公开(公告)号：GB2251245B

公开(公告)日：1994-08-10

申请号：GB9122644

申请日：1991-10-25

Applicant: INDIANA UNIVERSITY FOUNDATION

Inventor： NOVOTNY MILOS V ,  DOLNIK VLADISLAV ,  COBB KELLY A

IPC: B01D15/08 ,  B01D57/02 ,  B01J20/286 ,  C03C17/00 ,  C03C17/32 ,  C07K1/26 ,  C07K14/575 ,  C07K14/62 ,  C07K14/76 ,  G01N27/447 ,  G01N30/56 ,  G01N30/88 ,  C08F292/00 ,  C08F2/00 ,  C08J5/24 ,  C09D4/00

公开(公告)号：AU641607B2

公开(公告)日：1993-09-23

申请号：AU8590091

申请日：1991-10-17

Applicant: INDIANA UNIVERSITY FOUNDATION

Inventor： NOVOTNY MILOS V ,  DOLNIK VLADISLAV ,  COBB KELLY A

IPC: C08F2/10 ,  C08F4/30 ,  G01N27/447 ,  B01J47/08

Abstract: Gels are formed in capillary tubes by electrophoretically drawing a charged polymerization initiator into a capillary tube pre-filled with monomer, crosslinking agent and catalyst. The rate of travel of the initiator is slow enough to maintain a sharp leading edge or front, thereby causing polymerization to occur in a progressive manner from one end of the capillary to the other. The shrinkage inherent in the polymerization reaction is thus compensated by fluid movement ahead of the traveling initiator front, and discontinuities in the gel which would otherwise be formed are avoided.

公开(公告)号：DE4135545A1

公开(公告)日：1992-05-07

申请号：DE4135545

申请日：1991-10-28

Applicant: INDIANA UNIVERSITY FOUNDATION

Inventor： NOVOTNY MILOS V ,  DOLNIK VLADISLAV ,  COBB KELLY A

IPC: C08F2/10 ,  C08F4/30 ,  G01N27/447

Abstract: Gels are formed in capillary tubes by electrophoretically drawing a charged polymerization initiator into a capillary tube pre-filled with monomer, crosslinking agent and catalyst. The rate of travel of the initiator is slow enough to maintain a sharp leading edge or front, thereby causing polymerization to occur in a progressive manner from one end of the capillary to the other. The shrinkage inherent in the polymerization reaction is thus compensated by fluid movement ahead of the traveling initiator front, and discontinuities in the gel which would otherwise be formed are avoided.

公开(公告)号：AU8590091A

公开(公告)日：1992-04-30

申请号：AU8590091

申请日：1991-10-17

Applicant: INDIANA UNIVERSITY FOUNDATION

Inventor： NOVOTNY MILOS V ,  DOLNIK VLADISLAV ,  COBB KELLY A

IPC: C08F2/10 ,  C08F4/30 ,  G01N27/447 ,  B01J47/08

Abstract: Gels are formed in capillary tubes by electrophoretically drawing a charged polymerization initiator into a capillary tube pre-filled with monomer, crosslinking agent and catalyst. The rate of travel of the initiator is slow enough to maintain a sharp leading edge or front, thereby causing polymerization to occur in a progressive manner from one end of the capillary to the other. The shrinkage inherent in the polymerization reaction is thus compensated by fluid movement ahead of the traveling initiator front, and discontinuities in the gel which would otherwise be formed are avoided.

公开(公告)号：IT1249721B

公开(公告)日：1995-03-09

申请号：ITRM910813

申请日：1991-10-25

Applicant: INDIANA UNIVERSITY FOUNDATION

Inventor： NOVOTNY MILOS V ,  DOLNIK VLADISLAV ,  COBB KELLY A

IPC: B01D15/08 ,  B01D57/02 ,  B01J20/286 ,  C03C17/00 ,  C03C17/32 ,  C07K1/26 ,  C07K14/575 ,  C07K14/62 ,  C07K14/76 ,  G01N27/447 ,  G01N30/56 ,  G01N30/88 ,  C23B

公开(公告)号：DE4135545C2

公开(公告)日：1994-11-03

申请号：DE4135545

申请日：1991-10-28

Applicant: INDIANA UNIVERSITY FOUNDATION

Inventor： NOVOTNY MILOS V ,  DOLNIK VLADISLAV ,  COBB KELLY A

IPC: C08F2/10 ,  C08F4/30 ,  G01N27/447 ,  B01D57/02

Abstract: Gels are formed in capillary tubes by electrophoretically drawing a charged polymerization initiator into a capillary tube pre-filled with monomer, crosslinking agent and catalyst. The rate of travel of the initiator is slow enough to maintain a sharp leading edge or front, thereby causing polymerization to occur in a progressive manner from one end of the capillary to the other. The shrinkage inherent in the polymerization reaction is thus compensated by fluid movement ahead of the traveling initiator front, and discontinuities in the gel which would otherwise be formed are avoided.

公开(公告)号：GB2249838B

公开(公告)日：1994-05-04

申请号：GB9122660

申请日：1991-10-25

Applicant: INDIANA UNIVERSITY FOUNDATION

Inventor： NOVOTNY MILOS V ,  DOLNIK VLADISLAV ,  COBB KELLY A

IPC: C08F2/10 ,  C08F4/30 ,  G01N27/447 ,  G01N27/26

Abstract: Gels are formed in capillary tubes by electrophoretically drawing a charged polymerization initiator into a capillary tube pre-filled with monomer, crosslinking agent and catalyst. The rate of travel of the initiator is slow enough to maintain a sharp leading edge or front, thereby causing polymerization to occur in a progressive manner from one end of the capillary to the other. The shrinkage inherent in the polymerization reaction is thus compensated by fluid movement ahead of the traveling initiator front, and discontinuities in the gel which would otherwise be formed are avoided.

公开(公告)号：ITRM910813A1

公开(公告)日：1993-04-25

申请号：ITRM910813

申请日：1991-10-25

Applicant: INDIANA UNIVERSITY FOUNDATION

Inventor： COBB KELLY A ,  DOLNIK VLADISLAV ,  NOVOTNY MILOS V

IPC: B01D15/08 ,  B01D57/02 ,  B01J20/286 ,  C03C17/00 ,  C03C17/32 ,  C07K1/26 ,  C07K14/575 ,  C07K14/62 ,  C07K14/76 ,  G01N27/447 ,  G01N30/56 ,  G01N30/88

公开(公告)号：GB2251245A

公开(公告)日：1992-07-01

申请号：GB9122644

申请日：1991-10-25

Applicant: INDIANA UNIVERSITY FOUNDATION

Inventor： NOVOTNY MILOS V ,  DOLNIK VLADISLAV ,  COBB KELLY A

IPC: B01D15/08 ,  B01D57/02 ,  B01J20/286 ,  C03C17/00 ,  C03C17/32 ,  C07K1/26 ,  C07K14/575 ,  C07K14/62 ,  C07K14/76 ,  G01N27/447 ,  G01N30/56 ,  G01N30/88

公开(公告)号：GB2249838A

公开(公告)日：1992-05-20

申请号：GB9122660

申请日：1991-10-25

Applicant: INDIANA UNIVERSITY FOUNDATION

Inventor： NOVOTNY MILOS V ,  DOLNIK VLADISLAV ,  COBB KELLY A

IPC: C08F2/10 ,  C08F4/30 ,  G01N27/447

Abstract: Gels are formed in capillary tubes by electrophoretically drawing a charged polymerization initiator into a capillary tube pre-filled with monomer, crosslinking agent and catalyst. The rate of travel of the initiator is slow enough to maintain a sharp leading edge or front, thereby causing polymerization to occur in a progressive manner from one end of the capillary to the other. The shrinkage inherent in the polymerization reaction is thus compensated by fluid movement ahead of the traveling initiator front, and discontinuities in the gel which would otherwise be formed are avoided.