公开(公告)号：JP2010159418A

公开(公告)日：2010-07-22

申请号：JP2010023779

申请日：2010-02-05

Applicant: Board Of Trustees Of The Leland Stanford Junior Univ ,  Internatl Business Mach Corp ,  インターナショナル・ビジネス・マシーンズ・コーポレーションInternational Business Maschines Corporation ,  ザ ボード オブ トラスティーズ オブ ザ レランド スタンフォード ジュニア ユニバーシティー

Inventor： HEDRICK JAMES L ,  KILICKIRAN PINAR ,  NYCE GREGORY W ,  WAYMOUTH ROBERT M

IPC: C08J11/28 ,  B01J31/02 ,  B01J31/22 ,  C07C59/285 ,  C07C67/03 ,  C07C68/06 ,  C07D233/02 ,  C07D233/04 ,  C07D233/06 ,  C07D233/16 ,  C07D233/54 ,  C07D307/33 ,  C07F1/00

CPC classification number: C07D233/16 ,  C07C59/285 ,  C07C67/03 ,  C07C68/06 ,  C07D233/02 ,  C07D233/04 ,  C07D233/06 ,  C07D233/54 ,  C07D307/33 ,  C07F1/00 ,  C07C69/82 ,  C07C69/96

Abstract: PROBLEM TO BE SOLVED: To provide an improved method for carrying out depolymerization of a polymer. SOLUTION: The method is provided for carrying out depolymerization of the polymer containing an electrophilic linkage in the presence of a catalyst and a nucleophilic reagent, wherein production of undesirable byproducts resulting from polymer degradation is minimized. The reaction can be carried out at a temperature of 80°C or lower, and generally involves the use of an organic, nonmetallic catalyst, thereby ensuring that the depolymerization product(s) are substantially free of metal contaminants. In an exemplary depolymerization method, the catalyst is a carbene compound such as an N-heterocyclic carbene, or is a precursor to a carbene compound. The method provides an important alternative to current recycling techniques such as those used in the degradation of polyesters, polyamides, and the like. COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 要解决的问题：提供一种进行聚合物解聚的改进方法。 解决方案：该方法用于在催化剂和亲核试剂的存在下进行含有亲电键的聚合物的解聚，其中由聚合物降解产生的不期望的副产物的产生最小化。 反应可以在80℃或更低的温度下进行，通常涉及使用有机非金属催化剂，从而确保解聚产物基本上不含金属污染物。 在示例性的解聚方法中，催化剂是卡宾化合物如N-杂环卡宾，或是卡宾化合物的前体。 该方法提供了当前回收技术的重要替代方法，例如用于降解聚酯，聚酰胺等的那些。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：WO2004060987A3

公开(公告)日：2004-10-07

申请号：PCT/US0341283

申请日：2003-12-23

Applicant: IBM ,  UNIV LELAND STANFORD JUNIOR

Inventor： HEDRICK JAMES L ,  KILICKIRAN PINAR ,  NYCE GREGORY W ,  WAYMOUTH ROBERT M

IPC: C07C59/285 ,  C07C67/03 ,  C07C68/06 ,  C07D233/02 ,  C07D233/04 ,  C07D233/06 ,  C07D233/16 ,  C07D233/54 ,  C07D307/33 ,  C07F1/00 ,  C08J11/18 ,  B01J31/22

CPC classification number: C07D233/16 ,  C07C59/285 ,  C07C67/03 ,  C07C68/06 ,  C07D233/02 ,  C07D233/04 ,  C07D233/06 ,  C07D233/54 ,  C07D307/33 ,  C07F1/00 ,  C07C69/82 ,  C07C69/96

Abstract: A method is provided for carrying out depolymerization of a polymer containing electrophilic linkages in the presence of a catalyst and a nucleophilic reagent, wherein production of undesirable byproducts resulting from polymer degradation is minimized. The reaction can be carried out at a temperature of 80°C or less, and generally involves the use of an organic, nonmetallic catalyst, thereby ensuring that the deploymerization product(s) aer substantially free of metal contaminants. In an exemplary depolymerization method, the catalyst is a carbene compound such as an N-heterocyclic carbene, or is a precursor to a carbene compound. The method provides an important alternative to current recycling techniques such as those used in the degradation of polyesters, polyamides, and the like.

Abstract translation: 提供了一种在催化剂和亲核试剂的存在下进行含有亲电键的聚合物解聚的方法，其中由聚合物降解产生的不需要的副产物的产生最小化。 反应可以在80℃或更低的温度下进行，通常涉及使用有机非金属催化剂，从而确保基本上不含金属污染物的配位产品。 在示例性的解聚方法中，催化剂是卡宾化合物如N-杂环卡宾，或是卡宾化合物的前体。 该方法提供了当前回收技术的重要替代方法，例如用于降解聚酯，聚酰胺等的那些。

公开(公告)号：AU2003299913A8

公开(公告)日：2004-07-29

申请号：AU2003299913

申请日：2003-12-23

Applicant: IBM ,  UNIV LELAND STANFORD JUNIOR

Inventor： HEDRICK JAMES L ,  KILICKIRAN PINAR ,  NYCE GREGORY W ,  WAYMOUTH ROBERT M

IPC: C07C59/285 ,  C07C67/03 ,  C07C68/06 ,  C07D233/02 ,  C07D233/04 ,  C07D233/06 ,  C07D233/16 ,  C07D233/54 ,  C07D307/33 ,  C07F1/00 ,  C08J11/10

Abstract: A method is provided for carrying out depolymerization of a polymer containing electrophilic linkages in the presence of a catalyst and a nucleophilic reagent, wherein production of undesirable byproducts resulting from polymer degradation is minimized. The reaction can be carried out at a temperature of 80° C. or less, and generally involves the use of an organic, nonmetallic catalyst, thereby ensuring that the depolymerization product(s) are substantially free of metal contaminants. In an exemplary depolymerization method, the catalyst is a carbene compound such as an N-heterocyclic carbene, or is a precursor to a carbene compound. The method provides an important alternative to current recycling techniques such as those used in the degradation of polyesters, polyamides, and the like.

公开(公告)号：AU2003299913A1

公开(公告)日：2004-07-29

申请号：AU2003299913

申请日：2003-12-23

Applicant: IBM

Inventor： HEDRICK JAMES L ,  KILICKIRAN PINAR ,  NYCE GREGORY W ,  WAYMOUTH ROBERT M

IPC: C07C59/285 ,  C07C67/03 ,  C07C68/06 ,  C07D233/02 ,  C07D233/04 ,  C07D233/06 ,  C07D233/16 ,  C07D233/54 ,  C07D307/33 ,  C07F1/00 ,  C08J11/10

Abstract: A method is provided for carrying out depolymerization of a polymer containing electrophilic linkages in the presence of a catalyst and a nucleophilic reagent, wherein production of undesirable byproducts resulting from polymer degradation is minimized. The reaction can be carried out at a temperature of 80° C. or less, and generally involves the use of an organic, nonmetallic catalyst, thereby ensuring that the depolymerization product(s) are substantially free of metal contaminants. In an exemplary depolymerization method, the catalyst is a carbene compound such as an N-heterocyclic carbene, or is a precursor to a carbene compound. The method provides an important alternative to current recycling techniques such as those used in the degradation of polyesters, polyamides, and the like.