公开(公告)号：WO1994003551A1

公开(公告)日：1994-02-17

申请号：PCT/US1993005895

申请日：1993-06-18

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  DOUGHERTY, James, A. ,  CRIVELLO, James, V.

IPC: C09K03/00

CPC classification number: G03F7/029 ,  C07C381/12 ,  C07F9/902

Abstract: This invention relates to C14 to C20 alkoxy monophenyl sulfonium salt initiators having formula (I), wherein R is C14 to C20 alkyl; R1 and R2 are each independently C4 to C20 alkyl and X- is a non-basic, non-nucleophilic anion, which initiators are employed in the polymerization of mono- and poly- functional glycidyl ethers, alpha-olefin oxides and vinyl monomers or oligomers.

Abstract translation: 本发明涉及具有式（I）的C 14至C 20烷氧基单苯基锍盐引发剂，其中R为C 14至C 20烷基; R1和R2各自独立地为C4至C20烷基，X-是非碱性非亲核阴离子，其引发剂用于单官能和多官能缩水甘油醚，α-烯烃氧化物和乙烯基单体或低聚物的聚合 。

公开(公告)号：WO1993002119A1

公开(公告)日：1993-02-04

申请号：PCT/US1992004528

申请日：1992-06-29

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  DOUGHERTY, James, A. ,  VARA, Fulvio, J.

IPC: C08G59/26

CPC classification number: C08F216/12

Abstract: What is provided is a composition for cationic polymerization of vinyl ethers without color formation. The composition includes a defined additive comonomer to inhibit the formation of undesired colored materials during polymerization without affecting the properties of the polymer produced. The additive used herein copolymerizes with the vinyl ether to provide spacer molecular units of the additive therein whose presence precludes the formation of long chain conjugation in the copolymer which ordinarily would color the composition. Suitable polymerizable inhibitor additives include cyclic aliphatic epoxides, unsaturated carboxylic acids and their esters, styrene, styrene ethers, styrene oxide, and cycloalkene oxides, in an amount less than 5 % by weight of the composition.

Abstract translation: 提供了用于乙烯基醚的阳离子聚合而不形成颜料的组合物。 组合物包含限定的添加剂共聚单体，以在聚合期间抑制不期望的有色材料的形成而不影响所生产的聚合物的性质。 本文使用的添加剂与乙烯基醚共聚以提供其中添加剂的间隔分子单元，其存在阻止了共聚物中长链共轭的形成，其通常将着色组合物。 合适的可聚合抑制剂添加剂包括小于组合物重量的5％的环状脂族环氧化物，不饱和羧酸及其酯，苯乙烯，苯乙烯醚，氧化苯乙烯和环烯烃氧化物。

公开(公告)号：WO1995019378A1

公开(公告)日：1995-07-20

申请号：PCT/US1995000133

申请日：1995-01-06

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  DOUGHERTY, James, A. ,  WOLF, Philip, F.

IPC: C08F220/10

CPC classification number: C08F220/12 ,  A61C13/0024 ,  A61C13/0025 ,  C08F226/02 ,  C08F226/06

Abstract: This invention relates to a reactive diluent mixture employed in a free radical polymerization of film-forming monomers which comprises between about 25 and about 90 wt. % N-vinyl lactam containing 6 to 9 carbon atoms and between about 10 and about 75 wt. % of a non-cyclic vinyl amide having from 3 to 7 carbon atoms which is employed in a concentration of between about 10 and about 50 wt. % based on total film forming monomers.

Abstract translation: 本发明涉及用于成膜单体的自由基聚合的反应性稀释剂混合物，其包含约25至约90wt。 含有6至9个碳原子的N-乙烯基内酰胺和约10至约75重量％ ％的具有3至7个碳原子的非环状乙烯基酰胺，其浓度为约10至约50重量％。 基于总成膜单体的％。

公开(公告)号：WO1993006140A1

公开(公告)日：1993-04-01

申请号：PCT/US1992006454

申请日：1992-08-03

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  DOUGHERTY, James, A. ,  VARA, Fulvio, J. ,  PLOTKIN, Jeffrey, S. ,  TAYLOR, Paul, D. ,  NARAYANAN, Kolazi, S.

IPC: C08F14/24

CPC classification number: C08F214/188 ,  C09D4/00 ,  C08F216/00

Abstract: A rapidly curable fluorocopolymer comprises (a) 40 to 60 mole % of fluoroolefin units, (b) 8 to 60 mole % of the monovinyl ether of cyclohexanedimethanol units and (c) 5 to 45 mole % of alkyl vinyl ether units, wherein the mole % of a = b + c. The vinyl ether group provides an enhanced polymer Tg and a primary hydroxy site in the backbone of the polymer for effective and rapid crosslinking upon curing with isocyanates. The presence of (b) + (c) in substantially equimolar amounts with (a) provides coatings having the desired hardness without brittleness, and in suitable ratio for reaction copolymerization with (a). In another embodiment, this invention relates to coating compositions containing the alk-1-enyl ether reaction product of a hydroxylated compound, an alk-1-enyloxy oxirane and from 0 to 95 % of an alkyl epoxide.

Abstract translation: 快速固化的含氟共聚物包含（a）40-60摩尔％的氟烯烃单元，（b）8至60摩尔％的环己烷二甲醇单元的单乙烯基醚和（c）5至45摩尔％的烷基乙烯基醚单元，其中该摩尔 ％a = b + c。 乙烯基醚基团在聚合物主链中提供增强的聚合物Tg和主要羟基位点，用于在用异氰酸酯固化时有效且快速的交联。 （b）+（c）与（a）基本上等摩尔量的存在提供了具有所需硬度而不脆性的涂层，并且与（a）的反应共聚合的合适比例。 在另一个实施方案中，本发明涉及包含羟基化化合物，烷-1-烯氧基环氧乙烷和0至95％烷基环氧化物的烷-1-烯基醚反应产物的涂料组合物。

公开(公告)号：WO1998008878A1

公开(公告)日：1998-03-05

申请号：PCT/US1997011892

申请日：1997-06-19

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  DOUGHERTY, James, A. ,  MCKITTRICK, John, G. ,  CLARK, Raymond, Bret

IPC: C08F04/18

CPC classification number: C08F16/16

Abstract: A process for polymerizing a vinyl ether monomer which comprises contacting the vinyl ether with an initiator system of silicon dioxide and one or more metallic oxides.

Abstract translation: 一种聚合乙烯基醚单体的方法，其包括使乙烯基醚与二氧化硅和一种或多种金属氧化物的引发剂体系接触。

公开(公告)号：WO1992014764A1

公开(公告)日：1992-09-03

申请号：PCT/US1992000742

申请日：1992-01-29

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  VARA, Fulvio, J. ,  DOUGHERTY, James, A.

IPC: C08F02/46

CPC classification number: C08F299/0478

Abstract: A clear, liquid, shelf-stable photocurable composition capable of cured to form a clear, hard, adherent, solvent-resistant coating on a substrate comprising a blend of substantially equivalent amounts of (a) an unsaturated polyester polymer, oligomer, or mixtures thereof; and (b) a non-volatile, polyester-compatible vinyl ether, and vinyl pyrrolidone; and (c) a free radical photoinitiator.

Abstract translation: 一种透明，液态，稳定的可光固化组合物，其能够固化以在基材上形成透明，硬的，粘附的耐溶剂性涂层，其包含基本上相当量的（a）不饱和聚酯聚合物，低聚物或其混合物的共混物 ; 和（b）不挥发性聚酯相容的乙烯基醚和乙烯基吡咯烷酮; 和（c）自由基光引发剂。

公开(公告)号：WO1991011467A1

公开(公告)日：1991-08-08

申请号：PCT/US1990006758

申请日：1990-11-23

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  VARA, Fulvio, J. ,  DOUGHERTY, James, A. ,  PLOTKIN, Jeffrey, S. ,  NARAYANAN, Kolazi, S. ,  TAYLOR, Paul, D.

IPC: C08F02/46

CPC classification number: C08G65/336 ,  C07F7/045 ,  C08F8/42 ,  C08G59/4085 ,  C09D4/00 ,  C08F230/00

Abstract: The invention relates to alk-1-enyl ether silicates having the formula (I): [X]4-nSi[OR1OCH=CH-R2]n, and a process for making same, wherein X is halogen or -OR wherein R is lower alkyl or a mixture of halogen and OR, a mixture of OR and hydrogen or a mixture of halogen and hydrogen; R1 contains from 1 to 8 carbon atoms and is alkylene, alkenylene, alkynylene, optionally alkoxylated with up to 20 units of alpha , wherein Y is hydrogen or methyl and R2 is each hydrogen or lower alkyl and n has a value of from 1 to 4; and polyfunctional alkenyl ether having the formula (II): A[(CH2O)m(Z)rCH=CHR]n, wherein A is a carbon atom, -OCH=CHR or [C1 to C10 alkyl]4-n; R is C1 to C6 alkyl; Z is C2 to C8 alkyleneoxy; r has a value of from 0 to 6; m has a value of from 0 to 1 and at least one of r and m has a positive value; n has a value of from 1 to 4, with the proviso that m is 0 and n is one when A is -OCH=CHR, n has a value of 2 or 3 when A is [C1 to C10 alkyl]4-n and n has a value of 4 when A is carbon. This invention also relates to a radiation curable cross linkable compositions containing (a) from about 0.1 to about 5 wt. % of an initiator containing at least 25 % cationic intiator, (b) from about 0 to about 60 wt. % of a polymerizable vinyl ether, epoxide, vinyloxy alkyl urethane or acrylate and (c) from about 35 to about 99.9 wt. % of an ether of formula (II).

Abstract translation: 本发明涉及具有式（I）：[X] 4-nSi [OR 1 OCH = CH-R 2] n的烷-1-烯基醚硅酸盐及其制备方法，其中X为卤素或-OR，其中R为 低级烷基或卤素与OR的混合物，OR与氢的混合物或卤素与氢的混合物; R1含有1至8个碳原子，并且是亚烷基，亚烯基，亚炔基，任选地被至多20个单元的α烷氧基化，其中Y是氢或甲基，并且R 2各自为氢或低级烷基，n的值为1至4 ; 和具有式（II）的多官能烯基醚：A [（CH 2 O）m（Z）r CH = CHR] n，其中A是碳原子，-OCH = CHR或[C 1 -C 10烷基] 4-n; R为C1至C6烷基; Z为C2〜C8亚烷氧基; r的值为0到6; m具有0至1的值，并且r和m中的至少一个具有正值; n的值为1至4，条件是m为0且当A为-OCH = CHR时n为1，当A为[C 1至C 10烷基] 4-n时，n为2或3的值，n为 当A为碳时，n的值为4。 本发明还涉及可辐射固化的可交联组合物，其包含（a）约0.1至约5wt。 含有至少25％阳离子介导剂的引发剂的％，（b）约0至约60重量％ ％的可聚合乙烯基醚，环氧化物，乙烯基氧基烷基氨基甲酸酯或丙烯酸酯和（c）约35-约99.9重量％ ％的式（II）的醚。

公开(公告)号：WO1992004383A1

公开(公告)日：1992-03-19

申请号：PCT/US1991004619

申请日：1991-06-27

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  NARAYANAN, Kolazi, S. ,  PLOTKIN, Jeffrey, S. ,  VARA, Fulvio, J. ,  DOUGHERTY, James, A. ,  MILLER, Mark, M. ,  TAYLOR, Paul, D.

IPC: C08F02/50

CPC classification number: C07D317/36 ,  C09D4/00 ,  C08F220/00

Abstract: This invention relates to a coating composition which can be cured by exposure to radiation energy in the presence of a cationic photoinitiator. The composition comprises a mixture of between about 1 and about 75 wt. % of a reactive vinyl or alk-1-enyl ether cyclocarbonate having formula (I) wherein R is hydrogen or lower alkyl; R' is C2 to C4 alkylene; n has a value of from 0 to 4 and n' has a value of from 1 to 4 and between about 99 and about 25 wt. % of a polymerizable compound containing an onium salt initiator which is normally insoluble in said polymerizable compound or a mixture thereof. The invention also relates to the use of the composition as a protective coating on a substrate. Preferably, the cyclocarbonate is prepared by a two-stage liquid phase process wherein an alk-2-enyl glycidyl ether having formula (II) wherein R is hydrogen or lower alkyl; R' is C2 to C4 alkylene, n has a value of from 1 to 4 and n' has a value of from 0 to 4, is catalytically isomerized to the corresponding alk-1-enyl glycidyl ether in the first-stage of the reaction and the reaction mixture of the first-stage, containing the isomerization catalyst is then contacted with carbon dioxide in the presence of a phase transfer catalyst under a pressure ranging from atmospheric to about 400 psig in the second stage of the reaction.

Abstract translation: 本发明涉及可在阳离子光引发剂存在下通过暴露于辐射能固化的涂料组合物。 组合物包含约1至约75wt。 ％的具有式（I）的反应性乙烯基或烷-1-烯基醚环碳酸酯，其中R是氢或低级烷基; R'是C 2至C 4亚烷基; n具有0至4的值，n'具有1至4的值和约99至约25重量％的值。 ％的通常不溶于所述可聚合化合物的鎓盐引发剂的可聚合化合物或其混合物。 本发明还涉及组合物在基材上作为保护涂层的用途。 优选地，环碳酸酯通过两阶段液相方法制备，其中具有式（II）的烷基-2-烯基缩水甘油醚，其中R是氢或低级烷基; R'为C 2至C 4亚烷基，n为1至4，n'为0至4的值，在反应的第一阶段被催化异构化为相应的烷-1-烯基缩水甘油醚 然后在相转移催化剂的存在下，在反应的第二阶段，在大气压至约400psig的压力下，将含有异构化催化剂的第一级的反应混合物与二氧化碳接触。

公开(公告)号：WO1991011466A1

公开(公告)日：1991-08-08

申请号：PCT/US1990006713

申请日：1990-11-19

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  DOUGHERTY, James, A. ,  PLOTKIN, Jeffrey, S. ,  VARA, Fulvio, J. ,  NARAYANAN, Kolazi, S.

IPC: C08F02/46

CPC classification number: C09D4/00 ,  C08F216/00

Abstract: This invention relates to a cross-linkable, cationic radiation curable composition comprising (a) a non-volatile vinyl ether, epoxide, acrylate or an oligomer thereof, (b) a cationic photoinitiator and (c) a divinyl ether polyacetal oligomer having formula (I), wherein n has a value of from 1 to 50; X is uniformly sulfur or oxygen; R is C2 to C4 alkeneoxy alkylene, poly(alkyleneoxy) alkylene, or a branched, linear or cyclic C2 to C20 alkylene and R' is phenylene, diphenylene methane, diphenylene propane, xylylene, tolylene, or a branched, linear or cyclic C2 to C20 alkylene optionally substituted with an ether, ester, carbonate, carbamate, C2 to C4 alkyleneoxy alkylene or poly(C2 to C4 alkyleneoxy) alkylene radical. The invention also relates to the composition cured on a substrate.

公开(公告)号：WO1994003505A1

公开(公告)日：1994-02-17

申请号：PCT/US1993005854

申请日：1993-06-18

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  CRIVELLO, James, V. ,  DOUGHERTY, James, A.

IPC: C08F02/50

CPC classification number: C09D4/00 ,  C08F216/00

Abstract: The present invention relates to a rapidly curable, silicone-free release coating composition comprising (a) between about 50 and about 95 wt. % of a vinyl ether having the formula: CnH2n+1O-CH=CH2, wherein n has a value of from 8 to 20, optionally containing a cationically polymerizable comonomer; (b) between about 5 and about 50 wt. % of a multifunctional vinyl ether monomer and (c) between about 0.1 and about 10 wt. % of an onium salt photoinitiator.

Abstract translation: 本发明涉及快速固化的无硅酮释放涂料组合物，其包含（a）约50-约95wt。 ％的具有下式的乙烯基醚：CnH2n + 10-CH = CH2，其中n具有8至20的值，任选地含有阳离子聚合的共聚单体; （b）约5至约50wt。 ％的多官能乙烯基醚单体和（c）约0.1至约10重量％ ％的盐盐光引发剂。