2.
    发明专利
    未知

    公开(公告)号:DE2356958A1

    公开(公告)日:1974-08-29

    申请号:DE2356958

    申请日:1973-11-15

    Applicant: IBM

    Abstract: 1424252 Electro-plating tungsten-thorium alloy INTERNATIONAL BUSINESS MACHINES CORP 11 Oct 1973 [23 Feb 1973] 47439/73 Heading C7B [Also in Divisions G5 and H1] A thin-film alloy of W-Th is electro-plated on a substrate of which at least part is conductive from a heated aqueous solution containing WO 3 and Na 3 PO 4 , to which is gradually added aqueous Th(SO 4 ) 2 during plating. The basic substrate may be temporary, semitemporary or permanent. As described, a Cu layer 6 on Al 2 O 3 base 4, through which project electro-deposited Au pins 5 with their other ends flush with the Cu surface, is coated with a photo-resist to leave conductive paths 6' connecting pairs of posts 5. The W-Th alloy is deposited on 6' and the Cu etched away leaving the alloy supported on the posts in a form useful as part of a rectangular array of similar films in an incandescent filament character display device. Alternatively the entire Cu layer may be W-Th plated, a resist applied as before and the unwanted Cu and Th-W alloy etched, the latter with NaOH-K 3 Fe(CN) 6 . Plating conditions specified are a temperature of 80‹C, a c.d. of 160 mA/cm 2 for 10-30 mins, with addition of 20 drops/min of 10% w/w Th(SO 4 ) 2 solution. The alloy may be annealed to the single crystal state.

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