公开(公告)号：WO2013077989A1

公开(公告)日：2013-05-30

申请号：PCT/US2012/063310

申请日：2012-11-02

Applicant: ICL-IP AMERICA INC.

Inventor： ZILBERMAN, Joseph ,  LEE, Julia ,  LEVCHIK, Sergei, V. ,  YANG, Yankai

IPC: C07F9/40 ,  C08K5/5333 ,  C09K21/12

CPC classification number: C09K21/12 ,  C07F9/4006 ,  C07F9/4021 ,  C07F9/5407 ,  C07F9/5442 ,  C08K5/5317 ,  C08K5/5333

Abstract: There is provided herein a process for the preparation of aluminum salts of phosphonic acid esters by reacting phosphonic acid diesters with aluminum hydroxide in the presence of a catalyst. The catalyst is selected from the group consisting of a phase transfer catalyst, a thermally stable tertiary amine having a boiling point higher than about 140°C, a thermally stable tertiary phosphine having a boiling point higher than 140°C and combinations thereof. The aluminum phosphonates prepared can be used for making flame retarded thermoplastic polymers.

Abstract translation: 本文提供了在催化剂存在下使膦酸二酯与氢氧化铝反应制备膦酸酯的铝盐的方法。 催化剂选自相转移催化剂，沸点高于约140℃的热稳定叔胺，沸点高于140℃的热稳定叔膦及其组合。 所制备的膦酸铝可用于制备阻燃热塑性聚合物。