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公开(公告)号:DE3618458A1
公开(公告)日:1987-12-03
申请号:DE3618458
申请日:1986-06-02
Applicant: HOECHST AG
Inventor: SCHINZEL ERICH DR , MARTINI THOMAS DIPL CHEM DR
IPC: C07D221/14 , C11D3/42 , D06L3/12
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公开(公告)号:DE2850382A1
公开(公告)日:1980-06-04
申请号:DE2850382
申请日:1978-11-21
Applicant: HOECHST AG
Inventor: MARTINI THOMAS DIPL CHEM DR , MENGLER HELMUT DIPL CHEM DR , ROESCH GUENTHER , HOHLFELD GUENTHER
Abstract: Brighteners for detergents consisting of a mixture of 4,4'-bis-(2-morpholino-4-anilino-1,3,5-triazinylamino)-stilbene-2,2'-d isulfonic acid-di-Na salt and from 5 to 50% by weight, calculated on said brightener, of another brightener of the formula +TR in the above formula, M is an alkali metal cation, preferably sodium, X is a group of the formula -COR2 or -SO2R3, R2 being C1-C8-alkyl and R3 being C1-C5-alkyl, C4-C8-cycloalkyl, phenyl or toluyl, Y is hydrogen or C1-C5-alkyl, A is C3-C6-alkylene, R1 is hydrogen, C1-C5-alkyl, C4-C8-cycloalkyl, or a group of the formula and Z is an anilino group, a chloroanilino group or a morpholino group. Said brightener mixtures are color-stable and do not show any green discoloration even after a prolonged storage in a moist atmosphere.
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公开(公告)号:DE2306494A1
公开(公告)日:1974-09-05
申请号:DE2306494
申请日:1973-02-09
Applicant: HOECHST AG
Inventor: BENNINGER SIEGFRIED DIPL CHEM , MARTINI THOMAS DIPL CHEM DR , REBSDAT SIEGFRIED DIPL CHEM DR
IPC: C10M105/54 , C07C43/12 , C07D307/12 , C07D307/18 , C07D307/20 , C07D309/04 , C07D309/06 , C07D309/10 , C09K3/00 , C09K5/02 , C09K5/08 , C09K5/20 , C10M169/00 , C10N40/00 , C10N40/08 , C10N40/16 , C25B3/28 , F02B47/06 , C07D7/04 , C10M3/24 , C09K3/02
Abstract: Mono- or polyhydric alcohols of the alkan-, tetrahydrofuran- or tetrahydropyran series or di- or tri-alkyleneglycols are dissolved in an aprotic polar solvent and reacted with C3F6 in the presence of trialkylamines, or with tetrafluoroethylene to give the corresponding tetrafluoroethyl- or hexafluoropropyl ethers. The solution of the fluoroethers in anhydrous hydrofluoric acid is electrolyzed. Hydrogen-free perfluoroethers are obtained.
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公开(公告)号:DE2918672A1
公开(公告)日:1980-11-20
申请号:DE2918672
申请日:1979-05-09
Applicant: HOECHST AG
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公开(公告)号:DE2833470A1
公开(公告)日:1980-02-07
申请号:DE2833470
申请日:1978-07-29
Applicant: HOECHST AG
Inventor: PROSSEL GUENTER DIPL CHEM DR , SCHINZEL ERICH DR , SCHOENBERGER NORBERT DIPL CHEM , MARTINI THOMAS DIPL CHEM DR , ROESCH GUENTER
IPC: C09B57/00 , C07D271/10 , C07D271/113 , C07D413/10 , C07F9/653 , C08K5/35 , C11D3/42 , D06L3/12
Abstract: Novel 1,3,4-oxadiazolone-(2) compounds of the formula (1) wherein Y denotes carboxy optionally functionally modified or optionally substituted phenyl or a five-membered heterocycle optionally substituted and selected from the group consisting of: furan, thiophen, oxazole, imidazole, oxadiazole, oxadiazolone, triazole, benzofuran, thionaphthalene, benzoxazole, benzimidazole, and benzotriazole, R denotes hydrogen, alkyl or optionally substituted phenyl, n denotes 0 and 1 and the rings A and B carry optionally further non-chromophoric substituents. These compounds may be used as optical brighteners.
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公开(公告)号:DE2434992A1
公开(公告)日:1976-02-05
申请号:DE2434992
申请日:1974-07-20
Applicant: HOECHST AG
Inventor: MARTINI THOMAS DIPL CHEM DR
Abstract: Reaction of hexafluoropropene epoxide with phosphoric acid tris-(dialkylamides) gives the new perfluoro- alpha -[3.6-dimethyl-1.4-dioxanyl-2-oxy]-propionic acid fluoride. By hydrolysis and decarboxylation of the acid in the presence of fluorine perfluoro-2-ethoxy-[3.6-dimethyl-1.4-dioxane] is obtained which can be used as chemically inert lubricant or heat transfer liquid.
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公开(公告)号:DE2365381A1
公开(公告)日:1974-11-28
申请号:DE2365381
申请日:1973-02-09
Applicant: HOECHST AG
Inventor: BENNINGER SIEGFRIED DIPL CHEM , MARTINI THOMAS DIPL CHEM DR , REBSDAT SIEGFRIED DIPL CHEM DR
Abstract: Aliphatic and cyclic perfluoroalkyl ethers are prepd. by (A) reacting a mono- or polyalcohol with prim. and/or sec. alcohol gps., of formula (CH2OH)a-R'(OH)b (I) where R' is CnH2n+2-(a+b), where n = 1-10, c = 0-3, a and b = 0-4 and a + b >=1, or HO- (CH2)d-CH2CHR"-O e H (II), where R" is H and d = 0-4 or R" and d = O, and e = 2 or 3, in soln. in an aprotic polar solvent, with hexafluoropropylene in presence of trialkylamines, or with C2F4, at between -30 and +100 degrees C, to yield (CH2OCxF2xH)a (III) or HCxF2x-O- (CH2)d-CH2CHR"-O- eCxF2xH (IV), where x = 2 or 3, and (B) electrolysing III or IV in soln. in anhydrous HF at between -20 degrees C and +30 degrees C and tension 4-7.5 V to yield (CF2OCxF2x+l)a (V) or CxF2x+l-O- (CF2)d-CF2CFR"f-O eCxF2x+l (VI), where R'f is CnF2n+2-(a+b) R"f is F and d = 0-4 or R"f is CF3 and d + O. V and VI have great chemical stability, low dielectric constant, high breakthrough tension, and low loss factor in high frequency alternating fields.
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公开(公告)号:DE2944867A1
公开(公告)日:1981-05-27
申请号:DE2944867
申请日:1979-11-07
Applicant: HOECHST AG
Inventor: SCHOENBERGER NORBERT DIPL CHEM , SCHINZEL ERICH DR , MARTINI THOMAS DIPL CHEM DR , ROESCH GUENTHER
IPC: C09B57/08 , C07D221/14 , D06L3/12 , D06P3/70
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公开(公告)号:DE2900278A1
公开(公告)日:1980-07-24
申请号:DE2900278
申请日:1979-01-05
Applicant: HOECHST AG
IPC: C07D251/68 , D06L3/12 , D06L4/664
Abstract: Prodn. of a colourless stable crystal modification of an optical brightener of formula (I) (where M is Na or K) is effected by heating in a lower alkanol (pref. isopropanol) contg. 1-20 (pref. 5-19) wt.% H2O. Process is pref. effected by isolating (I) from its reaction mixt. in free acid form (M=H), dissolving this in H2O-contg. alcohol, forming the salt by adding alkali, and refluxing the suspension. The process avoids the addn. of electrolytes (c.f. DT1770376).
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