公开(公告)号：WO2012125389A2

公开(公告)日：2012-09-20

申请号：PCT/US2012/028184

申请日：2012-03-08

Applicant: IMRA AMERICA, INC. ,  TAN, Bing ,  HU, Zhendong ,  CHE, Yong

Inventor： TAN, Bing ,  HU, Zhendong ,  CHE, Yong

IPC: H01M4/52 ,  H01M4/485 ,  H01B1/04 ,  H01M4/04 ,  H01B1/12 ,  H01B1/02 ,  B05D5/00 ,  B05D3/02 ,  B82Y30/00

CPC classification number: B82Y30/00 ,  H01B1/04 ,  H01B1/08 ,  H01M4/366 ,  H01M4/48 ,  H01M4/483 ,  H01M4/485 ,  H01M4/58 ,  H01M4/587 ,  H01M4/62 ,  H01M4/624

Abstract: At least one embodiment of the present invention provides preparation methods and compositions for nanoarchitectured multi-component materials based on carboncoated iron-molybdenum mixed oxide as the electrode material for energy storage devices. A sol-gel process containing soluble organics is a preferred method. The soluble organics could become a carbon coating for the mixed oxide after thermal decomposition. The existence of the carbon coating provides the mixed oxide with an advantage in cycling stability over the corresponding carbon-free mixed oxide. For the carbon-coated mixed oxide, a stable cycling stability at high charge/discharge rate (3A/g) can be obtained with Mo/Fe molar ratios ≥ 1/3. The cycling stability and rate capability could be tuned by incorporating a structural additive such as Al 2 O 3 and a conductive additive such as carbon nanotubes. The high rate performance of the multi-component material has been demonstrated in a full device with porous carbons as the positive electrode material.

Abstract translation: 本发明的至少一个实施方案提供了基于碳涂覆的铁 - 钼混合氧化物作为储能装置的电极材料的纳米结构多组分材料的制备方法和组合物。 含有可溶性有机物的溶胶 - 凝胶法是优选的方法。 热分解后，可溶性有机物可能成为混合氧化物的碳涂层。 碳涂层的存在为混合氧化物提供了在相应的无碳混合氧化物上的循环稳定性的优点。 对于碳涂复合氧化物，当Mo / Fe摩尔比= 1/3时，可以获得高充电/放电速率（3A / g）下的稳定的循环稳定性。 循环稳定性和速率能力可以通过结合诸如Al 2 O 3的结构添加剂和诸如碳纳米管的导电添加剂来调节。 在具有多孔碳的正极材料的完整装置中已经证明了多组分材料的高速率性能。

公开(公告)号：WO2015138019A1

公开(公告)日：2015-09-17

申请号：PCT/US2014/069535

申请日：2014-12-10

Applicant: IMRA AMERICA,INC.

Inventor： TAN, Bing ,  HU, Zhendong ,  HE, Guanghui ,  CHE, Yong

IPC: H01M4/48

CPC classification number: H01M4/485 ,  H01M10/052 ,  H01M2004/021 ,  H01M2004/027

Abstract: The described embodiments provide an energy storage device that includes a positive electrode including an active material that can store and release ions, a negative electrode including a V, Nb co-doped TiO 2 (B), and a non-aqueous electrolyte including lithium ions. At least one embodiment provides a negative electrode active material including V, Nb co-doped TiO 2 (B). At least one embodiment provides a wet-chemistry process to prepare V, Nb co-doped TiO 2 (B).

Abstract translation: 所描述的实施例提供了一种能量存储装置，其包括包括可以存储和释放离子的活性材料的正极，包括V，Nb共掺杂TiO 2（B）的负极和包含锂离子的非水电解质。 至少一个实施方案提供了包括V，Nb共掺二氧化钛（B）的负极活性材料。 至少一个实施方案提供了制备V，Nb共掺杂TiO 2（B）的湿化学方法。

公开(公告)号：WO2012074622A1

公开(公告)日：2012-06-07

申请号：PCT/US2011/057562

申请日：2011-10-25

Applicant: IMRA AMERICA, INC ,  TAN, Bing ,  HU, Zhengdong ,  CHE, Yong

Inventor： TAN, Bing ,  HU, Zhengdong ,  CHE, Yong

IPC: H01M4/13

CPC classification number: H01M12/02 ,  H01G11/02 ,  H01G11/06 ,  H01G11/46 ,  H01G11/54 ,  H01M4/8605 ,  H01M4/90 ,  H01M4/9016 ,  H01M4/9041 ,  H01M12/08 ,  H01M14/00 ,  H01M16/00 ,  H01M16/003 ,  H01M16/006 ,  H01M2220/20 ,  H01M2220/30 ,  Y02E60/128 ,  Y02E60/13 ,  Y02E60/50 ,  Y02T10/7022

Abstract: A rechargeable energy storage device is disclosed. In at least one embodiment the energy storage device includes an air electrode providing an electrochemical process comprising reduction and evolution of oxygen and a capacitive electrode enables an electrode process consisting of non-faradic reactions based on ion absorption/desorption and/or faradic reactions. This rechargeable energy storage device is a hybrid system of fuel cells and ultracapacitors, pseudocapacitors, and/or secondary batteries.

Abstract translation: 公开了一种可再充电能量存储装置。 在至少一个实施例中，能量存储装置包括空气电极，其提供包括氧的还原和释放的电化学过程，并且电容电极能够实现由基于离子吸收/解吸和/或法拉第反应的非法拉第反应组成的电极过程。 该可再充电能量存储装置是燃料电池和超级电容器，假电容器和/或二次电池的混合系统。

公开(公告)号：WO2014133754A1

公开(公告)日：2014-09-04

申请号：PCT/US2014/015915

申请日：2014-02-12

Applicant: IMRA AMERICA, INC.

Inventor： TAN, Bing ,  HU, Zhendong ,  HE, Guanghui ,  CHE, Yong

IPC: H01M6/42

CPC classification number: H01M4/485 ,  B82Y30/00 ,  C01G23/053 ,  C01G23/0536 ,  C01P2002/30 ,  C01P2002/32 ,  C01P2002/50 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2004/80 ,  C01P2006/40 ,  H01G11/06 ,  H01G11/32 ,  H01G11/46 ,  H01G11/86 ,  H01M4/366 ,  H01M4/625 ,  H01M10/0525 ,  Y02E60/13

Abstract: The described embodiments provide an energy storage device that includes a positive electrode including a material that stores and releases ion, a negative electrode including Nb-doped TiO 2 (B), and a non-aqueous electrolyte containing lithium ions. The described embodiments provide a method including the steps of combining at least one titanium compound and at least one niobium compound in ethylene glycol to form a precursor solution, adding water into the precursor solution to induce hydrolysis and condensation reactions, thereby forming a reaction solution, heating the reaction solution to form crystallized particles, collecting the particles, drying the collected particles, and applying a thermal treatment at a temperature > 350°C to the dried particles to obtain Nb-doped TiO 2 (B) particles.

Abstract translation: 所描述的实施例提供了一种能量存储装置，其包括包括存储和释放离子的材料的正极，包含掺杂Nb的TiO 2（B）的负极和包含锂离子的非水电解质。 所描述的实施方案提供了一种方法，包括以下步骤：将至少一种钛化合物和至少一种铌化合物在乙二醇中混合以形成前体溶液，向前体溶液中加入水以引发水解和缩合反应，由此形成反应溶液， 加热反应溶液以形成结晶颗粒，收集颗粒，干燥收集的颗粒，并在温度> 350℃下对干燥颗粒进行热处理以获得掺杂Nb的TiO 2（B）颗粒。

公开(公告)号：WO2014099517A1

公开(公告)日：2014-06-26

申请号：PCT/US2013/074258

申请日：2013-12-11

Applicant: IMRA AMERICA, INC.

Inventor： TAN, Bing ,  HU, Zhendong ,  HE, Guanghui ,  CHE, Yong

IPC: H01M4/13 ,  H01M6/04 ,  H01G9/00

CPC classification number: H01G11/46 ,  H01G11/06 ,  H01G11/50 ,  H01G11/86 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/364 ,  H01M4/485 ,  H01M4/62 ,  H01M4/625 ,  H01M10/0525 ,  H01M2004/021 ,  Y02E60/13

Abstract: The described embodiments provide an energy storage device that includes a positive electrode including an active material that can store and release ions, a negative electrode including an active material that is a lithiated nano-architectured active material including tin and at least one stress-buffer component, and a non-aqueous electrolyte including lithium. The negative electrode active material is nano-architectured before lithiation.

Abstract translation: 所描述的实施例提供了一种能量存储装置，其包括包括能够存储和释放离子的活性材料的正电极，包含活性材料的负极，所述活性材料是包含锡的锂化纳米结构的活性材料和至少一种应力缓冲组分 和包含锂的非水电解质。 在锂化之前，负极活性物质是纳米结构的。

公开(公告)号：WO2013138541A1

公开(公告)日：2013-09-19

申请号：PCT/US2013/031119

申请日：2013-03-14

Applicant: IMRA AMERICA, INC.

Inventor： TAN, Bing ,  HU, Zhendong ,  HE, Guanghui ,  CHE, Yong

IPC: H01M4/02

CPC classification number: H01G11/30 ,  H01G11/50 ,  H01M4/362 ,  H01M4/366 ,  H01M4/5825 ,  H01M4/625 ,  H01M10/36 ,  H01M12/08 ,  Y02E60/128 ,  Y02E60/13

Abstract: Various embodiments of the present invention relate to electrode materials based on iron phosphates that can be used as the negative electrode materials for aqueous sodium ion batteries and electrochemical capacitors. At least one embodiment includes a negative electrode material for an aqueous sodium ion based energy storage device. The negative electrode material with a non-olivine crystal structure includes at least one phosphate selected from iron hydroxyl phosphate, Na 3 Fe 3 (PO 4 ) 4 , Na 3 Fe(PO 4 ) 2 , iron phosphate hydrate, ammonium iron phosphate hydrate, carbon-coated or carbon-mixed sodium iron phosphate. At least one embodiment includes an energy storage device that includes such a negative electrode material.

Abstract translation: 本发明的各种实施方案涉及可用作钠盐水溶液和电化学电容器的负极材料的基于磷酸铁的电极材料。 至少一个实施方案包括用于钠盐水溶液的能量储存装置的负极材料。 具有非橄榄石晶体结构的负极材料包括选自磷酸铁，Na 3 Fe 3（PO 4）4，Na 3 Fe（PO 4）2，磷酸铁水合物，磷酸铁铵水合物，碳涂覆或碳混合物中的至少一种磷酸盐 磷酸铁钠 至少一个实施例包括包括这种负极材料的能量存储装置。