公开(公告)号：US3518250A

公开(公告)日：1970-06-30

申请号：US3518250D

申请日：1965-12-17

Applicant: IBM

Inventor： SCHUMAKER ROBERT R

IPC: C07D209/86 ,  C07D219/06 ,  C07B27/00

CPC classification number: C07D219/06 ,  C07D209/86

公开(公告)号：US3412138A

公开(公告)日：1968-11-19

申请号：US51469665

申请日：1965-12-17

Applicant: IBM

Inventor： SOLAR SAMUEL L ,  SCHUMAKER ROBERT R

IPC: C07C227/16

CPC classification number: C07C227/16

公开(公告)号：FR2377406A1

公开(公告)日：1978-08-11

申请号：FR7736920

申请日：1977-11-30

Applicant: IBM

Inventor： ENGLER EDWARD M ,  SCHUMAKER ROBERT R

IPC: C07D339/04 ,  C07D295/16 ,  C07D295/21 ,  C07D339/06 ,  C07D495/02 ,  C07D495/04 ,  C07D517/04 ,  C07D519/00

公开(公告)号：CA1155860A

公开(公告)日：1983-10-25

申请号：CA348150

申请日：1980-03-21

Applicant: IBM

Inventor： ENGLER EDWARD M ,  PATEL VISHNUBHAI V ,  SCHUMAKER ROBERT R

IPC: C07D339/06 ,  C07D339/08 ,  C07D345/00 ,  C07D409/04 ,  C07D409/14 ,  C07D495/04 ,  C07D343/00

Abstract: The invention is directed to novel heterofulvalence geminal dithioiate compounds and their selenium and tellurium analogs having the general formula Wherein X is selected from S, Se and Te. R is selected from hydrogen, alkyl, aryl, or together form a ring of carbon atoms, cyano and dithiocarbonate groups and R1 is selected from alkali, alkaline earth and transition metals, alkyl, aryl, cyclic and heterocyclic groups. A novel method for preparing these compounds is also provided.

公开(公告)号：CA1116174A

公开(公告)日：1982-01-12

申请号：CA299917

申请日：1978-03-29

Applicant: IBM

Inventor： ENGLER EDWARD M ,  NICHOLS KENNETH H ,  PATEL VISHNUBHAI V ,  RIVERA NILDA M ,  SCHUMAKER ROBERT R

IPC: C09K3/16 ,  C07F1/00 ,  C07F1/08 ,  C07F3/06 ,  C07F15/00 ,  C08G75/00 ,  C08G79/00 ,  C09D5/24 ,  C09D185/00 ,  C07D341/00

Abstract: HIGHLY CODUCTING ORGANOMETALLIC POLYMERS This specification discloses highly conducting organometallic polymers having units chosen from the following recurring units and where each M is same or different and is a multivalent metal, and method for preparing the above polymers.

公开(公告)号：CA1064043A

公开(公告)日：1979-10-09

申请号：CA292334

申请日：1977-12-05

Applicant: IBM

Inventor： ENGLER EDWARD M ,  SCHUMAKER ROBERT R

IPC: C07D339/04 ,  C07D295/16 ,  C07D295/21 ,  C07D339/06 ,  C07D495/02 ,  C07D495/04 ,  C07D517/04 ,  C07D519/00

Abstract: TETRATHIAPENTALENE AND TETRASELENAPENTTALENE COMPOUNDS This application is concerned with tetrathiapentalene and tetrasalenapentalene compounds. Specifically, it is concerned with 1, 3, 4, 6-tetrathia-2, 5-dihetexo-pentalene and 1, 3, 4, 6 tetraselena-2, 5-dihetero-pentalene compounds having the formula or wherein X is S or Se; each of Y1 and Y2 is O, S, or Se; each or Z1 and Z2 is -SR, SeR ox = N? wherein R and Rr are H, alkyl, aryl, or together form a ring of carbon atoms; and An is the anion of a strong acid. These compounds are key synthetic intermediates for the preparation of tetrathiafulvalene and tetraselenafulvalene materials, in the art of producing organic conductors.

公开(公告)号：FR2385760A1

公开(公告)日：1978-10-27

申请号：FR7805795

申请日：1978-02-23

Applicant: IBM

Inventor： ENGLER EDWARD M ,  NICHOLS KENNETH H ,  PATEL VISHNUBHAI V ,  RIVERA NILDA M ,  SCHUMAKER ROBERT R

IPC: C09K3/16 ,  C07F1/00 ,  C07F1/08 ,  C07F3/06 ,  C07F15/00 ,  C08G75/00 ,  C08G79/00 ,  C09D5/24 ,  C09D185/00 ,  C07D339/06 ,  H01B1/00

Abstract: HIGHLY CODUCTING ORGANOMETALLIC POLYMERS This specification discloses highly conducting organometallic polymers having units chosen from the following recurring units and where each M is same or different and is a multivalent metal, and method for preparing the above polymers.

公开(公告)号：CA793318A

公开(公告)日：1968-08-27

申请号：CA793318D

Applicant: IBM

Inventor： SCHUMAKER ROBERT R