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1.发明授权公开(公告)号：US10596560B2
公开(公告)日：2020-03-24
申请号：US14909637
申请日：2014-06-30
Applicant: IFP Energies nouvelles
Inventor： Matthieu Lagauche , Laure Brandhorst , Christophe Bouchy
IPC: B01J29/06 , B01J29/74 , B01J37/00 , C07C5/27 , B01J29/72 , C01B39/02 , B01J29/70 , C10G45/64 , C10G45/62 , B01J29/76 , B01J29/78 , B01J29/04 , B01J35/10 , B01J35/02 , B01J35/00
Abstract: A process is described for preparing a catalyst comprising at least one zeolite with a modified EUO structure type, at least one matrix and at least one metal from group VIII of the periodic classification of the elements. Said catalyst is used in a process for the isomerization of an aromatic feed comprising at least one compound containing eight carbon atoms per molecule.
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2.发明授权公开(公告)号：US09546329B2
公开(公告)日：2017-01-17
申请号：US13661183
申请日：2012-10-26
Applicant: ENI S.P.A. , IFP ENERGIES NOUVELLES
Inventor： Christophe Bouchy , Aline Grezaud , Jean Philippe Heraud , Hugues Dulot , Vincenzo Calemma
CPC classification number: C10G65/12 , B01J21/12 , B01J23/42 , B01J23/44 , B01J35/0066 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/108 , B01J37/0009 , C10G65/043 , C10G2300/1022 , C10G2300/1081 , C10G2300/202 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2300/42 , C10G2400/04 , C10G2400/06 , C10G2400/08
Abstract: A process for the production of middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis comprising a limited content of molecules containing at least one oxygen atom. In the process, the feedstock is subjected to at least one hydrocracking/hydroisomerization stage in the presence of a hydrogen stream also containing a limited atomic oxygen content.
Abstract translation: 由费 - 托合成生产的石蜡原料生产中间馏分的方法，其包含含有至少一个氧原子的有限含量的分子。 在该方法中，原料在还含有有限原子氧含量的氢气流的存在下进行至少一个加氢裂化/加氢异构化阶段。
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3.发明授权Process for conversion of paraffinic feedstocks obtained from the biomass of middle distillate bases employing at least one IZM-2 zeolite-based catalyst 有权使用至少一种IZM-2沸石基催化剂从中间馏分碱的生物质获得的石蜡原料的转化方法公开(公告)号：US09156748B2
公开(公告)日：2015-10-13
申请号：US13723580
申请日：2012-12-21
Applicant: IFP ENERGIES NOUVELLES
Inventor： Christophe Bouchy , Emmanuelle Guillon , Filipe Manuel Marques Mota
CPC classification number: C07C5/226 , B01J29/72 , B01J29/74 , B01J29/78 , B01J2229/20 , B01J2229/42 , C10G3/46 , C10G3/47 , C10G45/62 , C10G45/64 , Y02P30/20
Abstract: The invention relates to a process for conversion of a paraffinic feedstock that has a number of carbon atoms of between 9 and 25, whereby said paraffinic feedstock is produced starting from renewable resources, employing a catalyst that comprises at least one hydrogenating-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table, taken by themselves or in a mixture, and a substrate that comprises at least one IZM-2 zeolite and at least one binder, with said process being carried out at a temperature of between 150 and 500° C., at a pressure of between 0.1 MPa and 15 MPa, at an hourly volumetric flow rate of between 0.1 and 10 h−1, and in the presence of a total quantity of hydrogen mixed with the feedstock such that the hydrogen/feedstock ratio is between 70 and 2,000 Nm3/m3 of feedstock.
Abstract translation: 本发明涉及一种转化石蜡原料的方法，该方法具有9至25个碳原子，其中所述链烷烃原料是从可再生资源开始生产的，该催化剂包含至少一种氢化脱氢金属 选自由本身或混合物中的VIB族和VIII族的金属形成的基团，以及包含至少一种IZM-2沸石和至少一种粘合剂的基材，所述方法 在0.1〜15MPa的压力下，以0.1〜10h -1的小时体积流量，在150〜500℃的温度下进行，在总量为 氢气与原料混合，使氢/原料比为70至2,000 Nm3 / m3的原料。
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4.发明授权Method of hydrocracking and oligomerizing a paraffinic product of Fischer-Tropsch synthesis using a dispersed zeolite beta based catalyst 有权使用分散的沸石β型催化剂加氢裂化和低聚Fischer-Tropsch合成链烷烃产物的方法公开(公告)号：US09051520B2
公开(公告)日：2015-06-09
申请号：US13661338
申请日：2012-10-26
Applicant: UNIVERSITE DE POITIERS , C.N.R.S. , IFP Energies nouvelles
Inventor： Nuno Miguel Rocha Batalha , Ludovic Pinard , Francisco Manuel Da Silva Lemos , Fernando Manuel Ramoa Ribeiro , Emmanuelle Guillon , Christophe Bouchy
IPC: C10G47/18 , C10G47/20 , B01J35/10 , B01J29/72 , B01J29/70 , B01J29/76 , B01J29/74 , B01J29/78 , B01J35/02
CPC classification number: C10G47/18 , B01J29/7007 , B01J29/7215 , B01J29/7415 , B01J29/7615 , B01J29/7815 , B01J35/023 , B01J35/1038 , B01J2229/20 , B01J2229/42 , B01J2229/64 , C10G47/20 , C10G2300/1022 , C10G2400/04
Abstract: A process for the production of middle distillates comprising at least one hydrocracking stage that oligomerizes a paraffinic feedstock produced by Fischer-Tropsch synthesis, the process using a catalyst that comprises at least one hydrogenating-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table, by themselves or in a mixture, and a substrate that comprises a beta zeolite in the form of crystallites with a mean size that is less than 100 nm dispersed in at least one porous mineral matrix, whereby the beta zeolite has a mesopore volume of less than 0.4 ml/g.
Abstract translation: 一种生产中间馏分的方法，其包括至少一个加氢裂化阶段，该加氢裂化阶段使由费 - 托合成产生的链烷烃原料低聚，该方法使用包含至少一种氢化脱氢金属的催化剂，所述催化剂选自由 元素周期表第VIB族和第VIII族的金属本身或混合物，以及底物，其包含分散在至少一种多孔矿物中的平均粒度小于100nm的微晶形式的β沸石 基质，其中β沸石的中孔体积小于0.4ml / g。
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公开(公告)号：US12146111B2
公开(公告)日：2024-11-19
申请号：US17785197
申请日：2020-12-09
Applicant: IFP Energies Nouvelles
Inventor： Christophe Bouchy
Abstract: Process for isomerization of paraffinic feedstocks operating at a temperature of between 200° C. and 500° C., at a total pressure of between 0.45 MPa and 7 MPa, at a partial pressure of hydrogen of between 0.3 and 5.5 MPa, at an hourly space velocity of between 0.1 and 10 kg of feedstock introduced per kg of catalyst and per hour, using a catalyst having at least one group VIII metal, at least one matrix and at least one IZM-2 zeolite, the total weight content of alkali metal and/or alkaline-earth metal elements is less than 200 ppm by weight relative to the total mass of said catalyst.
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Patent Agency Ranking
6.发明授权公开(公告)号：US09353320B2
公开(公告)日：2016-05-31
申请号：US13860850
申请日：2013-04-11
Applicant: ENI S.p.A. , IFP Energies nouvelles
Inventor： Aline Grezaud , Jean Philippe Heraud , Hugues Dulot , Christophe Bouchy , Vincenzo Calemma
IPC: C10G65/12 , C07C1/04 , C07C1/12 , B01J21/12 , B01J23/42 , B01J23/44 , B01J23/75 , B01J23/755 , B01J23/882 , B01J23/883 , B01J23/888 , B01J35/00 , B01J35/10 , B01J37/00 , B01J37/02 , C10G65/02 , C07C27/06 , C07C27/08 , C10G45/00 , C10G45/02
CPC classification number: C10G65/12 , B01J21/12 , B01J23/42 , B01J23/44 , B01J23/75 , B01J23/755 , B01J23/882 , B01J23/883 , B01J23/888 , B01J23/8885 , B01J35/0026 , B01J35/0066 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J37/0009 , B01J37/0201 , C07C1/0495 , C07C1/12 , Y02P20/52 , C07C9/04
Abstract: A method for producing middle distillates from a feedstock produced by Fischer-Tropsch synthesis and containing oxygenated compounds, including: a) a step of bringing the feedstock into contact with a hydrotreating catalyst allowing the methanation of the CO and CO2 contained in the feedstock or originating from the decomposition of the oxygenated compounds present in the feedstock, b) a step of hydroisomerization/hydrocracking of at least a part of the liquid and gaseous effluent originating from step a), in the presence of a hydroisomerization/hydrocracking catalyst, c) a step of gas/liquid separation of the effluent originating from step b) into a gaseous fraction comprising predominantly hydrogen and a hydroisomerized/hydrocracked liquid fraction, d) a step of fractionation of the liquid fraction separated in step c) to obtain at least one fraction of middle distillate, in which the hydrogen in step a) is obtained from the gaseous fraction separated in step c).
Abstract translation: 由费 - 托合成生产并含有氧化化合物的原料生产中间馏分的方法，包括：a）使原料与加氢处理催化剂接触的步骤，允许原料中所含的CO和CO 2的甲烷化或起始 来自原料中存在的含氧化合物的分解，b）在加氢异构化/加氢裂化催化剂存在下，来自步骤a）的至少一部分液体和气态流出物的加氢异构化/加氢裂化步骤，c） 将来自步骤b）的流出物气/液分离成主要包含氢气和加氢异构化/加氢裂化的液体馏分的气体馏分的步骤，d）在步骤c）中分离的液体馏分的分级步骤，以获得至少一个馏分 的中间馏分，其中步骤a）中的氢气是从步骤c）中分离的气体馏分得到的。
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公开(公告)号：US10906030B2
公开(公告)日：2021-02-02
申请号：US16212160
申请日：2018-12-06
Applicant: IFP Energies nouvelles
Inventor： Christophe Bouchy
IPC: B01J29/06 , B01J29/70 , B01J23/42 , B01J23/44 , B01J21/04 , B01J37/02 , C10G45/64 , B01J29/76 , B01J29/74 , B01J37/00 , B01J29/78 , C07C5/27
Abstract: The present invention relates to a process for preparing a difunctional catalyst using a zeolite IZM-2, a hydrogenating function and a matrix. The preparation process according to the invention simultaneously allows preferential localization of said hydrogenating function on the surface and/or in the microporosity of zeolite IZM-2 and homogeneous distribution of the hydrogenating function in the catalyst and preferably on zeolite IZM-2 by means of using an impregnation solution comprising specific noble metal precursors combined with the presence of ammonium salts, with a quite precise ratio of ammonium salt to noble metal.
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公开(公告)号：US10183902B2
公开(公告)日：2019-01-22
申请号：US15658900
申请日：2017-07-25
Applicant: IFP Energies Nouvelles
Inventor： Christophe Bouchy
Abstract: A catalyst is described comprising at least one IZM-2 zeolite containing silicon atoms and aluminum atoms, at least one matrix and at least one metal from group VIII of the periodic classification of the elements, the zeolite having a ratio between the number of moles of silicon and the number of moles of aluminum in the range 60 to 150. Said catalyst is used in a process for the isomerization of an aromatic feed comprising at least one compound containing eight carbon atoms per molecule.
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公开(公告)号：US10851030B2
公开(公告)日：2020-12-01
申请号：US16440272
申请日：2019-06-13
Applicant: IFP Energies nouvelles
Inventor： Christophe Bouchy
Abstract: The present invention describes a process for the isomerization of paraffinic feedstocks operating at a temperature of between 200° C. and 500° C., at a total pressure of between 0.45 MPa and 7 MPa, at a hydrogen partial pressure of between 0.3 and 5.5 MPa, at an hourly space velocity of between 0.1 and 10 kilograms of feedstock introduced per kilogram of catalyst and per hour and using a catalyst comprising at least one metal of group VIII of the periodic table of elements, at least one matrix and at least one zeolite IZM-2, in which the ratio between the number of moles of silicon and the number of moles of aluminium of the zeolite IZM-2 network is between 25 and 55, preferably between 25 and 50, and preferably between 30 and 50.
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公开(公告)号：US10793791B2
公开(公告)日：2020-10-06
申请号：US16513819
申请日：2019-07-17
Applicant: IFP Energies Nouvelles
Inventor： Jean-Philippe Heraud , Christophe Bouchy
Abstract: A process is described for producing middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis and divided into a light fraction (cold condensate) and a heavy fraction (waxes). The process involves fractionation of the waxes to obtain a light fraction, the final boiling point of which is between 350° C. and 400° C., and a heavy fraction which boils above the light fraction. The light fraction is mixed with at least one portion of the cold condensate. The resultant mixture is hydrotreated in the presence of a hydrotreatment catalyst of at least one portion of the resultant effluent is hydroisomerized in the presence of a catalyst comprising at least one noble metal from Group VIII and at least one zeolite IZM-2. At least one portion of the heavy fraction is subjected to hydrocracking and hydroisomerization in the presence of a hydrocracking catalyst. The resultant effluents are fractionated to obtain at least one middle distillates fraction.
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