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    PROCESS OF VAPOR PHASE CATALYTIC HYDROGENATION OF MALEIC ANHYDRIDE TO GAMMA-BUTYROLACTONE IN HIGH CONVERSION AND HIGH SELECTIVITY USING AN ACTIVATED CATALYST
    2.
    发明申请
    PROCESS OF VAPOR PHASE CATALYTIC HYDROGENATION OF MALEIC ANHYDRIDE TO GAMMA-BUTYROLACTONE IN HIGH CONVERSION AND HIGH SELECTIVITY USING AN ACTIVATED CATALYST 审中-公开
    使用活化催化剂的高转化率和高选择性的马来酸酐在蒸气相催化氢化甘油 - 丁氧基酮的方法

    公开(公告)号：WO1991016132A1

    公开(公告)日：1991-10-31

    申请号：PCT/US1991002389

    申请日：1991-04-08

    Applicant: ISP INVESTMENTS INC.

    Inventor： ISP INVESTMENTS INC. ,  TAYLOR, Paul, D. ,  DE THOMAS, Waldo ,  BUCHANAN, Donald, W., Jr.

    IPC: B01J23/06

    CPC classification number: C07D315/00 ,  B01J23/80 ,  B01J37/18

    Abstract: Vapor phase catalytic hydrogenation of maleic anhydride to gamma-butyrolactone is achieved in a conversion of 95 % or more and a selectivity of 80 % or more during a prolonged period of production. The process of the invention uses an activated catalyst prepared by reducing a catalyst composition comprising 30-65 % by weight of CuO, 18-50 % by weight of ZnO and 8-22 % by weight of Al2O3, and, particularly, by activating the reduced catalyst composition in hydrogen at an activation temperature of at least 400 DEG C, preferably 400 DEG C to 525 DEG C, and optimally about 425 DEG C. The hydrogenation process is carried out under predetermined and advantageous process conditions, including a defined molar ratio of hydrogen to maleic anhydride in the vapor reactant stream, a selected pressure during hydrogenation, an advantageous feed rate space velocity, a predetermined contact time, and a suitable reaction temperature.

    Abstract translation: 在长时间的生产过程中，将马来酸酐与γ-丁内酯的气相催化氢化达到95％以上的转化率和80％以上的选择性。 本发明的方法使用通过还原包含30-65重量％CuO，18-50重量％ZnO和8-22重量％Al 2 O 3的催化剂组合物制备的活化催化剂，特别是通过将 在氢气中活化温度为至少400℃，优选400℃至525℃，最优约425℃的氢气中的催化剂组成降低。氢化过程在预定和有利的工艺条件下进行，包括确定的摩尔比 在氢气中选择的压力，有利的进料速率空间速度，预定的接触时间和合适的反应温度。

    ALKENYL ETHERS AND RADIATION CURABLE COMPOSITIONS
    3.
    发明申请
    ALKENYL ETHERS AND RADIATION CURABLE COMPOSITIONS 审中-公开
    ALKENYL ETHERS和辐射可固化组合物

    公开(公告)号：WO1991011467A1

    公开(公告)日：1991-08-08

    申请号：PCT/US1990006758

    申请日：1990-11-23

    Applicant: ISP INVESTMENTS INC.

    Inventor： ISP INVESTMENTS INC. ,  VARA, Fulvio, J. ,  DOUGHERTY, James, A. ,  PLOTKIN, Jeffrey, S. ,  NARAYANAN, Kolazi, S. ,  TAYLOR, Paul, D.

    IPC: C08F02/46

    CPC classification number: C08G65/336 ,  C07F7/045 ,  C08F8/42 ,  C08G59/4085 ,  C09D4/00 ,  C08F230/00

    Abstract: The invention relates to alk-1-enyl ether silicates having the formula (I): [X]4-nSi[OR1OCH=CH-R2]n, and a process for making same, wherein X is halogen or -OR wherein R is lower alkyl or a mixture of halogen and OR, a mixture of OR and hydrogen or a mixture of halogen and hydrogen; R1 contains from 1 to 8 carbon atoms and is alkylene, alkenylene, alkynylene, optionally alkoxylated with up to 20 units of alpha , wherein Y is hydrogen or methyl and R2 is each hydrogen or lower alkyl and n has a value of from 1 to 4; and polyfunctional alkenyl ether having the formula (II): A[(CH2O)m(Z)rCH=CHR]n, wherein A is a carbon atom, -OCH=CHR or [C1 to C10 alkyl]4-n; R is C1 to C6 alkyl; Z is C2 to C8 alkyleneoxy; r has a value of from 0 to 6; m has a value of from 0 to 1 and at least one of r and m has a positive value; n has a value of from 1 to 4, with the proviso that m is 0 and n is one when A is -OCH=CHR, n has a value of 2 or 3 when A is [C1 to C10 alkyl]4-n and n has a value of 4 when A is carbon. This invention also relates to a radiation curable cross linkable compositions containing (a) from about 0.1 to about 5 wt. % of an initiator containing at least 25 % cationic intiator, (b) from about 0 to about 60 wt. % of a polymerizable vinyl ether, epoxide, vinyloxy alkyl urethane or acrylate and (c) from about 35 to about 99.9 wt. % of an ether of formula (II).

    Abstract translation: 本发明涉及具有式（I）：[X] 4-nSi [OR 1 OCH = CH-R 2] n的烷-1-烯基醚硅酸盐及其制备方法，其中X为卤素或-OR，其中R为 低级烷基或卤素与OR的混合物，OR与氢的混合物或卤素与氢的混合物; R1含有1至8个碳原子，并且是亚烷基，亚烯基，亚炔基，任选地被至多20个单元的α烷氧基化，其中Y是氢或甲基，并且R 2各自为氢或低级烷基，n的值为1至4 ; 和具有式（II）的多官能烯基醚：A [（CH 2 O）m（Z）r CH = CHR] n，其中A是碳原子，-OCH = CHR或[C 1 -C 10烷基] 4-n; R为C1至C6烷基; Z为C2〜C8亚烷氧基; r的值为0到6; m具有0至1的值，并且r和m中的至少一个具有正值; n的值为1至4，条件是m为0且当A为-OCH = CHR时n为1，当A为[C 1至C 10烷基] 4-n时，n为2或3的值，n为 当A为碳时，n的值为4。 本发明还涉及可辐射固化的可交联组合物，其包含（a）约0.1至约5wt。 含有至少25％阳离子介导剂的引发剂的％，（b）约0至约60重量％ ％的可聚合乙烯基醚，环氧化物，乙烯基氧基烷基氨基甲酸酯或丙烯酸酯和（c）约35-约99.9重量％ ％的式（II）的醚。

    VINYL ETHER COMPOUNDS
    5.
    发明申请
    VINYL ETHER COMPOUNDS 审中-公开
    乙烯醚化合物

    公开(公告)号：WO1991013052A1

    公开(公告)日：1991-09-05

    申请号：PCT/US1991000639

    申请日：1991-01-30

    Applicant: ISP INVESTMENTS INC.

    Inventor： ISP INVESTMENTS INC. ,  LIU, Kou-Chang ,  VARA, Fulvio, J. ,  DOUGHERTY, James, A. ,  NARAYANAN, Kolazi, S. ,  PLOTKIN, Jeffrey, S. ,  TAYLOR, Paul, D.

    IPC: C07C69/96

    CPC classification number: C07C43/23 ,  C07C69/96

    Abstract: Alkenyl ether carbonates having formula (A) wherein A is RHC=CHO(B)n-, lower alkyl or a mixture thereof; B is (a) divalent radical having from 2 to 12 carbon atoms and is selected from the group of alkylene, mono or polyalkoxylated alkylene, alkenylene, alkynylene, arylene, alkarylene and aralkylene radicals, which radicals are optionally substituted with halo, alkyl, cyano, nitro or alkoxy; R is hydrogen or lower alkyl and n is from 1 to 10. These are provided alkenyl ether polycarbonate, a polymerizable compound formed from reaction of a dialkenyl ether monocarbonate and a polyhydroxy alcohol having at least three hydroxy groups, a polymerizable compound formed from the reaction of a hydroxylated polymeric polyether, polyurethane, polycarbonate, polyester of an alkanedioic acid or polybutadiene and a dialkenyloxy carbonate co-reactant, and polyaryloxypolyvinyl ethers. The polymerized compounds are intermediates for hard abrasion resistant films and coatings. The monomers and oligomers are intermediates for hydrogels or photoresist materials.

    Abstract translation: 式（A）的烯基醚碳酸酯，其中A为RHC = CHO（B）n-，低级烷基或其混合物; B是（a）具有2至12个碳原子的二价基团，并且选自亚烷基，单或多烷氧基化的亚烷基，亚烯基，亚炔基，亚芳基，亚烷基和亚芳基，其基团任选被卤素，烷基，氰基 ，硝基或烷氧基; R为氢或低级烷基，n为1〜10。这些为烯基醚聚碳酸酯，由二烯基醚单碳酸酯与至少具有三个羟基的多羟基醇反应形成的可聚合化合物，由反应形成的可聚合化合物 的羟基化聚合物聚醚，聚氨酯，聚碳酸酯，链烷二酸或聚丁二烯的聚酯和二链烯基氧基碳酸酯共反应物，以及聚芳氧基聚乙烯醚。 聚合的化合物是用于硬质耐磨膜和涂层的中间体。 单体和低聚物是水凝胶或光致抗蚀剂材料的中间体。

    PROCESS FOR THE PREPARATION OF VINYLPYRROLIDONE/VINYL ACETATE COPOLYMERS
    6.
    发明申请
    PROCESS FOR THE PREPARATION OF VINYLPYRROLIDONE/VINYL ACETATE COPOLYMERS 审中-公开
    制备乙烯基吡咯烷酮/乙酸乙烯酯共聚物的方法

    公开(公告)号：WO1994022923A1

    公开(公告)日：1994-10-13

    申请号：PCT/US1994002469

    申请日：1994-03-04

    Applicant: ISP INVESTMENTS INC.

    Inventor： ISP INVESTMENTS INC. ,  ZHONG, Yuanzhen ,  PARIKH, Hemant ,  TAYLOR, Paul, D. ,  SMITH, Terry, E.

    IPC: C08F02/00

    CPC classification number: C08F226/10

    Abstract: This invention relates to an improved process for producing a clear solution of vinylpyrrolidone (VP) and vinyl acetate (VA) monomers which comprises, in an anhydrous system, (a) reacting a C2 to C3 alcoholic solution containing said VA monomer and between about 60 and about 80 wt.% portion of total VP monomer in the presence of between about 0.05 and about 0.3 wt.% of a free radical initiator selected from the group consisting of tert-amylperoxy pivalate and 2,2-azobis(2-methylbutyronitrile) or a mixture thereof for a period of from about 5 to about 10 hours, at a temperature between about 60 and about 110 DEG C; (b) gradually adding the remaining VP monomer in C2 to C3 alcohol solution at reaction temperature after the addition of the VA monomer is complete; (c) raising the temperature of the resulting reaction mixture to between about 110 and about 150 DEG C; (d) continuing the polymerization reaction at said higher temperature in the presence of from about 0.11 to about 0.6 wt.%, based on total monomers, of 2,5-dimethyl-2,5-bis(tert-butylperoxy) hexane and (e) cooling the resulting reaction mixture and recovering a homogeneous VP/VA copolymer C2 to C3 alcohol solution containing less than 100 ppm of residual vinylpyrrolidone monomer or vinyl acetate residual monomer.

    Abstract translation: 本发明涉及一种用于生产乙烯基吡咯烷酮（VP）和乙酸乙烯酯（VA）单体的透明溶液的改进方法，其包括在无水体系中，（a）使含有所述VA单体的C2至C3醇溶液与约60 和约80重量％的总VP单体的存在下，在约0.05和约0.3重量％的选自叔戊基过氧化新戊酸酯和2,2-偶氮二（2-甲基丁腈）的自由基引发剂的存在下， 或其混合物在约5至约10小时之间，在约60至约110℃的温度下; （b）在加入VA单体完成后，在反应温度下逐渐加入剩余的VP单体在C2〜C3醇溶液中; （c）将所得反应混合物的温度提高至约110至约150℃; （d）在约0.11至约0.6重量％存在下，基于总单体2,5-二甲基-2,5-双（叔丁基过氧）己烷和（ e）冷却所得反应混合物并回收含有少于100ppm的残余乙烯基吡咯烷酮单体或乙酸乙烯酯残余单体的均匀的VP / VA共聚物C2至C3醇溶液。

    RADIATION CURABLE COATING COMPOSITIONS
    7.
    发明申请
    RADIATION CURABLE COATING COMPOSITIONS 审中-公开
    辐射可固化涂料组合物

    公开(公告)号：WO1992004383A1

    公开(公告)日：1992-03-19

    申请号：PCT/US1991004619

    申请日：1991-06-27

    Applicant: ISP INVESTMENTS INC.

    Inventor： ISP INVESTMENTS INC. ,  NARAYANAN, Kolazi, S. ,  PLOTKIN, Jeffrey, S. ,  VARA, Fulvio, J. ,  DOUGHERTY, James, A. ,  MILLER, Mark, M. ,  TAYLOR, Paul, D.

    IPC: C08F02/50

    CPC classification number: C07D317/36 ,  C09D4/00 ,  C08F220/00

    Abstract: This invention relates to a coating composition which can be cured by exposure to radiation energy in the presence of a cationic photoinitiator. The composition comprises a mixture of between about 1 and about 75 wt. % of a reactive vinyl or alk-1-enyl ether cyclocarbonate having formula (I) wherein R is hydrogen or lower alkyl; R' is C2 to C4 alkylene; n has a value of from 0 to 4 and n' has a value of from 1 to 4 and between about 99 and about 25 wt. % of a polymerizable compound containing an onium salt initiator which is normally insoluble in said polymerizable compound or a mixture thereof. The invention also relates to the use of the composition as a protective coating on a substrate. Preferably, the cyclocarbonate is prepared by a two-stage liquid phase process wherein an alk-2-enyl glycidyl ether having formula (II) wherein R is hydrogen or lower alkyl; R' is C2 to C4 alkylene, n has a value of from 1 to 4 and n' has a value of from 0 to 4, is catalytically isomerized to the corresponding alk-1-enyl glycidyl ether in the first-stage of the reaction and the reaction mixture of the first-stage, containing the isomerization catalyst is then contacted with carbon dioxide in the presence of a phase transfer catalyst under a pressure ranging from atmospheric to about 400 psig in the second stage of the reaction.

    Abstract translation: 本发明涉及可在阳离子光引发剂存在下通过暴露于辐射能固化的涂料组合物。 组合物包含约1至约75wt。 ％的具有式（I）的反应性乙烯基或烷-1-烯基醚环碳酸酯，其中R是氢或低级烷基; R'是C 2至C 4亚烷基; n具有0至4的值，n'具有1至4的值和约99至约25重量％的值。 ％的通常不溶于所述可聚合化合物的鎓盐引发剂的可聚合化合物或其混合物。 本发明还涉及组合物在基材上作为保护涂层的用途。 优选地，环碳酸酯通过两阶段液相方法制备，其中具有式（II）的烷基-2-烯基缩水甘油醚，其中R是氢或低级烷基; R'为C 2至C 4亚烷基，n为1至4，n'为0至4的值，在反应的第一阶段被催化异构化为相应的烷-1-烯基缩水甘油醚 然后在相转移催化剂的存在下，在反应的第二阶段，在大气压至约400psig的压力下，将含有异构化催化剂的第一级的反应混合物与二氧化碳接触。

    PROCESS FOR PRODUCING PVP-H2O2 PRODUCTS
    9.
    发明申请
    PROCESS FOR PRODUCING PVP-H2O2 PRODUCTS 审中-公开
    生产PVP-H2O2产品的方法

    公开(公告)号：WO1992017158A1

    公开(公告)日：1992-10-15

    申请号：PCT/US1992002287

    申请日：1992-03-23

    Applicant: ISP INVESTMENTS INC.

    Inventor： ISP INVESTMENTS INC. ,  BISS, Russel, B. ,  COHEN, Jeffrey, M. ,  MERIANOS, John, J. ,  TAYLOR, Paul, D.

    IPC: A61K07/40

    CPC classification number: A61Q17/005 ,  A01N59/00 ,  A61K8/02 ,  A61K8/22 ,  A61K8/8176 ,  A61K31/79 ,  A61K33/40 ,  A61K2800/52 ,  A61Q19/00 ,  C01B15/01 ,  C11D3/394 ,  C11D3/3945 ,  C11D17/00 ,  A01N25/34 ,  A01N25/16 ,  A01N25/12 ,  A01N25/10 ,  A01N2300/00

    Abstract: A process for the production of PVP-H2O2 products in the form of free-flowing powders, or a free-standing, porous solid or foam, is described. To prepare free-flowing powders, a fluidized bed is maintained at a reaction temperature of about room temperature to 60 DEG C and is contacted with finely divided droplets of a 30 to 85 % by weigth aqueous H2O2 solution. Preferably the fluidized bed temperature is about 35 DEG -45 DEG C, a 5-70 % H2O2 solution is used, and the feed rate of introduction of the H2O2 solution is about 5-50 g/minute/kg PVP present. The PVP-H2O2 product preferably contains about 15-24 %, preferably 18-22 %, H2O2 (1:1 molar ratio) and less than about 5 % water.

    Abstract translation: 描述了以自由流动的粉末或独立的多孔固体或泡沫的形式生产PVP-H 2 O 2产物的方法。 为了制备自由流动的粉末，将流化床保持在约室温至60℃的反应温度，并通过重量百分比的H 2 O 2水溶液与30至85％的细分散液滴接触。 优选地，流化床温度为约35-45℃，使用5-70％H 2 O 2溶液，并且所述H 2 O 2溶液的引入速率为约5-50g /分钟/ kg存在的PVP。 PVP-H 2 O 2产物优选含有约15-24％，优选18-22％的H 2 O 2（1:1摩尔比）和小于约5％的水。

    ASYMMETRICAL POLYPYRROLIDONYL COMPOUNDS HAVING A WIDE LIQUID RANGE
    10.
    发明申请
    ASYMMETRICAL POLYPYRROLIDONYL COMPOUNDS HAVING A WIDE LIQUID RANGE 审中-公开
    具有宽液体范围的非对称聚对苯二甲酸酯化合物

    公开(公告)号：WO1994020462A1

    公开(公告)日：1994-09-15

    申请号：PCT/US1994001460

    申请日：1994-02-08

    Applicant: ISP INVESTMENTS INC.

    Inventor： ISP INVESTMENTS INC. ,  MANDELLA, William, L. ,  TAYLOR, Paul, D. ,  SMITH, Terry, E.

    IPC: C07D207/267

    CPC classification number: C07D207/27

    Abstract: This invention relates to non-polymeric, asymmetrical, low freezing, high boiling, aliphatic compounds containing from 2 to 5 pyrrolidonyl rings and from 13 to 40 carbon atoms which melt below 0 DEG C and which boil above 300 DEG C at atmospheric pressure and to the synthesis and use of said liquid polypyrrolidonyl compounds.

    Abstract translation: 本发明涉及含有2至5个吡咯烷酮环和13至40个碳原子的非聚合物，不对称，低冷冻，高沸点脂肪族化合物，其熔点低于0℃，在大气压下沸腾至高于300℃， 所述液体聚吡咯烷酮化合物的合成和使用。

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