5.
    发明专利
    未知

    公开(公告)号:DE3519161A1

    公开(公告)日:1986-12-04

    申请号:DE3519161

    申请日:1985-05-29

    Applicant: HOECHST AG

    Abstract: A process for the purification of 1,2-dichloroethane is described, in which the crude product, containing not more than 3% by weight of high-boilers, is distilled in a first column at 125 DEG to 180 DEG C. in such a way that the bottom product contains not more than 7% by weight of high-boilers. The purified, vaporous 1,2-dichloroethane discharged at the head of this column is used to heat product streams containing 1,2-dichloroethane. The bottom product from the first column is distilled in a second column, advantageously at a pressure of 5 to 40 kPa, together with a feed composed of vaporous 1,2-dichloroethane obtained from the reaction of ethylene with chlorine. The process makes it possible to purify 1,2-dichloroethane with a saving in energy.

    10.
    发明专利
    未知

    公开(公告)号:DE3878701D1

    公开(公告)日:1993-04-08

    申请号:DE3878701

    申请日:1988-01-22

    Abstract: Prodn. of vinyl chloride (I) from 1,2-dichloroethane (II) is carried out by thermal elimination of HCl in a cracking furnace contg. a radiation zone. The novelty is that a gas contg. at least 95 wt.% (II) is heated in a heat exchanger by indirect heat exchange with hot gas contg. (I) leaving the radiation zone and then passed into the furnace. The furnace pref. contains a radiation and a convection zone and the hot gas contg. at least 95 wt.% (II) is produced from liq. (II) in the convection zone by indirect heat exchange with the flue gas. Alternatively, gas contg. at least 85, pref. at least 95 wt.% (II) is produced from liq. (II) entirely or partly outside the furnace in a vaporiser, pref. by indirect heat exchange with hot gas contg. (I) discharged from the radiation zone.

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