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公开(公告)号:CA2342461C
公开(公告)日:2007-11-20
申请号:CA2342461
申请日:2001-03-28
Applicant: JSR CORP
Inventor: YAMAKAWA YOSHITAKA , GOTO KOHEI , KAKUTA MAYUMI , ROZHANSKII IGOR
Abstract: A polyarylene copolymer which comprises (A) from 60 to 3 mol% aromatic compound units having a main chain containing one or more electron-withdrawing groups therein and (B) from 40 to 97 mol% aromatic compound units having a main chain containing no electron-withdrawing groups therein (provided that (A)+(B) = 100 mol%), and a proton-conductive membrane comprising the polyarylene copolymer having sulfonic acid groups.
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公开(公告)号:DE69822918D1
公开(公告)日:2004-05-13
申请号:DE69822918
申请日:1998-04-14
Applicant: JSR CORP
Inventor: MATSUBARA MINORU , INOUE YASUTATE , KAKUTA MAYUMI , ROZHANSKII IGOR , GOTO KOHEI
Abstract: Electronic parts and a process for manufacturing the electronic parts are provided. The electronic parts comprise an electric insulating material exhibiting a high heat resistance and low dielectric constant as a structural component. The electric insulating material is formed of a polyimide containing a recurring unit represented by the following general formula (1).
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公开(公告)号:DE60314816D1
公开(公告)日:2007-08-23
申请号:DE60314816
申请日:2003-08-21
Applicant: JSR CORP
Inventor: ROZHANSKII IGOR , TAKAHASHI MASAYUKI , GOTO KOHEI , KONNO YOUSUKE , OHTSUKI TOSHIHIRO , YAMAKAWA YOSHITAKA , KADOTA TOSHIAKI
IPC: C08G61/12 , C08J5/22 , C07C309/73 , C07C309/75 , C07C317/24 , C08G61/00 , C08G65/40 , H01B1/06 , H01M8/02 , H01M8/10
Abstract: Disclosed is an aromatic sulfonic acid ester derivative represented by the formula (1); in the formula, X is an atom or a group selected from a halogen atom excluding fluorine, -OSO3CH3 and -OSO3CF3, A is a divalent electron attractive group, B is a divalent electron donating group or a direct bonding, R is a hydrocarbon group of 1 to 20 carbon atoms, Ar is an aromatic group having a substituent of -SO3R (wherein R is a hydrocarbon group of 1 to 20 carbon atoms), m is an integer of 0 to 10, n is an integer of 0 to 10 and k is an integer of 1 to 4. Also disclosed is a process for producing a polyarylene having a sulfonic acid group, which process comprises the steps of coupling polymerization of an aromatic compound containing the derivative of the formula (1), to prepare a polyarylene and hydrolysis of the polyarylene, and which process has high safety and is easily capable of controlling the amount of sulfonoc acid group introduced into a polymer and the introducing position thereof.
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公开(公告)号:DE60116678D1
公开(公告)日:2006-04-06
申请号:DE60116678
申请日:2001-03-27
Applicant: JSR CORP
Inventor: GOTO KOHEI , YAMAKAWA YOSHITAKA , KAKUTA MAYUMI , ROZHANSKII IGOR
Abstract: A polyarylene copolymer which comprises (A) from 60 to 3 mol% aromatic compound units having a main chain containing one or more electron-withdrawing groups therein and (B) from 40 to 97 mol% aromatic compound units having a main chain containing no electron-withdrawing groups therein (provided that (A)+(B) = 100 mol%), and a proton-conductive membrane comprising the polyarylene copolymer having sulfonic acid groups.
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公开(公告)号:CA2342461A1
公开(公告)日:2001-09-29
申请号:CA2342461
申请日:2001-03-28
Applicant: JSR CORP
Inventor: GOTO KOHEI , ROZHANSKII IGOR , YAMAKAWA YOSHITAKA , KAKUTA MAYUMI
Abstract: A polyarylene copolymer which comprises (A) from 60 to 3 mol% aromatic compound units having a main chain containing one or more electron-withdrawing groups therein and (B) from 40 to 97 mol% aromatic compound unity having a main chain containing no electron-withdrawing groups therein (provided that (A) + (B) - 100 mol%), and a proton-conductive membrane comprising the polyarylene copolymer having sulfonic acid groups.
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公开(公告)号:CA2615492A1
公开(公告)日:2007-01-25
申请号:CA2615492
申请日:2006-06-30
Applicant: HONDA MOTOR CO LTD , JSR CORP
Inventor: FUKUDA KAORU , ROZHANSKII IGOR , HIGAMI MAKOTO , TAKAHASHI RYOICHIRO , SHINKAI HIROSHI , KANAOKA NAGAYUKI , YAMAKAWA YOSHITAKA
Abstract: This invention provides an electrode electrolyte for a solid polymer-type fuel cell, in which a cost problem and a problem related to recovery of catalyst metals are solved, having excellent proton conductivity, dimensional stability and heat resistance. An electrode electrolyte for a solid polymer electrolyte-type fuel cell contains a polymer, which has a polyphenylene structure as a main chain and both a sulfonic acid group and a nitrogen-containing heterocyclic group as a side chain. A side chain having the nitrogen-containing heterocyclic group has a structure represented by the following general formula (D) . (In formula, Z represents at least one kind of structures selected from a group consisting of a direct bond, -O- and -S-, Y represents at least one kind of structures selected from a group consisting of -CO-, -SO 2 -, -SO-, -CONH-, -COO-, -(CF 2 ) l - (l is an integer of 1 to 10) and -C(CF 3 ) 2 - and R 20 represents a nitrogen-containing heterocyclic group. q represents an integer of 1 to 5 and p represents an integer of 0 to 4.) The above nitrogen-containing heterocyclic group is at least one kind of group derived from a compound selected from the group consisting of nitrogen-containing heterocyclic compounds including pyrrole, thiazole, isothiazole, oxazole, isoxazole, pyridine, imidazole, imidazoline, pyrazole, 1,3,5-triazine, pyrimidine, pyridazine, pyrazine, indole, quinoline, isoquinoline, purine, benzimidazole, benzoxazole, benzothiazole, tetrazole, tetrazine, triazole, carbazole, acridine, quinoxaline and quinazoline and derivatives thereof.
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公开(公告)号:DE60116678T2
公开(公告)日:2006-08-24
申请号:DE60116678
申请日:2001-03-27
Applicant: JSR CORP
Inventor: GOTO KOHEI , YAMAKAWA YOSHITAKA , KAKUTA MAYUMI , ROZHANSKII IGOR
Abstract: A polyarylene copolymer which comprises (A) from 60 to 3 mol% aromatic compound units having a main chain containing one or more electron-withdrawing groups therein and (B) from 40 to 97 mol% aromatic compound units having a main chain containing no electron-withdrawing groups therein (provided that (A)+(B) = 100 mol%), and a proton-conductive membrane comprising the polyarylene copolymer having sulfonic acid groups.
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公开(公告)号:CA2438009A1
公开(公告)日:2004-02-22
申请号:CA2438009
申请日:2003-08-22
Applicant: JSR CORP
Inventor: KADOTA TOSHIAKI , TAKAHASHI MASAYUKI , ROZHANSKII IGOR , GOTO KOHEI , OHTSUKI TOSHIHIRO , YAMAKAWA YOSHITAKA , KONNO YOUSUKE
IPC: C08J5/22 , C07C309/73 , C07C309/75 , C07C317/24 , C08G61/00 , C08G61/12 , H01B1/06 , H01M8/02 , H01M8/10
Abstract: Disclosed is an aromatic sulfonic acid ester derivative represented by the formula (1); in the formula, X is an atom or a group selected from a halogen atom excluding fluorine, -OSO3CH3 and -OSO3CF3, A is a divalent electron attractive group, B is a divalent electron donating group or a direct bonding, R a is a hydrocarbon group of 1 to 20 carbon atoms, Ar is an aromatic group having a substituent of -SO3R b (wherein R b is a hydrocarbon group of 1 to 20 carbon atoms), m is an integer of 0 to 10, n is an integer of 0 to 10 and k is an integer of 1 to 4. Also disclosed is a process for producing a polyarylene having a sulfonic acid group, which process comprises the steps of coupling polymerization of an aromatic compound containing the derivative of the formula (1), to prepare a polyarylene and hydrolysis of the polyarylene, and which process has high safety and is easily capable of controlling the amount of sulfonoc acid group introduced into a polymer and the introducing position thereof.
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公开(公告)号:DE69801985T2
公开(公告)日:2002-04-11
申请号:DE69801985
申请日:1998-01-29
Applicant: JSR CORP
Inventor: AKIIKE TOSHIYUKI , SHIBA TADAHIRO , KONNO KEIJI , ROZHANSKII IGOR , GOTO KOHEI
IPC: C08G61/10 , C07C309/63
Abstract: The present invention is a process for producing a phenylene-containing polymer in the presence of a catalyst system containing a transition metal compound, and a film-forming material comprising the phenylene-containing polymer.
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公开(公告)号:CA2615494C
公开(公告)日:2011-08-09
申请号:CA2615494
申请日:2006-06-30
Applicant: JSR CORP
Inventor: HIGAMI MAKOTO , ROZHANSKII IGOR , YAMAKAWA YOSHITAKA
Abstract: A nitrogen-containing aromatic compound is represented by Formula (1). A polymer is obtained by polymerizing the compound. (see formula 1) wherein X is an atom or a group selected from halogen atoms other than fluorine and -OSO2Rb (wherein Rb is an alkyl group, a fluorine-substituted alkyl group or an aryl group) ; Y is at least one structure selected from the group consisting of -CO-, -SO2-, -SO-, -CONH-, -COO-, - (CF2) 1- (wherein 1 is an integer of 1 to 10) and -C (CF3) 2-; Z is at least one structure selected from the group consisting of a direct bond, -O- and -S-; R20 is a nitrogen-containing heterocyclic group; q is an integer of 1 to 5; and p is an integer of 0 to 4.
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