:AU528823B2
公开(公告)日:1983-05-12
申请号:AU4871279
申请日:1979-07-06
Applicant: HOECHST AG
Inventor: RUST KURT , BRINKMANN LUDWIG , LUTZ PAUL
IPC: C08F4/00 , C08F4/02 , C08F4/60 , C08F4/64 , C08F10/00 , C08F297/08 , A61K31/557 , C08F110/06
Abstract: A catalyst system of such high efficiency that the purification of the polymer can be dispensed with is obtained by first reacting a magnesium halide with an electron donor and/or a cyclopolyene, bringing the product obtained into contact with a TiCl3-containing compound and using a stereoregulator. The system has a high stereospecificity whereby the proportion of atactic polymer is kept low. No excess amount of transition metal halides is required and the polymer obtained has uniform coarse particles and a very low halogen content.
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公开(公告)号:DE3325221A1
公开(公告)日:1985-01-24
申请号:DE3325221
申请日:1983-07-13
Applicant: HOECHST AG
Inventor: RUST KURT DR , FRANKE RAINER DR , LUTZ PAUL
Abstract: If a tetravalent titanium compound is reduced by means of an organoaluminium compound in the presence of a magnesium alkoxide (alcoholate) and/or a product of the reaction thereof with an organoaluminium compound, a catalyst component is obtained which can be used, without removal of by-products, for the polymerisation of ethylene or mixtures of ethylene with other 1-olefins. This catalyst component can be used to prepare, in very good activity, both polyolefins having a broad molecular weight distribution and low-molecular-weight polymers having a narrow molecular weight distribution.
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公开(公告)号:CA1152055A
公开(公告)日:1983-08-16
申请号:CA331329
申请日:1979-07-06
Applicant: HOECHST AG
Inventor: RUST KURT , BRINKMANN LUDWIG , LUTZ PAUL
Abstract: A catalyst system of high efficiency so that the purification of the polymer can be dispensed with is obtained by first reacting a magnesium halide with an electron donor and/or a cyclopolyene, bringing the product obtained into contact with a TiCl3-containing compound and using a stereoregulator. The system has a high stereospecificity whereby the proportion of atactic polymer is kept low. No excess amount of transition metal halides is required and the polymer obtained has uniform coarse particles and a very low halogen content.
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公开(公告)号:AU4871279A
公开(公告)日:1980-01-10
申请号:AU4871279
申请日:1979-07-06
Applicant: HOECHST AG
Inventor: RUST KURT , BRINKMANN LUDWIG , LUTZ PAUL
IPC: C08F4/00 , C08F4/02 , C08F4/60 , C08F4/64 , C08F10/00 , C08F297/08 , C08F110/06
Abstract: A catalyst system of such high efficiency that the purification of the polymer can be dispensed with is obtained by first reacting a magnesium halide with an electron donor and/or a cyclopolyene, bringing the product obtained into contact with a TiCl3-containing compound and using a stereoregulator. The system has a high stereospecificity whereby the proportion of atactic polymer is kept low. No excess amount of transition metal halides is required and the polymer obtained has uniform coarse particles and a very low halogen content.
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公开(公告)号:DE2830039A1
公开(公告)日:1980-01-17
申请号:DE2830039
申请日:1978-07-07
Applicant: HOECHST AG
Inventor: RUST KURT DIPL CHEM DR , BRINKMANN LUDWIG DIPL CHEM DR , LUTZ PAUL
Abstract: A catalyst system of such high efficiency that the purification of the polymer can be dispensed with is obtained by first reacting a magnesium halide with an electron donor and/or a cyclopolyene, bringing the product obtained into contact with a TiCl3-containing compound and using a stereoregulator. The system has a high stereospecificity whereby the proportion of atactic polymer is kept low. No excess amount of transition metal halides is required and the polymer obtained has uniform coarse particles and a very low halogen content.
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公开(公告)号:SG67333A1
公开(公告)日:1999-09-21
申请号:SG1996006994
申请日:1993-12-07
Applicant: HOECHST AG
Inventor: HETTICH BERHARD , BOHM LUDWIG , BILDA DIETER , LUTZ PAUL , SENS OLIVER
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公开(公告)号:DE2965432D1
公开(公告)日:1983-07-07
申请号:DE2965432
申请日:1979-07-04
Applicant: HOECHST AG
Inventor: RUST KURT DR , BRINKMANN LUDWIG DR , LUTZ PAUL
Abstract: A catalyst system of such high efficiency that the purification of the polymer can be dispensed with is obtained by first reacting a magnesium halide with an electron donor and/or a cyclopolyene, bringing the product obtained into contact with a TiCl3-containing compound and using a stereoregulator. The system has a high stereospecificity whereby the proportion of atactic polymer is kept low. No excess amount of transition metal halides is required and the polymer obtained has uniform coarse particles and a very low halogen content.
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