Abstract:
A cyclic olefin having a specific polar group is polymerized by addition polymerization in a hydrocarbon solvent, using a polymerization catalyst component containing (i) a specific transition metal compound, (ii) a Lewis acid compound and (iii) an alkyl aluminoxane, or the cyclic olefin is polymerized by addition polymerization in the hydrocarbon solvent, using the polymerization catalyst component, by further adding at least one aromatic vinyl compound and at least one cyclic nonconjugated polyene compound, or either one of them as a molecular weight modifier, thereby obtaining a cyclic olefinic addition polymer.
Abstract:
A cyclic olefin having a specific polar group is polymerized by addition polymerization in a hydrocarbon solvent, using a polymerization catalyst component containing (i) a specific transition metal compound, (ii) a Lewis acid compound and (iii) an alkyl aluminoxane, or the cyclic olefin is polymerized by addition polymerization in the hydrocarbon solvent, using the polymerization catalyst component, by further adding at least one aromatic vinyl compound and at least one cyclic nonconjugated polyene compound, or either one of them as a molecular weight modifier, thereby obtaining a cyclic olefinic addition polymer.
Abstract:
A cyclic olefin addition copolymer obtained by copolymerizing a cyclic olefin compound having a side chain substituent group with a ring structure, such as endo-tricycloÄ4.3.0.1 Üdeca-3,7-diene or endo-tricycloÄ4.3.0.1 Üdeca-3-ene, with another cyclic olefin compound such as bicycloÄ2.2.1Ühept-2-ene, and further with a cyclic olefin compound having a hydrolysable silyl group as needed, or hydrogenating after copolymerization; a composition for crosslinking in which a specific crosslinking agent is incorporated; a crosslinked product obtained by crosslinking the composition; an optical material containing the copolymer, the composition or the crosslinked product; and a method for producing the copolymer in which addition polymerization is conducted using a specific nickel catalyst.
Abstract:
A cycloolefin addition copolymer which is obtained by copolymerizing a cycloolefin compound having a side-chain substituent having a ring structure, such as endo-tricyclo[4.3.0.12,5]deca-3,7-diene or endo-tricyclo[4.3.0.12,5]deca-3-ene, with other cycloolefin compound such as bicyclo[2.2.1]hept-2-ene and optionally further with a cycloolefin compound having a hydrolyzable silyl group or by conducting the copolymerization and then hydrogenation; a crosslinkable composition comprising the copolymer and a specific crosslinking agent incorporated therein; a crosslinked object obtained by crosslinking the composition; an optical material comprising any of the copolymer, composition, and crosslinked object; and a process for producing the copolymer which comprises conducting addition polymerization using a specific nickel catalyst.
Abstract:
A cycloolefin having a specific polar group is polymerized by addition polymerization in a hydrocarbon solvent with the aid of a polymerization catalyst ingredient comprising (i) a specific transition metal compound, (ii) a Lewis acid compound, and (iii) an alkylaluminoxane to obtain a cycloolefin addition polymer. Alternatively, a cycloolefin is polymerized by addition polymerization in the hydrocarbon solvent with the aid of the polymerization catalyst ingredient in the presence of a molecular weight regulator comprising at least one aromatic vinyl compound or at least one cyclic unconjugated polyene compound or both to thereby obtain a cycloolefin addition polymer.
Abstract:
PROBLEM TO BE SOLVED: To obtain a near-infrared ray cut filter which has a wide viewing angle, is superior in near-infrared ray cutting capability, has a low hygroscopicity, and is free from foreign matters and warpage.SOLUTION: The near-infrared ray cut filter includes a resin substrate (I) containing a compound (I) which has a structure derived from a compound expressed by a formula (I).
Abstract:
PROBLEM TO BE SOLVED: To provide a polymer film composed of a cycloolefinic addition (co)polymer, a laminate film having excellent adhesion with the clad layer of a polymer light waveguide and a manufacturing method for the laminate film. SOLUTION: The laminate film has a hardened layer prepared by applying a hardening solution comprising (A) an oligomer of a radical polymerizable urethane (meth)acrylate having a structure meeting specified requirements, (B) a (meth)acrylate other than the urethane (meth)acrylate of (A) and (C) a photopolymerization initiator onto a polymer film composed of a polymer having one or more structural units meeting specified requirements and hardening the applied solution. COPYRIGHT: (C)2009,JPO&INPIT
Abstract:
PROBLEM TO BE SOLVED: To provide a polymer optical waveguide that is superior in properties, such as waveguide loss, refractive index, heat resistance, moisture resistance and flexibility and moreover, that is superior in processibility. SOLUTION: The polymer optical waveguide has formed a core and a clad comprising a hardened material of a photosensitive resin composition, containing two kinds of different (meth) acrylate containing an aromatic ring and photo radical polymerization initiator as components on a polymer film composed of cyclic olefin based addition copolymer. COPYRIGHT: (C)2009,JPO&INPIT
Abstract:
PROBLEM TO BE SOLVED: To improve adhesion/adhesive properties with another member by forming a film or a sheet having high appearance and shape stability without a wrinkle or a warp, providing a process which can remove the residual solvent of the film or the sheet and high transparency and heat resistance obtained by the process, improving destructive characteristics in forming of the film or the sheet by a solution casting process with a cycloolefin addition polymer. SOLUTION: The film or the sheet for an optical material is obtained by dissolving the cycloolefin addition polymer of a specific structure by using a mixed solvent containing a solvent (I) for dissolving the polymer at 25°C and having a boiling point at 1 atm or lower of 130°C or lower and a solvent (II) for not dissolving the polymer at a boiling point at 1 atm or lower of 150°C or lower for dissolving the polymer at 25°C as a cast solvent, and depositing the film by a solution casting process. COPYRIGHT: (C)2004,JPO