Abstract:
A process for hydrocracking hydrocarbon-containing VD feedstocks allowing the improved production of middle distillates: a) hydrocracking of feedstocks in hydrogen and at least one hydrocracking catalyst, b) gas/liquid separation of effluent originating from a) producing a liquid effluent and a gaseous effluent with hydrogen, c) comprising the gaseous effluent before recycling into hydrocracking a), d) fractionation of liquid effluent into at least one effluent of converted hydrocarbon-containing products having boiling points less than 340° C. and an unconverted liquid fraction having a boiling point greater than 340° C., e) hydrocracking unconverted liquid fraction from d), in hydrogen and a hydrocracking catalyst, f) hydrotreating effluent from e) in a mixture with a hydrocarbon-containing gas-oil liquid feedstock having at least 95% by weight of compounds boiling at a boiling point between 150 and 400° C., hydrotreating f) operating in hydrogen and with at least one hydrotreating catalyst.
Abstract:
The invention relates to a process for transformation of lignocellulosic biomass or cellulose using in a simultaneous manner an original combination of at least two homogeneous catalysts and one or more heterogeneous catalyst(s). The use of these catalysts makes it possible to obtain mono-oxidized or poly-oxidized upgradable products directly and to limit the formation of non-upgradable products. Non-upgradable products are defined as soluble and non-soluble humins, i.e., products of high molecular weight obtained from undesirable condensation reactions of sugars and their derivatives.
Abstract:
The invention relates to a process for conversion of a paraffinic feedstock that has a number of carbon atoms of between 9 and 25, whereby said paraffinic feedstock is produced starting from renewable resources, employing a catalyst that comprises at least one hydrogenating-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table, taken by themselves or in a mixture, and a substrate that comprises at least one IZM-2 zeolite and at least one binder, with said process being carried out at a temperature of between 150 and 500° C., at a pressure of between 0.1 MPa and 15 MPa, at an hourly volumetric flow rate of between 0.1 and 10 h−1, and in the presence of a total quantity of hydrogen mixed with the feedstock such that the hydrogen/feedstock ratio is between 70 and 2,000 Nm3/m3 of feedstock.
Abstract:
The invention relates to a catalyst comprising at least one metal selected from the group formed by metals of group VIB and of group VIII of the periodic table, used alone or as a mixture, and a support comprising at least one zeolite NU-86, at least one zeolite Y and at least one porous mineral matrix containing at least aluminium and/or at least silicon. The invention also relates to a process for hydrocracking of hydrocarbon feeds employing said catalyst.
Abstract:
A process for the production of middle distillates comprising at least one hydrocracking stage that oligomerizes a paraffinic feedstock produced by Fischer-Tropsch synthesis, the process using a catalyst that comprises at least one hydrogenating-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table, by themselves or in a mixture, and a substrate that comprises a beta zeolite in the form of crystallites with a mean size that is less than 100 nm dispersed in at least one porous mineral matrix, whereby the beta zeolite has a mesopore volume of less than 0.4 ml/g.
Abstract:
The invention relates to a method of preparing a catalyst comprising a) preparation of a support comprising 0.2 to 30 wt % of zeolite NU-86 and from 70 to 99.8 wt % of a porous mineral matrix, the percentages by weight being expressed relative to the total weight of said support, b) impregnation of the support prepared according to step a) with at least one solution containing at least one precursor of at least one metal selected from group VIII metals and group VIB metals, used alone or as a mixture, c) at least one ripening step, and d) at least one drying step carried out at a temperature below 150° C., without a subsequent calcining step. The present invention also relates to a process for hydrocracking hydrocarbon feeds using the catalyst prepared according to the method of preparation according to the invention.
Abstract:
The present invention is based on the use of a two-step hydrocracking process for the production of naphtha, comprising a step of hydrogenation placed downstream of the second hydrocracking step, the hydrogenation step treating the effluent resulting from the second hydrocracking step in the presence of a specific hydrogenation catalyst. Furthermore, the hydrogenation step and the second hydrocracking step are performed under specific operating conditions and in particular under quite specific temperature conditions.
Abstract:
The invention concerns a catalyst comprising at least one zeolite with structure type MTW, a matrix, at least one metal from group VIII of the periodic classification of the elements, said catalyst having a mesopore volume increased by at least 10% compared with its initial mesopore volume, which is generally in the range 0.55 to 0.75 mL/g, at the end of a treatment with steam at a partial pressure in the range 0.01 to 0.07 MPa and at a temperature in the range 300° C. to 400° C. for at least 0.5 hour. The invention concerns the process for the preparation of said catalyst as well as an isomerization process employing said catalyst.
Abstract:
The invention concerns a process for the transformation of lignocellulosic biomass or cellulose into mono- or poly-oxygenated compounds, in which the lignocellulosic biomass or the cellulose is brought into simultaneous contact with a catalytic system comprising a combination of one or more homogeneous catalysts and one or more heterogeneous catalysts, in the same reaction chamber, in the presence of at least one solvent, said solvent being water alone or as a mixture with at least one other solvent, in a reducing atmosphere, and at a temperature in the range 80° C. to 250° C. and at a pressure in the range 0.5 MPa to 20 MPa.
Abstract:
The invention relates to a method of preparing a catalyst comprising a) preparation of a support comprising 0.2 to 30 wt % of zeolite NU-86 and from 70 to 99.8 wt % of a porous mineral matrix, the percentages by weight being expressed relative to the total weight of said support, b) impregnation of the support prepared according to step a) with at least one solution containing at least one precursor of at least one metal selected from group VIII metals and group VIB metals, used alone or as a mixture, c) at least one ripening step, and d) at least one drying step carried out at a temperature below 150° C., without a subsequent calcining step. The present invention also relates to a process for hydrocracking hydrocarbon feeds using the catalyst prepared according to the method of preparation according to the invention.