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    NEW BISETHER CONTAINING 2,2'-BIARYL GROUP AND ITS PRODUCTION
    1.
    发明专利
    NEW BISETHER CONTAINING 2,2'-BIARYL GROUP AND ITS PRODUCTION 失效

    公开(公告)号：JPH1059889A

    公开(公告)日：1998-03-03

    申请号：JP16712497

    申请日：1997-06-24

    Applicant: HOECHST AG

    Inventor： REGNAT DIETER DR ,  KLEINER HANS-JERG DR ,  BAHRMANN HELMUT DR

    IPC: B01J31/02 ,  C07B61/00 ,  C07C41/09 ,  C07C41/16 ,  C07C43/164 ,  C07C43/20 ,  C07C43/205

    Abstract: PROBLEM TO BE SOLVED: To obtain the subject new compound insensitive to oxygen and/or sulfur and not hydrolyzed under hydroformylation conditions or having complex characteristics. SOLUTION: A compound of formula I [R -R are each independently H, a 1-4C alkyl or alkoxy, a 2-4C alkenyl, etc.; (m), (n) are each independently 0, 1 wherein [(m)+(n)] is 1 or 2; R is not substituted or is phenyl or naphthyl which may be substituted with a 1-4C alkyl, etc.,], e.g. 2,2'-bis(phenoxymethyl)-1,1'-binaphthyl. The compound of formula I is obtained by reacting a compound of formula II (A is OH, etc.,) with a compound of formula III [B is a releasable group: Z (Cl, Br, I, etc.,), when A is OH, or B is OH, when A is the releasable group Z] in a molar ratio of 1:(2-2.2) in the presence of a base and in an organic solvent inactive under the reaction conditions, in the presence (absence) of a phase transfer catalyst and water at 10-100 deg.C. The compound of formula I can exhibit an effect as a hydroformylation catalyst for the production of aldehyde compounds.

    PRODUCTION OF ALDEHYDE BY USING CATALYST SYSTEM COMPRISING RHODIUM AND SUBSTITUTED DIPHENYLPHOSPHINES
    2.
    发明专利
    PRODUCTION OF ALDEHYDE BY USING CATALYST SYSTEM COMPRISING RHODIUM AND SUBSTITUTED DIPHENYLPHOSPHINES 失效

    公开(公告)号：JPH107613A

    公开(公告)日：1998-01-13

    申请号：JP5514697

    申请日：1997-03-10

    Applicant: HOECHST AG

    Inventor： BAHRMANN HELMUT DR ,  KLEINER HANS-JERG DR ,  REGNAT DIETER DR

    IPC: B01J31/24 ,  B01J31/28 ,  B01J31/40 ,  C07B61/00 ,  C07C45/50 ,  C07C45/78 ,  C07C47/02

    Abstract: PROBLEM TO BE SOLVED: To produce an aldehyde in high yield at a low cost with a long life of a readily reutilizable catalyst by reacting an olefinic compound with carbon monoxide and hydrogen in the presence of a specific catalyst and separating the resultant reactional product from the catalyst. SOLUTION: (C) A 2-20C olefinic compound is reacted with (D) carbon monoxide and (E) hydrogen in the presence (or absence) of (B) a solvent in the presence of (A) a catalyst comprising (A1 ) rhodium and (A2 ) a compound represented by formula I [R is H or a 1-12C alkyl; R is a 1-8C straight-chain alkylene, a 2-4C oxygen-containing alkylene, a group represented by formula II or III or a 3-10C cycloalkylene; R is a 1-25C alkyl or a 6-10C aryl; A is COO or SO3 ; (x), (y), (m) and (n) are as follows: (x)=0, (y)=(m)=(n)=1;(x)=(y)=1 and (m) and (n) are each 1 or 2 or (x) is 1; (y) is 0 and (m) and (n) are each 0 or 1 when R is a group represented by formula II or III] at 50-190 deg.C temperature under 0.1-45MPa pressure and the resultant reactional product is then separated from the component A.

    SUBSTITUTED DIPHENYLDIPHOSPHINE COMPOUND AND ITS PRODUCTION
    3.
    发明专利
    SUBSTITUTED DIPHENYLDIPHOSPHINE COMPOUND AND ITS PRODUCTION 失效

    公开(公告)号：JPH101491A

    公开(公告)日：1998-01-06

    申请号：JP5515097

    申请日：1997-03-10

    Applicant: HOECHST AG

    Inventor： REGNAT DIETER DR ,  KLEINER HANS-JERG DR ,  BAHRMANN HELMUT DR

    IPC: C07F9/50

    Abstract: PROBLEM TO BE SOLVED: To obtain the subject new diphosphine compound useful as e.g. a stabilizer, a raw material for the Wittig reagent, raw material for metal complex catalysts, by reaction between an amino group-bearing diphenylphosphine oxide, a dihalide and a base under specified conditions. SOLUTION: This compound, which is a new substituted diphenyldiphosphine compound of formula I [R is H or a 1-12C alkyl; R is a 1-8C alkylene, 2-4C oxygen-contg. alkylene, a group of formula II, 3-10C cycloalkylene, etc.; R is a 1-25C alkyl or 6-10C aryl; A is COO or SO3 ; (x)=0 and (y)=1 and (m)=1 and (n)=1, or (x)=1 and (y)=1 and (m)=1 or 2 and (n)=1 or 2, or, when R is a group of formula II, etc., (x)=1 and (y)=0 and (m)=0 or 1 and (n)=0 or 1], is useful as a stabilizer for olefins, a ligand for metal complex catalysts, etc. This new compound is obtained by reaction of a phosphine oxide of formula III or formula IV with a dihalide of the formula X-R -X (X is a halogen) and a base.

    4.
    发明专利
    未知

    公开(公告)号：DE59307840D1

    公开(公告)日：1998-01-29

    申请号：DE59307840

    申请日：1993-05-14

    Applicant: HOECHST AG

    Inventor： REGNAT DIETER DR ,  KLEINER HANS-JERG DR

    IPC: C07F9/46

    Abstract: Aryl esters of phosphinous acids of the formula (I) … … can be prepared in a simple manner and in high yields by reacting 2,4-di-tert-butylphenyl dihalophosphite with alkyl- or arylmagnesium bromides or chlorides. … Aryl esters of phosphinous acids are used for the preparation of secondary phosphane oxides, which are used in catalyst systems as starting materials for the preparation of phosphane ligands.

    8.
    发明专利
    未知

    公开(公告)号：DE4419990A1

    公开(公告)日：1995-12-14

    申请号：DE4419990

    申请日：1994-06-08

    Applicant: HOECHST AG

    Inventor： NAUMANN CHRISTOPH DR ,  REGNAT DIETER DR

    IPC: C07F9/6568 ,  C07F9/54

    Abstract: Novel phosphonium salts of formula (I) in which each CH2 gp. is ortho to the Ar-Ar band are claimed as are also (i) prepn. of (I) by reacting a bi-aryl cpd. of formula (II) with a P. cpd. (III) at 0-200 degrees C opt. in a solvent, opt. with exchange of anion Y by anion X which is a monovalent anion or the equiv. of a mineral acid carboxylic acid, sulphonic acid or alcohol multivalent anion; and (ii) use of (I) as an antistatic agent Ar-Ar = biphenyl, 1-phenyl-naphthyl or 1,1'-bi-naphthyl residue; R = F or 1-8C alkyl or alkoxy, (n = 0-4); R and R = 1-10C alkyl, 5-10C cyclo-aliphatic or Ar (R )m where Ar = phenyl or naphthyl; R3 = F, Cl, CF3, SO3H, SO3M. (M = Li, Nd or K), 2-8C dialkylamino or 1-8C alkyl or alkoxy and m = 0-5; or R and R together with P form a 4-7 membered ring opt. annelated with one or two 6-10C aromatic ring systems; A = H or Si(1-4C alkyl)3; Y = Cl, Br, I or R SO3 (R = F, CF3, CH3, Ph or tolyl); and X = anion as per (i) above.

    9.
    发明专利
    未知

    公开(公告)号：AT178040T

    公开(公告)日：1999-04-15

    申请号：AT95103583

    申请日：1995-03-13

    Applicant: HOECHST AG

    Inventor： KLEINER HANS-JERG DR ,  REGNAT DIETER DR ,  ROESCHERT HORST DR

    IPC: C07B61/00 ,  C07B60/00 ,  C07C17/14 ,  C07C25/22 ,  C07C22/04 ,  B01J19/12

    Abstract: The prodn. of 2,2'-bis(halomethyl)-1,1'-binaphthyl (I) comprises reacting 2,2'-dimethyl-1,1'-binaphthyl (II) with a halogenating agent (III) at -10 to 120 degrees C. under the action of light with a wavelength of 10 -10 m, in the presence of solvent and opt. a radical generator. Pref. reaction is carried out in inert solvent, with a wt. ratio of (II):(solvent = 1:(3-40), pref. 1:(4-20), esp. pref. 1:(5-15). Pref. solvents are chlorinated benzenes, chlorinated aliphatic hydrocarbons, or esters of 1-6C aliphatic carboxylic acids and 1-4C alkanols, pref. CH2Cl2, chlorobenzene (MCB) and/or dichlorobenzene (DCB), esp. pref. MCB and/or DCB, more esp. pref. MCB. Mole ratio (II):(III) = 1:(1.5-2.5), pref.1:(1.8-2.3), esp. pref. 1:(1.9-2.2). (III) is a chlorinating or brominating agent, pref. chlorine, N-chlorosuccinimide (NCS), bromine, N-bromo-succinimide (NBS), 1,3-dibromo-5,5-dimethylhydantoin or bromo-Meldrum's acid, esp. pref. NCS, bromine or NBS. The light source is a conventional UV emitter, and suitable radical generators are organic peroxides, peroxy-carboxylic acids, hydroperoxides or azo cpds., pref. benzoyl peroxide, benzoyl perhexadecanoate or AIBN

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