-
1.
公开(公告)号:US3619234A
公开(公告)日:1971-11-09
申请号:US3619234D
申请日:1969-02-14
Applicant: HOECHST AG
Inventor: WEIHSBACH JOACHIM , SMERZ OTTO , ROSCH GUNTER
IPC: D06L3/12
CPC classification number: D06L4/679
Abstract: Fibrous materials of synthetic polyamides or cellulose esters are capable of optical brightening according to the so-called thermosol process (padding at ambient temperature with subsequent fixation by a heat treatment) when fixing in the presence of an auxiliary consisting of a polyalkylene glycol and a fatty alcohol oxethylate. Optionally foam-depressing phosphoric acid alkyl esters and branched carboxylic acid esters are used additionally.
-
公开(公告)号:DE2702635A1
公开(公告)日:1978-08-03
申请号:DE2702635
申请日:1977-01-22
Applicant: HOECHST AG
Inventor: SMERZ OTTO DR , SCHINZEL ERICH DR , ROESCH GUENTER , WEIHSBACH JOACHIM
-
3.
公开(公告)号:CA876605A
公开(公告)日:1971-07-27
申请号:CA876605D
Applicant: HOECHST AG
Inventor: WEIHSBACH JOACHIM , SMERZ OTTO , ROSCH GUNTER
-
公开(公告)号:DE1719355A1
公开(公告)日:1968-08-05
申请号:DE1719355
申请日:1968-03-02
Applicant: HOECHST AG
Inventor: WEIHSBACH JOACHIM , SMERZ OTTO DIPL-CHEM DR , ROESCH GUENTER
Abstract: 1,248,319. Optically brightening textiles. FARBWERKE HOECHST A.G. 27 Feb., 1969 [2 March, 1968], No. 10619/69. Heading D1P. [Also in Division C5] Synthetic polyamide or cellulose ester fibrous materials are optically brightened by impregnating with a liquor containing an optical brightener and subsequently fixing the brightener on the fibres by heat treatment in the presence of an auxiliary agent comprising or consisting of a polyalkylene glycol HO-(C n H 2n O) x -H where n is 2 or 3 and x is from 2 to 22 and a fatty alcohol oxyethylate RO-(C 2 H 4 O) z -H where R is a C 8 to C 24 alkyl or alkenyl residue and z is from 3 to 16. Preferably the auxiliary agent also includes a foam-depressing compound such as an aliphatic carboxylic acid ester R 2 COOR 1 where R 1 and R 2 each represents a C 4 to C 18 saturated or unsaturated aliphatic group and may be the same or different, one or both of said groups containing at least one C 1 to C 4 side chain, preferably in the α- position in the acid radical but in the α- or #- position in the alcohol radical. A phosphoric acid ester of a C 4 to C 8 aliphatic alcohol may also be included in the auxiliary agent. As described the auxiliary agent is applied to the fibres together with the brightening agent and citric acid, and other treating agents may be included in the treating solution, dispersion or emulsion. Examples are given of brightening knitted nylon 6 fabric, nylon 66 fabric, and cellulose triacetate fibres. Specified optical brightening agents are sodium-1-sulphonate ethylsulphonylphenyl-3-p chlorophenyl pyrazol-4-ine and the corresponding 1-acetamido ethyl sulphonyl-phenyl compound and 4:4' bis (2"- anilino - 4" - methoxy - 6".- imino-1":3":5"- triazine)-stilbene-2:2'-bis(sodium sulphonate), and heat treatment is effected at 190 to 200C. In the case of nylon 66 fabric a dye is added to the treating solution to improve the whiteness of the fabric, while in treating cellulose triacetate fibres a nonyl phenol/ ethylene oxide condensate is additionally included.
-
-
-