FLUORESCENT BRIGHTENER MIXTURE FOR SYNTHETIC RESIN

    公开(公告)号:JPH101563A

    公开(公告)日:1998-01-06

    申请号:JP3943697

    申请日:1997-02-24

    Applicant: HOECHST AG

    Abstract: PROBLEM TO BE SOLVED: To obtain a fluorescent brightener mixture which can synergistically improve the whitening effect of a synthetic resin by combining two brighteners selected from specified compounds. SOLUTION: This mixture is a fluorescent brighter comprising below described and B, represented by formulas I and II (wherein R and R are each hydrogen, a 1-10 C alkyl or the like; and X is a 1,4-naphthylene group, a 2,5- thiophene group or a 2,5-furan group) and at least one brighter represented by formula III (R in position 5 is hydrogen, a halogen, a 1-4 C alkyl or a phenyl, R is hydrogen or R and R in positions 5 and 6 or positions 5 and 7 are each methyl; n is 0 or 1; and B is cyano, carbo-1-4 C-alkoxyl or the like). This mixture is desirably prepared by mixing components A and B with each other in an A/B weight ratio of (20-80%)/(80-20%). This mixture is used in an amount of 1-5,000ppm based on the resin.

    Mischungen von optischen Aufhellern für Kunststoffe
    2.
    发明公开
    Mischungen von optischen Aufhellern für Kunststoffe 失效
    on。。。。。。。。。。。。。。。

    公开(公告)号:EP0791680A3

    公开(公告)日:1998-09-09

    申请号:EP97102373

    申请日:1997-02-14

    Applicant: HOECHST AG

    CPC classification number: C08K5/0041 D06L4/65

    Abstract: Mischungen von optischen Aufhellern enthaltend einen oder mehrere Aufheller der Formel 1 und 1a sowie einen oder mehrere Aufheller der Formel 2

    Abstract translation: - 荧光增白剂的混合物包含(a)式(I)的双苯并恶唑基和/或式(II)和(b)的β-萘并1,2,2-二氮杂-2-基-3-苯基香豆素和(b)β- 苯并恶唑-2-基) - 苯乙烯和/或式(III)的4-(苯并恶唑-2-基) - 二苯乙烯作为增白剂; 其中R 1,R 2 =氢(H),1-10碳(C)烷基或碳 - (1-4C) - 烷氧基; X = 1,4-亚萘基,2,5-噻吩或2,5-呋喃; R 3 = H,卤素,1-4C烷基或5-位上的苯基,R 4 = H; 或R 3,R 4 =甲基(Me)在5-和6-或5-和7-位; n = 0或1; B =氰基,碳 - (1-4C) - 烷氧基或一组式; R 5 = 1-6 C烷基,1-8 C环烷基,1-4 C烷氧基 - (1-4 C) - 烷基,羟基 - (1-4 C) - 烷基或 - (CH 2 CH 2 O)n -R “; n = 2或3; R'= H或1-4C烷基; R 6 =苯基,卤代苯基,1-4 C烷基苯基或1-4 C烷氧基苯基; R 7 = 1-4 C烷基; R 8 - 氰基或碳 - (1-4C) - 烷氧基。

    3.
    发明专利
    未知

    公开(公告)号:DE19607046A1

    公开(公告)日:1997-08-28

    申请号:DE19607046

    申请日:1996-02-24

    Applicant: HOECHST AG

    Abstract: - Mixtures of optical brighteners contain (a) bisbenzoxazolyl(s) of formula (I) and/or 7-naphthoÄ1,2-dÜtriazol-2-yl-3-phenyl-coumarin of formula (II) and (b) beta -(benzoxazol-2-yl)-styrene(s) and/or 4-(benzoxazol-2-yl)-stilbene(s) of formula (III) as brighteners; in which R , R = hydrogen (H), 1-10 carbon (C) alkyl or carbo-(1-4 C)-alkoxy; X = 1,4-naphthylene, 2,5-thiophene or 2,5-furan; R = H, halogen, 1-4 C alkyl or phenyl in the 5-position and R = H; or R , R = methyl (Me) in the 5- and 6- or 5- and 7-position; n = 0 or 1; B = cyano, carbo-(1-4 C)-alkoxy or a group of the formulae; R = 1-6 C alkyl, 1-8 C cycloalkyl, 1-4 C alkoxy-(1-4 C)-alkyl, hydroxy-(1-4 C)-alkyl or -(CH2CH2O)n-R'; n = 2 or 3; R' = H or 1-4 C alkyl; R = phenyl, halophenyl, 1-4 C alkylphenyl or 1-4 C alkoxyphenyl; R = 1-4 C alkyl; R - cyano or carbo-(1-4 C)-alkoxy.

    4.
    发明专利
    未知

    公开(公告)号:BR9701047A

    公开(公告)日:1998-12-15

    申请号:BR9701047

    申请日:1997-02-21

    Applicant: HOECHST AG

    Abstract: - Mixtures of optical brighteners contain (a) bisbenzoxazolyl(s) of formula (I) and/or 7-naphthoÄ1,2-dÜtriazol-2-yl-3-phenyl-coumarin of formula (II) and (b) beta -(benzoxazol-2-yl)-styrene(s) and/or 4-(benzoxazol-2-yl)-stilbene(s) of formula (III) as brighteners; in which R , R = hydrogen (H), 1-10 carbon (C) alkyl or carbo-(1-4 C)-alkoxy; X = 1,4-naphthylene, 2,5-thiophene or 2,5-furan; R = H, halogen, 1-4 C alkyl or phenyl in the 5-position and R = H; or R , R = methyl (Me) in the 5- and 6- or 5- and 7-position; n = 0 or 1; B = cyano, carbo-(1-4 C)-alkoxy or a group of the formulae; R = 1-6 C alkyl, 1-8 C cycloalkyl, 1-4 C alkoxy-(1-4 C)-alkyl, hydroxy-(1-4 C)-alkyl or -(CH2CH2O)n-R'; n = 2 or 3; R' = H or 1-4 C alkyl; R = phenyl, halophenyl, 1-4 C alkylphenyl or 1-4 C alkoxyphenyl; R = 1-4 C alkyl; R - cyano or carbo-(1-4 C)-alkoxy.

    7.
    发明专利
    未知

    公开(公告)号:ID16040A

    公开(公告)日:1997-08-28

    申请号:ID970546

    申请日:1997-02-24

    Applicant: HOECHST AG

    Abstract: - Mixtures of optical brighteners contain (a) bisbenzoxazolyl(s) of formula (I) and/or 7-naphthoÄ1,2-dÜtriazol-2-yl-3-phenyl-coumarin of formula (II) and (b) beta -(benzoxazol-2-yl)-styrene(s) and/or 4-(benzoxazol-2-yl)-stilbene(s) of formula (III) as brighteners; in which R , R = hydrogen (H), 1-10 carbon (C) alkyl or carbo-(1-4 C)-alkoxy; X = 1,4-naphthylene, 2,5-thiophene or 2,5-furan; R = H, halogen, 1-4 C alkyl or phenyl in the 5-position and R = H; or R , R = methyl (Me) in the 5- and 6- or 5- and 7-position; n = 0 or 1; B = cyano, carbo-(1-4 C)-alkoxy or a group of the formulae; R = 1-6 C alkyl, 1-8 C cycloalkyl, 1-4 C alkoxy-(1-4 C)-alkyl, hydroxy-(1-4 C)-alkyl or -(CH2CH2O)n-R'; n = 2 or 3; R' = H or 1-4 C alkyl; R = phenyl, halophenyl, 1-4 C alkylphenyl or 1-4 C alkoxyphenyl; R = 1-4 C alkyl; R - cyano or carbo-(1-4 C)-alkoxy.

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