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公开(公告)号:FR2668604B1
公开(公告)日:1995-10-13
申请号:FR9113213
申请日:1991-10-25
Applicant: INDIANA UNIVERSITY FOUNDATION
Inventor: NOVOTNY MILOS V , VLADISLAV DOLNIK , COBB KELLY A
IPC: C08F2/10 , C08F4/30 , G01N27/447 , C07K3/14
Abstract: Gels are formed in capillary tubes by electrophoretically drawing a charged polymerization initiator into a capillary tube pre-filled with monomer, crosslinking agent and catalyst. The rate of travel of the initiator is slow enough to maintain a sharp leading edge or front, thereby causing polymerization to occur in a progressive manner from one end of the capillary to the other. The shrinkage inherent in the polymerization reaction is thus compensated by fluid movement ahead of the traveling initiator front, and discontinuities in the gel which would otherwise be formed are avoided.
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公开(公告)号:FR2668604A1
公开(公告)日:1992-04-30
申请号:FR9113213
申请日:1991-10-25
Applicant: INDIANA UNIVERSITY FOUNDATION
Inventor: NOVOTNY MILOS V , VLADISLAV DOLNIK , COBB KELLY A
IPC: C08F2/10 , C08F4/30 , G01N27/447
Abstract: Gels are formed in capillary tubes by electrophoretically drawing a charged polymerization initiator into a capillary tube pre-filled with monomer, crosslinking agent and catalyst. The rate of travel of the initiator is slow enough to maintain a sharp leading edge or front, thereby causing polymerization to occur in a progressive manner from one end of the capillary to the other. The shrinkage inherent in the polymerization reaction is thus compensated by fluid movement ahead of the traveling initiator front, and discontinuities in the gel which would otherwise be formed are avoided.
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公开(公告)号:GB2251245B
公开(公告)日:1994-08-10
申请号:GB9122644
申请日:1991-10-25
Applicant: INDIANA UNIVERSITY FOUNDATION
Inventor: NOVOTNY MILOS V , DOLNIK VLADISLAV , COBB KELLY A
IPC: B01D15/08 , B01D57/02 , B01J20/286 , C03C17/00 , C03C17/32 , C07K1/26 , C07K14/575 , C07K14/62 , C07K14/76 , G01N27/447 , G01N30/56 , G01N30/88 , C08F292/00 , C08F2/00 , C08J5/24 , C09D4/00
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公开(公告)号:AU641607B2
公开(公告)日:1993-09-23
申请号:AU8590091
申请日:1991-10-17
Applicant: INDIANA UNIVERSITY FOUNDATION
Inventor: NOVOTNY MILOS V , DOLNIK VLADISLAV , COBB KELLY A
IPC: C08F2/10 , C08F4/30 , G01N27/447 , B01J47/08
Abstract: Gels are formed in capillary tubes by electrophoretically drawing a charged polymerization initiator into a capillary tube pre-filled with monomer, crosslinking agent and catalyst. The rate of travel of the initiator is slow enough to maintain a sharp leading edge or front, thereby causing polymerization to occur in a progressive manner from one end of the capillary to the other. The shrinkage inherent in the polymerization reaction is thus compensated by fluid movement ahead of the traveling initiator front, and discontinuities in the gel which would otherwise be formed are avoided.
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公开(公告)号:DE4135545A1
公开(公告)日:1992-05-07
申请号:DE4135545
申请日:1991-10-28
Applicant: INDIANA UNIVERSITY FOUNDATION
Inventor: NOVOTNY MILOS V , DOLNIK VLADISLAV , COBB KELLY A
IPC: C08F2/10 , C08F4/30 , G01N27/447
Abstract: Gels are formed in capillary tubes by electrophoretically drawing a charged polymerization initiator into a capillary tube pre-filled with monomer, crosslinking agent and catalyst. The rate of travel of the initiator is slow enough to maintain a sharp leading edge or front, thereby causing polymerization to occur in a progressive manner from one end of the capillary to the other. The shrinkage inherent in the polymerization reaction is thus compensated by fluid movement ahead of the traveling initiator front, and discontinuities in the gel which would otherwise be formed are avoided.
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公开(公告)号:AU8590091A
公开(公告)日:1992-04-30
申请号:AU8590091
申请日:1991-10-17
Applicant: INDIANA UNIVERSITY FOUNDATION
Inventor: NOVOTNY MILOS V , DOLNIK VLADISLAV , COBB KELLY A
IPC: C08F2/10 , C08F4/30 , G01N27/447 , B01J47/08
Abstract: Gels are formed in capillary tubes by electrophoretically drawing a charged polymerization initiator into a capillary tube pre-filled with monomer, crosslinking agent and catalyst. The rate of travel of the initiator is slow enough to maintain a sharp leading edge or front, thereby causing polymerization to occur in a progressive manner from one end of the capillary to the other. The shrinkage inherent in the polymerization reaction is thus compensated by fluid movement ahead of the traveling initiator front, and discontinuities in the gel which would otherwise be formed are avoided.
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公开(公告)号:IT1249720B
公开(公告)日:1995-03-09
申请号:ITRM910812
申请日:1991-10-25
Applicant: INDIANA UNIVERSITY FOUNDATION
Inventor: NOVOTNY MILOS V , DOLNIK VLADISLAV , COBB KELLY A
IPC: C08F2/10 , C08F4/30 , G01N27/447 , C23B
Abstract: Gels are formed in capillary tubes by electrophoretically drawing a charged polymerization initiator into a capillary tube pre-filled with monomer, crosslinking agent and catalyst. The rate of travel of the initiator is slow enough to maintain a sharp leading edge or front, thereby causing polymerization to occur in a progressive manner from one end of the capillary to the other. The shrinkage inherent in the polymerization reaction is thus compensated by fluid movement ahead of the traveling initiator front, and discontinuities in the gel which would otherwise be formed are avoided.
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公开(公告)号:ITRM910812A1
公开(公告)日:1993-04-25
申请号:ITRM910812
申请日:1991-10-25
Applicant: INDIANA UNIVERSITY FOUNDATION
Inventor: COBB KELLY A , DOLNIK VLADISLAV , NOVOTNY MILOS V
IPC: C08F2/10 , C08F4/30 , G01N27/447
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公开(公告)号:DE4135516A1
公开(公告)日:1992-05-07
申请号:DE4135516
申请日:1991-10-28
Applicant: INDIANA UNIVERSITY FOUNDATION
Inventor: NOVOTNY MILOS V , DOLNIK VLADISLAV , COBB KELLY A
IPC: B01D15/08 , B01D57/02 , B01J20/286 , C03C17/00 , C03C17/32 , C07K1/26 , C07K14/575 , C07K14/62 , C07K14/76 , G01N27/447 , G01N30/56 , G01N30/88
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公开(公告)号:AU8590191A
公开(公告)日:1992-04-30
申请号:AU8590191
申请日:1991-10-17
Applicant: INDIANA UNIVERSITY FOUNDATION
Inventor: NOVOTNY MILOS V , DOLNIK VLADISLAV , COBB KELLY A
IPC: B01D15/08 , B01D57/02 , B01J20/286 , C03C17/00 , C03C17/32 , C07K1/26 , C07K14/575 , C07K14/62 , C07K14/76 , G01N27/447 , G01N30/56 , G01N30/88 , C07K3/14 , C03C25/02
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