公开(公告)号：WO2015138019A1

公开(公告)日：2015-09-17

申请号：PCT/US2014/069535

申请日：2014-12-10

Applicant: IMRA AMERICA,INC.

Inventor： TAN, Bing ,  HU, Zhendong ,  HE, Guanghui ,  CHE, Yong

IPC: H01M4/48

CPC classification number: H01M4/485 ,  H01M10/052 ,  H01M2004/021 ,  H01M2004/027

Abstract: The described embodiments provide an energy storage device that includes a positive electrode including an active material that can store and release ions, a negative electrode including a V, Nb co-doped TiO 2 (B), and a non-aqueous electrolyte including lithium ions. At least one embodiment provides a negative electrode active material including V, Nb co-doped TiO 2 (B). At least one embodiment provides a wet-chemistry process to prepare V, Nb co-doped TiO 2 (B).

Abstract translation: 所描述的实施例提供了一种能量存储装置，其包括包括可以存储和释放离子的活性材料的正极，包括V，Nb共掺杂TiO 2（B）的负极和包含锂离子的非水电解质。 至少一个实施方案提供了包括V，Nb共掺二氧化钛（B）的负极活性材料。 至少一个实施方案提供了制备V，Nb共掺杂TiO 2（B）的湿化学方法。

公开(公告)号：WO2013138541A1

公开(公告)日：2013-09-19

申请号：PCT/US2013/031119

申请日：2013-03-14

Applicant: IMRA AMERICA, INC.

Inventor： TAN, Bing ,  HU, Zhendong ,  HE, Guanghui ,  CHE, Yong

IPC: H01M4/02

CPC classification number: H01G11/30 ,  H01G11/50 ,  H01M4/362 ,  H01M4/366 ,  H01M4/5825 ,  H01M4/625 ,  H01M10/36 ,  H01M12/08 ,  Y02E60/128 ,  Y02E60/13

Abstract: Various embodiments of the present invention relate to electrode materials based on iron phosphates that can be used as the negative electrode materials for aqueous sodium ion batteries and electrochemical capacitors. At least one embodiment includes a negative electrode material for an aqueous sodium ion based energy storage device. The negative electrode material with a non-olivine crystal structure includes at least one phosphate selected from iron hydroxyl phosphate, Na 3 Fe 3 (PO 4 ) 4 , Na 3 Fe(PO 4 ) 2 , iron phosphate hydrate, ammonium iron phosphate hydrate, carbon-coated or carbon-mixed sodium iron phosphate. At least one embodiment includes an energy storage device that includes such a negative electrode material.

Abstract translation: 本发明的各种实施方案涉及可用作钠盐水溶液和电化学电容器的负极材料的基于磷酸铁的电极材料。 至少一个实施方案包括用于钠盐水溶液的能量储存装置的负极材料。 具有非橄榄石晶体结构的负极材料包括选自磷酸铁，Na 3 Fe 3（PO 4）4，Na 3 Fe（PO 4）2，磷酸铁水合物，磷酸铁铵水合物，碳涂覆或碳混合物中的至少一种磷酸盐 磷酸铁钠 至少一个实施例包括包括这种负极材料的能量存储装置。

公开(公告)号：WO2014133754A1

公开(公告)日：2014-09-04

申请号：PCT/US2014/015915

申请日：2014-02-12

Applicant: IMRA AMERICA, INC.

Inventor： TAN, Bing ,  HU, Zhendong ,  HE, Guanghui ,  CHE, Yong

IPC: H01M6/42

CPC classification number: H01M4/485 ,  B82Y30/00 ,  C01G23/053 ,  C01G23/0536 ,  C01P2002/30 ,  C01P2002/32 ,  C01P2002/50 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2004/80 ,  C01P2006/40 ,  H01G11/06 ,  H01G11/32 ,  H01G11/46 ,  H01G11/86 ,  H01M4/366 ,  H01M4/625 ,  H01M10/0525 ,  Y02E60/13

Abstract: The described embodiments provide an energy storage device that includes a positive electrode including a material that stores and releases ion, a negative electrode including Nb-doped TiO 2 (B), and a non-aqueous electrolyte containing lithium ions. The described embodiments provide a method including the steps of combining at least one titanium compound and at least one niobium compound in ethylene glycol to form a precursor solution, adding water into the precursor solution to induce hydrolysis and condensation reactions, thereby forming a reaction solution, heating the reaction solution to form crystallized particles, collecting the particles, drying the collected particles, and applying a thermal treatment at a temperature > 350°C to the dried particles to obtain Nb-doped TiO 2 (B) particles.

Abstract translation: 所描述的实施例提供了一种能量存储装置，其包括包括存储和释放离子的材料的正极，包含掺杂Nb的TiO 2（B）的负极和包含锂离子的非水电解质。 所描述的实施方案提供了一种方法，包括以下步骤：将至少一种钛化合物和至少一种铌化合物在乙二醇中混合以形成前体溶液，向前体溶液中加入水以引发水解和缩合反应，由此形成反应溶液， 加热反应溶液以形成结晶颗粒，收集颗粒，干燥收集的颗粒，并在温度> 350℃下对干燥颗粒进行热处理以获得掺杂Nb的TiO 2（B）颗粒。

公开(公告)号：WO2014099517A1

公开(公告)日：2014-06-26

申请号：PCT/US2013/074258

申请日：2013-12-11

Applicant: IMRA AMERICA, INC.

Inventor： TAN, Bing ,  HU, Zhendong ,  HE, Guanghui ,  CHE, Yong

IPC: H01M4/13 ,  H01M6/04 ,  H01G9/00

CPC classification number: H01G11/46 ,  H01G11/06 ,  H01G11/50 ,  H01G11/86 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/364 ,  H01M4/485 ,  H01M4/62 ,  H01M4/625 ,  H01M10/0525 ,  H01M2004/021 ,  Y02E60/13

Abstract: The described embodiments provide an energy storage device that includes a positive electrode including an active material that can store and release ions, a negative electrode including an active material that is a lithiated nano-architectured active material including tin and at least one stress-buffer component, and a non-aqueous electrolyte including lithium. The negative electrode active material is nano-architectured before lithiation.

Abstract translation: 所描述的实施例提供了一种能量存储装置，其包括包括能够存储和释放离子的活性材料的正电极，包含活性材料的负极，所述活性材料是包含锡的锂化纳米结构的活性材料和至少一种应力缓冲组分 和包含锂的非水电解质。 在锂化之前，负极活性物质是纳米结构的。