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1.发明申请ANODICALLY ASSISTED CHEMICAL ETCHING OF CONDUCTIVE POLYMERS AND POLYMER COMPOSITES 审中-公开导电聚合物和聚合物复合材料的阳极辅助化学蚀刻
公开(公告)号：WO2010139051A1
公开(公告)日：2010-12-09
申请号：PCT/CA2010/000811
申请日：2010-05-28
Applicant: INTEGRAN TECHNOLOGIES, INC. , MCCREA, Jonathan , PANAGIOTOPOULOS, Konstantinos , KATUGAHA, Herath , TOMANTSCHGER, Klaus
IPC: C25F3/02 , C08J7/04 , C08K3/00 , C08L101/12
CPC classification number: C08J7/12 , C23C18/1641 , C23C18/1653 , C23C18/2093 , C23C18/22 , C23C18/42 , C25D5/54 , C25D5/56 , C25F3/02
Abstract: A novel activation/etch method is disclosed for conductive polymer substrates and conductive polymer composite substrates to achieve good adhesion to subsequently applied coatings. The method in a preferred case involves anodically polarizing conductive polymers/polymer composites in aqueous etching solutions.
Abstract translation: 公开了用于导电聚合物基底和导电聚合物复合基底的新型激活/蚀刻方法，以实现对随后施加的涂层的良好粘附。 在优选情况下的方法涉及在水性蚀刻溶液中的阳极极化导电聚合物/聚合物复合材料。
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公开(公告)号：WO2022126241A1
公开(公告)日：2022-06-23
申请号：PCT/CA2021/051607
申请日：2021-11-12
Applicant: INTEGRAN TECHNOLOGIES INC.
Inventor： PALUMBO, Gino , TOMANTSCHGER, Klaus , MCCREA, Jonathan , LIMOGES, David Lionel
Abstract: Sacrificial inserts for use in gas turbine engines to reduce friction and wear damage between compressor fan blades and the fan rotors are disclosed. The consumable metallic shims have low friction and reduce fretting and galling on fan blade roots and fan rotor dovetail slots thereby increasing their operating lives, as well as reduce engine noise and improve engine efficiency. The electroformed, compliant, multi-purpose shims may have variable thickness and, when positioned between the blade dovetail root and the rotor disk dovetail slot, prevent movement and slippage between air foil blades and the rotor.
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公开(公告)号：WO2010139054A1
公开(公告)日：2010-12-09
申请号：PCT/CA2010/000816
申请日：2010-05-31
Applicant: INTEGRAN TECHNOLOGIES, INC. , FACCHINI, Diana , GONZALEZ, Francisco , MCCREA, Jonathan , UETZ, Mike , PALUMBO, Gino , TOMANTSCHGER, Klaus , NAGARAJAN, Nandakumar , VICTOR, Jared J. , ERB, Uwe
Inventor： FACCHINI, Diana , GONZALEZ, Francisco , MCCREA, Jonathan , UETZ, Mike , PALUMBO, Gino , TOMANTSCHGER, Klaus , NAGARAJAN, Nandakumar , VICTOR, Jared J. , ERB, Uwe
Abstract: Free standing articles or articles at least partially coated with substantially porosity free, fine-grained and/or amorphous Co-bearing metallic materials optionally containing solid particulates dispersed therein, are disclosed. The electrodeposited metallic layers and/or patches comprising Co provide, enhance or restore strength, wear and/or lubricity of substrates without reducing the fatigue performance compared to either uncoated or equivalent thickness Cr coated substrate. The fine-grained and/or amorphous metallic coatings comprising Co are particularly suited for articles exposed to thermal cycling, fatigue and other stresses and/or in applications requiring anti-microbial and hydrophobic properties.
Abstract translation: 公开了至少部分地涂覆有基本上无孔隙的细颗粒和/或无定形的含Co金属材料的任选地含有分散在其中的固体颗粒的独立制品或制品。 包含Co的电沉积金属层和/或贴剂提供，增强或恢复基材的强度，磨损和/或润滑性，而不降低与未涂覆或等效厚度的Cr涂覆的基材相比的疲劳性能。 包含Co的细晶粒和/或无定形金属涂层特别适用于暴露于热循环，疲劳和其他应力的物品和/或需要抗微生物和疏水性质的应用中。
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4.发明申请PROCESS FOR ELECTROPLATING METALLIC AND METALL MATRIX COMPOSITE FOILS, COATINGS AND MICROCOMPONENTS 审中-公开电镀金属和金属基复合材料，涂料和微生物的方法
公开(公告)号：WO2004001100A1
公开(公告)日：2003-12-31
申请号：PCT/EP2002/007023
申请日：2002-06-25
Applicant: INTEGRAN TECHNOLOGIES, INC. , PALUMBO, Gino , BROOKS, Iain , MCCREA, Jonathan , HIBBARD, Glenn, D. , GONZALEZ, Francisco , TOMANTSCHGER, Klaus , ERB, Uwe
Inventor： PALUMBO, Gino , BROOKS, Iain , MCCREA, Jonathan , HIBBARD, Glenn, D. , GONZALEZ, Francisco , TOMANTSCHGER, Klaus , ERB, Uwe
IPC: C25D1/04
CPC classification number: C25D1/04 , C25D5/02 , C25D5/06 , C25D5/08 , C25D5/18 , C25D5/20 , C25D7/04 , C25D15/00 , C25D15/02
Abstract: The invention relates to a process for forming coatings or free-standing deposits of nano-crystalline metals, metal alloys or metal matrix composites. The process employs drum plating or selective plating processes involving pulse electrode-position and a non-stationary anode or cathode. Novel nano-crystalline metal matrix composites and micro components are disclosed as well. Also described is a process for forming micro-components with grain sizes below 1,000nm.
Abstract translation: 本发明涉及一种用于形成纳米结晶金属，金属合金或金属基质复合材料的涂层或独立沉积物的方法。 该方法采用包括脉冲电极位置和非固定阳极或阴极的鼓电镀或选择性电镀工艺。 还公开了新颖的纳米晶体金属基复合材料和微型组件。 还描述了一种用于形成粒度小于1000nm的微组件的方法。
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5.发明申请
公开(公告)号：WO2021184114A1
公开(公告)日：2021-09-23
申请号：PCT/CA2021/050349
申请日：2021-03-16
Applicant: INTEGRAN TECHNOLOGIES INC.
Inventor： PALUMBO, Gino , MONACO, Leo , MCCREA, Jonathan , TOMANTSCHGER, Klaus , LIMOGES, Dave , MILLS, Michael
Abstract: An apparatus and system for in-situ electropolishing and/or for in-situ electroforming a structural or functional reinforcement layer such as a sleeve of a selected metallic material on the internal surfaces of metallic tubular conduits are described. The apparatus and system can be employed on straight tubes, tube joints to different diameter tubes or face plates, tube elbows and other complex shapes encountered in piping systems. The apparatus includes components which can be independently manipulated and assembled on or near a degraded site and, after secured in place, form an electrolytic cell within the workpiece. The apparatus contains counter-electrodes which can be moved relative to the workpiece surface during the electroplating and/or electropolishing operation to provide flexibility in selecting and employing electropolishing process parameters and electroplating process parameters to design and optimize the surface roughness as well as the size, shape and properties of the electrodeposited reinforcing layer(s).
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Patent Agency Ranking
公开(公告)号：WO2014001401A1
公开(公告)日：2014-01-03
申请号：PCT/EP2013/063418
申请日：2013-06-26
Applicant: INTEGRAN TECHNOLOGIES INC. , BROOKS, Iain
Inventor： BROOKS, Iain , MCCREA, Jonathan , KATUGAHA, Herath , PALUMBO, Gino , PANAGIOTOPOULOS, Konstantinos , NAGARAJAN, Nandakumar , HIRMER, Gerhard
CPC classification number: C25D5/50 , B05D2201/06 , B32B15/06 , B32B15/18 , B32B15/20 , B32B25/08 , B32B27/20 , B32B2255/10 , B32B2255/205 , B32B2255/26 , B32B2262/106 , B32B2307/202 , B32B2307/702 , B32B2307/704 , B32B2307/714 , B32B2457/00 , B32B2605/00 , B32B2605/18 , C23C18/1653 , C23C18/2086 , C23C24/04 , H05K3/387 , Y10T428/31522 , Y10T428/31678
Abstract: An article of manufacture includes a substrate having an outer surface clad with a metal construct including one or more continuous metal layers, at least one of which is an amorphous layer or a microcrystalline layer having a grain size below 5000 nm. A bonding layer is provided between the substrate and the layered metallic construct so that the bonding layer is in direct contact with the substrate and with the layered metallic construct. The bonding layer is made of a substantially fully cured resin including at least 10% of a rubber. The layered metallic construct has peel strength greater than 10N/cm. Also provided is a process for making the article including coating an article outer surface with a bonding layer and a layered metallic construct. The bonding layer is substantially fully cured before the layered metal construct is bonded to the article. The coated article is annealed.
Abstract translation: 一种制品包括具有外表面的基材，该外表面包括金属构件，该金属构件包括一个或多个连续金属层，其中至少一个是非晶层或具有低于5000nm的晶粒尺寸的微晶层。 在基板和层状金属构造体之间设置粘合层，使得粘结层与基底和层状金属构件直接接触。 粘合层由包括至少10％的橡胶的基本完全固化的树脂制成。 层状金属构造物的剥离强度大于10N / cm。 还提供了一种用于制造制品的方法，包括用粘结层和层状金属构造物涂覆制品外表面。 在层状金属构造物结合到制品之前，粘合层基本上完全固化。 涂层制品退火。
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7.发明申请METAL-COATED POLYMER ARTICLE OF HIGH DURABILITY AND VACUUM AND/OR PRESSURE INTEGRITY 审中-公开金属涂层聚合物具有高耐久性和真空和/或压力完整性的物品
公开(公告)号：WO2010139052A1
公开(公告)日：2010-12-09
申请号：PCT/CA2010/000812
申请日：2010-05-28
Applicant: INTEGRAN TECHNOLOGIES, INC. , MCCREA, Jonathan , GONZALEZ, Francisco , PALUMBO, Gino , TOMANTSCHGER, Klaus , EMRICH, Rich , PANAGIOTOPOULOS, Konstantinos , PASQUANTONIO, Mary , KRATOCHWIL, John , KATUGAHA, Herath
Inventor： MCCREA, Jonathan , GONZALEZ, Francisco , PALUMBO, Gino , TOMANTSCHGER, Klaus , EMRICH, Rich , PANAGIOTOPOULOS, Konstantinos , PASQUANTONIO, Mary , KRATOCHWIL, John , KATUGAHA, Herath
IPC: C23C16/06
CPC classification number: B32B15/08 , B32B5/16 , B32B15/043 , B32B15/16 , B32B27/14 , C08J7/04 , C08J7/045 , C08J7/123 , C08J2323/06 , C23C18/1601 , C23C18/165 , C23C18/20 , C23C18/2006 , C23C18/2013 , C23C18/2086 , C23C18/2093 , C23C18/22 , C23C18/30 , C23C24/04 , C23C28/00 , C23C28/021 , C23C28/023 , C25D7/00 , Y10T428/12049 , Y10T428/12479 , Y10T428/12882 , Y10T428/13 , Y10T428/131 , Y10T428/1314 , Y10T428/1321 , Y10T428/1355 , Y10T428/1359 , Y10T428/1372 , Y10T428/1376 , Y10T428/1379 , Y10T428/1386 , Y10T428/1393 , Y10T428/24997 , Y10T428/25 , Y10T428/256 , Y10T428/257 , Y10T428/259 , Y10T428/269 , Y10T428/31678
Abstract: Metal-coated polymer articles containing structural substantially porosity-free, fine-grained and/or amorphous metallic coatings/layers optionally containing solid particulates dispersed therein on polymer substrates, are disclosed. The substantially porosity-free metallic coatings/layers/patches are applied to polymer or polymer composite substrates to provide, enhance or restore vacuum/pressure integrity and fluid sealing functions. Due to the excellent adhesion between the metallic coating and the polymer article satisfactory thermal cycling performance is achieved. The invention can also be employed as a repair/refurbishment technique. The fine-grained and/or amorphous metallic coatings are particularly suited for strong and lightweight articles, precision molds, sporting goods, aerospace and automotive parts and other components exposed to thermal cycling and stress created by erosion and impact damage.
Abstract translation: 公开了含有基本上无孔隙结构，细粒度和/或无定形金属涂层/层的金属涂覆的聚合物制品，其任选地含有分散在聚合物基材上的固体颗粒。 将基本上无孔隙的金属涂层/层/贴片施加到聚合物或聚合物复合基材上以提供，增强或恢复真空/压力完整性和流体密封功能。 由于金属涂层和聚合物制品之间优异的粘附性，可实现令人满意的热循环性能。 本发明也可以用作维修/翻新技术。 细粒度和/或无定形金属涂层特别适用于强而轻的制品，精密模具，运动用品，航空航天和汽车零件以及其他暴露于热循环和其他由侵蚀和冲击损坏产生的应力的部件。
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公开(公告)号：WO2010139053A1
公开(公告)日：2010-12-09
申请号：PCT/CA2010/000815
申请日：2010-05-31
Applicant: INTEGRAN TECHNOLOGIES, INC. , TOMANTSCHGER, Klaus , MCCREA, Jonathan , NAGARAJAN, Nandakumar , GONZALEZ, Francisco , PALUMBO, Gino , PANAGIOTOPOULOS, Konstantinos , KATUGAHA, Herath , FACCHINI, Diana , VICTOR, Jared J. , ERB, Uwe
Inventor： TOMANTSCHGER, Klaus , MCCREA, Jonathan , NAGARAJAN, Nandakumar , GONZALEZ, Francisco , PALUMBO, Gino , PANAGIOTOPOULOS, Konstantinos , KATUGAHA, Herath , VICTOR, Jared J. , ERB, Uwe
CPC classification number: C23C18/1641 , A63B59/70 , A63B2102/24 , B32B1/08 , B32B3/30 , B32B7/02 , B32B15/08 , B32B15/18 , B32B15/20 , B32B27/08 , B32B27/16 , B32B27/18 , B32B27/20 , B32B27/281 , B32B27/285 , B32B27/288 , B32B27/302 , B32B27/304 , B32B27/308 , B32B27/32 , B32B27/322 , B32B27/34 , B32B27/36 , B32B27/365 , B32B27/38 , B32B27/40 , B32B27/42 , B32B2255/06 , B32B2255/10 , B32B2255/20 , B32B2255/205 , B32B2262/101 , B32B2262/106 , B32B2264/02 , B32B2264/10 , B32B2264/12 , B32B2270/00 , B32B2307/202 , B32B2307/212 , B32B2307/30 , B32B2307/51 , B32B2307/538 , B32B2307/54 , B32B2307/718 , B32B2457/00 , B32B2509/00 , B32B2535/00 , B32B2597/00 , B32B2605/00 , C09J163/00 , C23C14/021 , C23C14/024 , C23C14/028 , C23C16/0227 , C23C16/0254 , C23C16/0272 , C23C18/1851 , C23C18/1855 , C23C18/1893 , C23C18/1896 , C25D5/54 , Y10T428/12111 , Y10T428/12389 , Y10T428/12451 , Y10T428/12472 , Y10T428/12569 , Y10T428/12944 , Y10T428/1355 , Y10T428/24355 , Y10T428/24545 , Y10T428/24612 , Y10T428/26 , Y10T428/269
Abstract: Metal-clad polymer articles containing structural fine-grained and/or amorphous metallic coatings/layers optionally containing solid particulates dispersed therein, are disclosed. The fine-grained and/or amorphous metallic coatings are particularly suited for strong and lightweight articles, precision molds, sporting goods, automotive parts and components exposed to thermal cycling although the coefficient of linear thermal expansion (CLTE) of the metallic layer and the substrate are mismatched. The interface between the metallic layer and the polymer is suitably pretreated to withstand thermal cycling without failure.
Abstract translation: 公开了包含分散在其中的任选地含有固体颗粒的结构细晶粒和/或非晶金属涂层/层的金属包层聚合物制品。 细晶粒和/或非晶金属涂层特别适用于强而轻的制品，精密模具，运动用品，暴露于热循环的汽车部件和部件，尽管金属层和基材的线性热膨胀系数（CLTE） 不匹配。 金属层和聚合物之间的界面适当地经过预处理以承受热循环而不失败。
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9.发明申请
公开(公告)号：WO2006063469A1
公开(公告)日：2006-06-22
申请号：PCT/CA2005/001925
申请日：2005-12-16
Applicant: INTEGRAN TECHNOLOGIES, INC.
Inventor： PALUMBO, Gino , MCCREA, Jonathan , TOMANTSCHGER, Klaus , BROOKS, Iain , JEONG, Daehyun , LIMOGES, Dave , PANAGIOTOPOULOS, Konstantinos , ERB, Uwe
CPC classification number: C25D7/00 , A01K87/00 , A45B9/00 , A63B49/02 , A63B49/10 , A63B49/12 , A63B53/04 , A63B53/0466 , A63B53/047 , A63B53/10 , A63B53/12 , A63B59/00 , A63B59/50 , A63B60/54 , A63B2053/0416 , A63B2209/00 , A63B2209/023 , B82Y30/00 , C23C26/00 , C25D5/00 , C25D15/02 , F42B5/30 , Y10T428/12049 , Y10T428/12201 , Y10T428/12569 , Y10T428/1321 , Y10T428/24612 , Y10T428/249941 , Y10T428/31507 , Y10T428/31511 , Y10T428/31681 , Y10T428/31685 , Y10T428/31692
Abstract: Lightweight articles comprising a polymeric material at least partially coated with a fine-grained metallic material are disclosed. The fine-grained metallic material has an average grain size of 2nm to 5,000nm, a thickness between 25 micron and 5cm, and a hardness between 200VHN and 3,000 VHN. The lightweight articles are strong and ductile and exhibit high coefficients of restitution and a high stiffness and are particularly suitable for a variety of applications including aerospace and automotive parts, sporting goods, and the like.
Abstract translation: 公开了包含至少部分涂覆有细粒金属材料的聚合材料的轻质制品。 细晶金属材料的平均晶粒尺寸为2nm至5,000nm，厚度为25微米至5cm，硬度为200VHN至3,000VHN。 轻型制品是坚固的和延展性的并且表现出高的恢复系数和高刚度，并且特别适用于各种应用，包括航空航天和汽车零件，运动用品等。
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10.发明申请
公开(公告)号：WO2006063468A1
公开(公告)日：2006-06-22
申请号：PCT/CA2005/001923
申请日：2005-12-16
Applicant: INTEGRAN TECHNOLOGIES, INC.
Inventor： PALUMBO, Gino , MCCREA, Jonathan , TOMANTSCHGER, Klaus , BROOKS, Iain , JEONG, Daehyun , LIMOGES, Dave , PANAGIOTOPOULOS, Konstantinos , ERB, Uwe
CPC classification number: C25D7/00 , A01K87/00 , A45B9/00 , A63B49/02 , A63B49/10 , A63B49/12 , A63B53/04 , A63B53/10 , A63B53/12 , A63B59/00 , A63B59/50 , A63B59/70 , A63B60/54 , A63B2053/0416 , A63B2209/00 , A63B2209/02 , A63B2209/023 , B82Y30/00 , C23C24/04 , C23C28/021 , C23C28/027 , C25D5/00 , C25D7/0607 , C25D15/02 , F41H5/0457 , F42B5/30 , F42B6/04 , F42B12/80 , Y10T428/12028 , Y10T428/12063 , Y10T428/12146 , Y10T428/12292 , Y10T428/12493 , Y10T428/12535 , Y10T428/12597 , Y10T428/12674 , Y10T428/12701 , Y10T428/12708 , Y10T428/12736 , Y10T428/12743 , Y10T428/1275 , Y10T428/12757 , Y10T428/12764 , Y10T428/12778 , Y10T428/12937 , Y10T428/12972 , Y10T428/13 , Y10T428/24942 , Y10T428/256 , Y10T428/26 , Y10T428/2918 , Y10T428/2956 , Y10T428/2958 , Y10T428/2964 , Y10T428/30 , Y10T428/31678
Abstract: Fine-grained (average grain size 1nm to 1,000nm) metallic coatings optionally containing solid particulates dispersed therein are disclosed. The fine-grained metallic materials are significantly harder and stronger than conventional coatings of the same chemical composition due to Hall-Petch strengthening and have low linear coefficients of thermal expansion (CTEs). The invention provides means for matching the CTE of the fine-grained metallic coating to the one of the substrate by adjusting the composition of the alloy and/or by varying the chemistry and volume fraction of particulates embedded in the coating. The fine-grained metallic coatings are particularly suited for strong and lightweight articles, precision molds, sporting goods, automotive parts and components exposed to thermal cycling. The low CTEs and the ability to match the CTEs of the fine-grained metallic coatings with the CTEs of the substrate minimize dimensional changes during thermal cycling and prevent premature failure.
Abstract translation: 公开了细颗粒（平均晶粒尺寸1nm至1,000nm）金属涂层，其任选地含有分散在其中的固体颗粒。 由于Hall-Petch强化，细粒金属材料比同一化学成分的常规涂层显着更硬和更强，并且具有低线性热膨胀系数（CTE）。 本发明提供了通过调节合金的组成和/或通过改变嵌入涂层中的微粒的化学和体积分数来匹配细粒金属涂层的CTE与基体之一的方法。 细粒金属涂层特别适用于强而轻的制品，精密模具，运动用品，汽车零件和暴露于热循环的部件。 低CTE和将细粒金属涂层的CTE与衬底的CTE匹配的能力使热循环期间的尺寸变化最小化并防止过早失效。
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