Process for producing homo-and copolymers of cyclic acetals
    2.
    发明授权
    Process for producing homo-and copolymers of cyclic acetals 失效
    生产循环乙醇的共聚物的方法

    公开(公告)号:US3848020A

    公开(公告)日:1974-11-12

    申请号:US28155972

    申请日:1972-08-17

    Applicant: HOECHST AG

    Inventor: BURG K SCHLAF H

    CPC classification number: C08G4/00 C08G2/10

    Abstract: 1. IN A PROCESS FOR PRODUCING MOLDABLE HOMOPOLYMERS OF TRIOXANE OR COPOLYMERS COMPRISING A MAJOR AMOUNT OF UNITS DERIVED FROM TRIOXANE AND A MINOR AMOUNT OF UNITS DERIVED FROM A LINEAR ACETAL OF AN A,W-DIOL OR A CYCLIC ACETAL OF THE FORMULA

    O
    WHEREIN R1, R2, R3 AND R4 MAY BE THE SAME OR DIFFERENT REPRESENT HYDROGEN OR AN ALKYL GROUP WHICH CAN BE HALOGEN-SUBSTITUTED, R5 REPRESENTS AN OXYMETHYLENE RADICAL WHICH CAN BE SUBSTITUTED BY AN ALKYL OR HALOGEN-SUBSTITUTED ALKYL GROUP, AND N IS 1 TO 3, OR WHEN N IS 1, R5 CAN BE THE RADICAL -(O-CH2CH2)M-OCH2- WHEREIN M IS 1 TO 3, AT A TEMPERATURE BETWEEN THE MELTING POINT AND BOILING POINT OF THE MONOMER OR MONOMER MIXTURE IN THE PRESENCE OF A PROTONIC ACID, THE IMPROVEMENT WHICH CONSISTS IN USING AN ANHYDROUS PERFLUOROALKYL SULFONIC ACID WITH 1 TO 18 CARBON ATOMS AS THE PROTONIC ACID.

    4.
    发明专利
    未知

    公开(公告)号:DK140850C

    公开(公告)日:1980-04-28

    申请号:DK496675

    申请日:1975-11-05

    Applicant: HOECHST AG

    Abstract: Oxymethylene polymers (POM) are obtained in granular form by cooling a POM solution or dispersion having a temperature above the sintering temperature of the POM in two stages to a temperature just below the said sintering temperature. The solvent or dispersion agent used is a mixture of methanol and water and the cooling agent is a methanol/water mixture which may contain POM suspended therein. The granular POM obtained is suitable as technical material for making shaped articles.

    7.
    发明专利
    未知

    公开(公告)号:SE7705211L

    公开(公告)日:1977-11-07

    申请号:SE7705211

    申请日:1977-05-04

    Applicant: HOECHST AG

    Abstract: of the disclosure: Granular oxymethlene polymers are prepared by cooling a solution or dispersion of an oxymethylene polymer, the temperature of the said solution of dispersion polymer, to a temperature just below the said sintering temperature. As dissolving or dispersing agent there is used a mixture of methanol and water. The cooling of the said solution of dispersion is effected in two stages while using a liquid cooling agent or a cooling device. After precipitation the coarse-granular polymer is separated from the fine-granular portion. It is suitable as engineering plastic for preparing molded articles.

    8.
    发明专利
    未知

    公开(公告)号:DK199477A

    公开(公告)日:1977-11-07

    申请号:DK199477

    申请日:1977-05-05

    Applicant: HOECHST AG

    Abstract: of the disclosure: Granular oxymethlene polymers are prepared by cooling a solution or dispersion of an oxymethylene polymer, the temperature of the said solution of dispersion polymer, to a temperature just below the said sintering temperature. As dissolving or dispersing agent there is used a mixture of methanol and water. The cooling of the said solution of dispersion is effected in two stages while using a liquid cooling agent or a cooling device. After precipitation the coarse-granular polymer is separated from the fine-granular portion. It is suitable as engineering plastic for preparing molded articles.

    9.
    发明专利
    未知

    公开(公告)号:DK496675A

    公开(公告)日:1976-05-08

    申请号:DK496675

    申请日:1975-11-05

    Applicant: HOECHST AG

    Abstract: Oxymethylene polymers (POM) are obtained in granular form by cooling a POM solution or dispersion having a temperature above the sintering temperature of the POM in two stages to a temperature just below the said sintering temperature. The solvent or dispersion agent used is a mixture of methanol and water and the cooling agent is a methanol/water mixture which may contain POM suspended therein. The granular POM obtained is suitable as technical material for making shaped articles.

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