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公开(公告)号:SG73410A1
公开(公告)日:2000-06-20
申请号:SG1996006972
申请日:1993-06-07
Applicant: HOECHST AG
Inventor: HELMER-METZMANN FREDDY , OSAN FRANK , SCHNELLER ARNOLD , RITTER HELMUT , LEDJEFF KONSTANTIN , NOLTE ROLAND , THORWORTH RALF
IPC: B01D71/52 , C08F2/48 , C08G65/40 , C08G65/48 , C08J5/18 , C08J5/22 , C08L71/00 , C08L71/10 , C08L71/12 , C25B13/08 , H01B1/06 , H01M8/02 , H01M8/10 , C23A
Abstract: In order to produce a polymer electrolyte membrane from sulphonated aromatic polyether ketone, an aromatic polyether ketone of the formula (I) where Ar is a phenylene ring having p- and/or m-bonds, Ar' is a phenylene, naphthylene, biphenylene, anthrylene or another divalent aromatic unit, X, N and M, independently of one another, are 0 or 1, Y is 0, 1, 2 or 3, P is 1, 2, 3 or 4, is sulphonated, and the sulphonic acid is isolated. At least 5 % of the sulphonyl groups in the sulphonic acid are converted into sulphonyl chloride groups, and these are reacted with an amine which has at least one crosslinkable substituent or a further functional group, and unreacted sulphonyl chloride groups are subsequently hydrolysed. The resultant aromatic sulphonamide is isolated and dissolved in an organic solvent, the solution is converted into a film, and the crosslinkable substituents present in the film are then crosslinked. In specific cases, the crosslinkable substituents can be omitted. In this case, sulphonated polyether ketone is converted into a film from solution.