公开(公告)号：WO1996020694A1

公开(公告)日：1996-07-11

申请号：PCT/US1995016292

申请日：1995-12-14

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  LIU, Kou-Chang ,  ROCAFORT, Colleen, M.

IPC: A61K09/12

CPC classification number: A61K8/8182 ,  A61K8/046 ,  A61Q5/06 ,  Y10S424/01 ,  Y10S424/02 ,  Y10S514/957

Abstract: Low voc hair spray fixative compositions containing a fixative which is a tetramer of vinyl pyrrolidone, vinyl caprolactam, 3-(N-dimethylaminopropyl) methacrylamide and a C8-C18 alkyl acrylamide or acrylate, in predetermined compositional ranges of each monomer, and molecular weight, are described. The hair spray compositions herein are clear and low in viscosity, and form a spray of relatively small particle size which spreads evenly on the hair of the user as clear films which exhibit an effective high humidity curl retention property, good stiffness, and low tack and short drying times.

Abstract translation: 含有在各单体的预定组成范围内的乙烯基吡咯烷酮，乙烯基己内酰胺，3-（N-二甲基氨基丙基）甲基丙烯酰胺和C 8 -C 18烷基丙烯酰胺或丙烯酸酯的四聚物的固定剂的低调式发胶固定剂组合物和分子量， 被描述。 本发明的喷发组合物是透明且粘度低的，并且形成相对较小粒度的喷雾，其均匀地分布在使用者的头发上，作为透明膜，其表现出有效的高湿度卷曲保持性，良好的刚度和低粘性， 干燥时间短

公开(公告)号：WO1997021427A1

公开(公告)日：1997-06-19

申请号：PCT/US1996014928

申请日：1996-09-10

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  ULMER, Herbert ,  ROCAFORT, Colleen, M.

IPC: A61K09/12

CPC classification number: A61Q5/06 ,  A61K8/046 ,  A61K8/8164 ,  Y10S424/01 ,  Y10S424/02 ,  Y10S514/957

Abstract: A hair spray composition of 80 % or less VOC includes a fixative which is the half-ester of a copolymer of maleic anhydride and methyl vinyl ether having advantageous physical and performance properties even at low fixative levels. The copolymer is made by polymerizing the monomers at a selected temperature in the presence of a predetermined amount of a polymerization initiator whose decomposition fragments are soluble in hydroalcoholic solutions containing high levels of water. The composition is clear and without precipitate formation, has a low weight average molecular weight and a narrow molecular weight distribution, or polydispersity, affording a low solution viscosity. The composition also forms a spray pattern of small particle size, providing clear, hard fixative films with superior adhesion to the hair of the user, an advantageous high humidity curl retention (hold), and low tack and dry times, in both pump and aerosol products.

Abstract translation: 80％或更低VOC的喷发组合物包括固定剂，其即使在低固定水平下也具有有利的物理和性能特性的马来酸酐和甲基乙烯基醚的共聚物的半酯。 共聚物是通过在预定量的聚合引发剂存在下在选定温度下聚合单体制备的，其分解片段可溶于含有高含量水的水醇溶液。 该组合物是透明的且没有沉淀物形成，具有低重均分子量和窄分子量分布或多分散性，提供低溶液粘度。 该组合物还形成小粒径的喷雾图案，提供清晰，硬的固定膜，具有优于使用者头发的粘附性，在泵和气溶胶中有利的高湿度卷曲保持（保持）和低粘性和干燥时间 产品。

公开(公告)号：WO1996020691A1

公开(公告)日：1996-07-11

申请号：PCT/US1995016803

申请日：1995-12-22

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  SHIH, Jenn, S. ,  ROCAFORT, Colleen, M. ,  LOGIN, Robert, B.

IPC: A61K07/11

CPC classification number: A61K8/046 ,  A61K8/8182 ,  A61Q5/06 ,  Y10S424/02

Abstract: A low VOC (volatile organic compounds) hair spray composition having a combination of desirable user performance characteristics is described herein. The hair fixative resin in the composition is a terpolymer of 40-75 % by weight of a vinyl lactam, preferably vinyl pyrrolidone, 15-40 % of a polymerizable carboxylic acid, preferably acrylic acid or methacrylic acid, and 5-25 % of a hydrophobic monomer, preferably a long chain alkyl (C8-C24) acrylate, methacrylate, acrylamide or methacrylamide. The terpolymer has a K-value of 30-55, preferably 40-50, which provides compositions having good sprayability in both pump and aerosol form, and small, fine spray particles.

Abstract translation: 本文描述了具有期望的用户性能特征的组合的低VOC（挥发性有机化合物）喷发组合物。 组合物中的头发固定树脂是40-75重量％的乙烯基内酰胺，优选乙烯基吡咯烷酮，15-40％的可聚合羧酸，优选丙烯酸或甲基丙烯酸，和5-25％ 疏水单体，优选长链烷基（C 8 -C 24）丙烯酸酯，甲基丙烯酸酯，丙烯酰胺或甲基丙烯酰胺。 三元共聚物的K值为30-55，优选为40-50，其提供在泵和气溶胶形式以及小的细小喷雾颗粒中具有良好喷雾性的组合物。

公开(公告)号：WO1996019971A1

公开(公告)日：1996-07-04

申请号：PCT/US1995016667

申请日：1995-12-13

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  LIU, Kou-Chang ,  ROCAFORT, Colleen, M. ,  ANDERSON, Lowell, R. ,  REUVEN, Yakir

IPC: A61K09/12

CPC classification number: A61K8/8182 ,  A61K8/046 ,  A61Q5/06 ,  Y10S424/01 ,  Y10S424/02 ,  Y10S514/957 ,  C08F226/06 ,  C08F226/10 ,  C08F220/60

Abstract: Low VOC hair spray resin compositions containing homogeneous terpolymers of vinyl pyrrolidone, vinyl caprolactam and 3-(N-dimethylaminopropyl) methacrylamide are described. The hair spray compositions are made using a solution of the terpolymer which is clear and low in viscosity, and which provides a spray of relative small particle size. The hair spray compositions exhibit an effective high humidity curl retention property.

Abstract translation: 描述了含有乙烯基吡咯烷酮，乙烯基己内酰胺和3-（N-二甲基氨基丙基）甲基丙烯酰胺的均匀三元共聚物的低VOC喷发树脂组合物。 发胶组合物是使用透明且粘度低的三元共聚物溶液制成的，并提供相对较小粒度的喷雾。 喷发组合物显示出有效的高湿度卷曲保持性。

公开(公告)号：WO1996006592A1

公开(公告)日：1996-03-07

申请号：PCT/US1995006466

申请日：1995-05-22

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  ROCAFORT, Colleen, M.

IPC: A61K07/11

CPC classification number: A61Q5/06 ,  A61K8/046 ,  A61K8/8182 ,  Y10S424/01 ,  Y10S514/957

Abstract: This invention relates to a 0.5 to 7 wt.% solids hair fixative composition having superior moisture resistant hold and minimal tack duration which provides a stiff film on artificial or human hair and superior hair combability, which composition essentially contains a resin mixture of (a) a terpolymer derived from about 17 to about 30 wt.% N-vinyl pyrrolidone, from about 60 to about 80 wt.% N-vinyl caprolactam and from about 3 to about 6 wt.% di-C1-C4 alkyl amino-C1-C4alkyl-acrylate or methacrylate having a number average molecular weight of between about 20,000 and about 200,000 and (b) an N-vinyl pyrrolidone/vinyl acetate copolymer having a number average molecular weight of between about 10,000 and about 100,000; combined in a weight ratio of 1.4-6:1 (a) to (b). In the present composition, the vinyl acetate moiety of N-vinyl pyrrolidone/vinyl acetate copolymer interacts with resin (a) to reinforce stiffness and holding properties under conditions of extremely high humidity and materially lowers the duration of tackiness during drying.

Abstract translation: 本发明涉及0.5至7重量％固体发丝固定剂组合物，其具有优异的防潮保持性和最小的粘着持续时间，其在人造或人发上提供硬膜，并具有优异的头发可梳理性，该组合物基本上含有（a） 衍生自约17至约30重量％的N-乙烯基吡咯烷酮，约60至约80重量％的N-乙烯基己内酰胺和约3至约6重量％的二-C 1 -C 4烷基氨基-C1- 数均分子量为约20,000至约200,000的C 4烷基 - 丙烯酸酯或甲基丙烯酸酯和（b）数均分子量为约10,000至约100,000的N-乙烯基吡咯烷酮/乙酸乙烯酯共聚物; 组合重量比为1.4-6：1（a）至（b）。 在本发明的组合物中，N-乙烯基吡咯烷酮/乙酸乙烯酯共聚物的乙酸乙烯酯部分与树脂（a）相互作用，以在非常高的湿度条件下增强刚度和保持性能，并且在干燥期间粘性持续时间大大降低。

公开(公告)号：EP0820268A1

公开(公告)日：1998-01-28

申请号：EP95943962.0

申请日：1995-12-22

Applicant: ISP INVESTMENTS INC.

Inventor： SHIH, Jenn, S. ,  ROCAFORT, Colleen, M. ,  LOGIN, Robert, B.

IPC: A61K8 ,  A61Q5

CPC classification number: A61K8/046 ,  A61K8/8182 ,  A61Q5/06 ,  Y10S424/02

Abstract: A low VOC (volatile organic compounds) hair spray composition having a combination of desirable user performance characteristics is described herein. The hair fixative resin in the composition is a terpolymer of 40-75 % by weight of a vinyl lactam, preferably vinyl pyrrolidone, 15-40 % of a polymerizable carboxylic acid, preferably acrylic acid or methacrylic acid, and 5-25 % of a hydrophobic monomer, preferably a long chain alkyl (C8-C24) acrylate, methacrylate, acrylamide or methacrylamide. The terpolymer has a K-value of 30-55, preferably 40-50, which provides compositions having good sprayability in both pump and aerosol form, and small, fine spray particles.

公开(公告)号：EP0865273B1

公开(公告)日：2004-07-28

申请号：EP96931627.2

申请日：1996-09-10

Applicant: ISP INVESTMENTS INC.

Inventor： ULMER, Herbert ,  ROCAFORT, Colleen, M.

IPC: A61K9/12 ,  A61K7/06

CPC classification number: A61Q5/06 ,  A61K8/046 ,  A61K8/8164 ,  Y10S424/01 ,  Y10S424/02 ,  Y10S514/957

公开(公告)号：EP0865273A1

公开(公告)日：1998-09-23

申请号：EP96931627.0

申请日：1996-09-10

Applicant: ISP INVESTMENTS INC.

Inventor： ULMER, Herbert ,  ROCAFORT, Colleen, M.

IPC: A61K8 ,  A61Q5

CPC classification number: A61Q5/06 ,  A61K8/046 ,  A61K8/8164 ,  Y10S424/01 ,  Y10S424/02 ,  Y10S514/957

Abstract: A hair spray composition of 80 % or less VOC includes a fixative which is the half-ester of a copolymer of maleic anhydride and methyl vinyl ether having advantageous physical and performance properties even at low fixative levels. The copolymer is made by polymerizing the monomers at a selected temperature in the presence of a predetermined amount of a polymerization initiator whose decomposition fragments are soluble in hydroalcoholic solutions containing high levels of water. The composition is clear and without precipitate formation, has a low weight average molecular weight and a narrow molecular weight distribution, or polydispersity, affording a low solution viscosity. The composition also forms a spray pattern of small particle size, providing clear, hard fixative films with superior adhesion to the hair of the user, an advantageous high humidity curl retention (hold), and low tack and dry times, in both pump and aerosol products.