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    MIXTURE OF OPTICAL BRIGHTENERS
    2.
    发明授权
    MIXTURE OF OPTICAL BRIGHTENERS 失效

    公开(公告)号：KR850000051B1

    公开(公告)日：1985-02-14

    申请号：KR790003139

    申请日：1979-09-12

    Applicant: HOECHST AG

    Inventor： GUNTHER DIETER ,  ROSCH GUNTER ,  ERCKEL RUDIGER ,  PROBST HEINZ

    IPC: C09K11/06 ,  C09G1/06 ,  H04N5/30

    Abstract: Optical brighteners are prepared from 0.98-0.50 parts of a mixture prepared from 0.05-0.95 parts of compd. (I) and 0.95-0.05 parts of compd.(II), and 0.02-0.50 parts of compd. (III), where R1 = H or C1-C4 alkyl; R2 = H or C1-C4 alkyl in 6- or 7-position; A = -CN, - COOH, -COOCH3, -C6H5, or a nitrogen ring compd. containing R4 gp.; R4 = C1-C4 alkyl or β-hydroxy ethyl; and R3 = H or C1-C4 alkyl.

    Dispersions of optical brighteners containing salt-forming solubilizing groups
    6.
    发明授权
    Dispersions of optical brighteners containing salt-forming solubilizing groups 失效
    含有盐形成溶解组的光亮剂分散体

    公开(公告)号：US3689429A

    公开(公告)日：1972-09-05

    申请号：US3689429D

    申请日：1971-04-15

    Applicant: HOECHST AG

    Inventor： DEUBEL REINHOLD ,  SCHINZEL ERICH ,  HEMMERLING VOLKER ,  ROSCH GUNTER

    IPC: C09B67/24 ,  D06L3/12

    CPC classification number: C09B67/0075 ,  C09B67/0072 ,  D06L4/621 ,  D06L4/664

    Abstract: STABLE DISPERSIONS OF OPTICAL BRIGHTENERS HAVING SALTFORMING SOLUBILIZING GROUPS ARE OBTAINED WHEN USING AN ANHYDROUS WATER-MISCIBLE DI- OR TRIHYDRIC LOWER ALIPHATIC ALCOHOL, A LOWER ALKYL OR PHENYL ETHER OR A WATER-SOLUBLE POLYETHER THEREOF AS DISPERSING AGENT AND DISPERSING MEDIIUM. THE USE OF A FURTHER NON-IONIC DISPERSING AGENT IS OPTIONAL. THESE DISPERSIONS ARE PREFERRED FOR CONTINUOUS BRIGHTENING PROCESSES BECAUSE OF THEIR EASY DOSAGE AND THE AVOIDING OF DUST AND ISSOLVING MANIPULATIONS.

    Abstract translation: 1,250,207。 荧光增白剂的分散体。 FARBWERKE HOECHST A.G. 1968年12月20日[1967年12月23日]，第60764/68号。 标题B1V。 [也在D1部分]含有羧酸和/或磺酸基团的荧光增白剂在由无水水混溶性二元或三元醇和/或醇的醚组成的液体分散介质中的稳定分散体和/或 醇的水溶性聚醚可以含有10％至90％的荧光增白剂。 荧光增白剂可以是双 - 三嗪基氨基芪二磺酸或水溶性1,3-二芳基吡唑啉的水溶性衍生物; 给出了例子。 分散体可以通过用分散介质和任选地用非离子分散剂（例如聚乙氧基化壬基苯酚）在捏合或研磨装置中处理荧光增白剂直到颗粒具有0.5-3微米的尺寸来制备。

    Process for the optical brightening of fibrous materials made from polyacrylonitrile
    9.
    发明授权
    Process for the optical brightening of fibrous materials made from polyacrylonitrile 失效
    从聚丙烯酸酯制成的纤维材料的光学加工方法

    公开(公告)号：US3690947A

    公开(公告)日：1972-09-12

    申请号：US3690947D

    申请日：1970-01-21

    Applicant: HOECHST AG

    Inventor： ROSCH GUNTER ,  LINKE WERNER ,  SMERZ OTTO ,  SCHINZEL ERICH

    IPC: C09B57/00 ,  C07D231/06 ,  D06L3/12 ,  D06M13/35 ,  C09K1/02

    CPC classification number: C07D231/06 ,  D06L4/679 ,  D06M13/35

    Abstract: FIBROUS MATERIALS MADE OF POLYMERS CONTAINING AT LEAST 85% OF POLYACRYLATONITRILE CAN BE OPTICALLY BRIGHTENED IN A SAID MATERIAL WITH A LIQUOR CONTAINING A 1-(4''-B-ALKOXYETHYL SULFONYL)-PHENYL-3-B-CHLOROPHENYL-$2-PYRAZOLINE, ADJUSTING THE IMPREGNATED MATERIAL TO A LIQUOR CONTENT OF ABOUT 5 TO 120% BY WEIGHT REFERRED TO THE DRY-WEIGHT OF THE GOODS, AND HEATING IT FOR ABOUT 2 SECONDS TO 30 MINUTES TO A TEMPERATURE OF ABOUT 100 TO 150*C.

    Abstract translation: 1288545荧光增白FARBWERKE HOECHST AG 19 Jan 1970 [30 Jan 1969] 4340/70标题DIP包含至少85％的聚丙烯腈的聚合物的纤维材料通过用含有通式光亮剂的液体浸渍材料进行光学增白，其中A代表 支链或非支链C 2-4亚烷基，R SP 1表示C 1-4烷基，R SP 2表示C 1-4烷基或两个基团 R 2 与氮原子一起形成饱和杂环，X表示无色阴离子，n为1或2，将材料的液体含量调整为参考材料的5-120重量％ 并在100 <-150℃下加热，优选用蒸汽加热2秒至30分钟。 如果亮面织物要立即印刷，则优选在50 <-150℃进行中间干燥。 添加增稠剂例如淀粉醚，黄蓍胶，角豆粉和结晶胶，以防止在干燥过程中荧光增白剂的迁移。 当增亮液中加入脂肪酸和氧乙基化氨的非离子缩合产物和/或脂肪酸和低分子量脂肪族多胺的季
    缩合产物时，可实现增强的增亮。 其中A，R 1，R 2，X和n具有上述含义的通式的第二增白剂显示绿蓝色荧光，并且当应用时 与式II化合物的混合物，以补偿后者的淡红色。

    Optical brightening composition mixture of three analogous compounds
    10.
    发明授权
    Optical brightening composition mixture of three analogous compounds 失效
    三种类似化合物的光学组合物混合物

    公开(公告)号：US3655574A

    公开(公告)日：1972-04-11

    申请号：US3655574D

    申请日：1970-01-12

    Applicant: HOECHST AG

    Inventor： FRISCHKORN HANS ,  SCHINZEL ERICH ,  ROSCH GUNTER

    IPC: D06L3/12 ,  C09K1/02

    CPC classification number: D06L4/65

    Abstract: An optical brightener composition consisting of an unsymmetrical bis-triazinylamino-stilbene disulfonic acid and of the two corresponding symmetrical compounds is superior to the single components as regards the degree of whiteness obtained thereby and the multiplicity of applications for brightening of fibrous materials of cellulosic and polyamide fibers.

    Abstract translation: 由不对称双三嗪基氨基 - 二苯乙烯二磺酸和两种相应的对称化合物组成的荧光增白剂组合物相对于由此得到的白度程度优于单一组分，并且纤维素和聚酰胺的纤维材料的增亮应用的多样性 纤维。

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