1.
    发明专利
    未知

    公开(公告)号:DE69513114T2

    公开(公告)日:2000-04-13

    申请号:DE69513114

    申请日:1995-01-20

    Applicant: KAO CORP

    Abstract: A process for producing an acyloxybenzenesulfonic acid or a salt thereof by sulfonating an acyloxybenzene (1) with the use of at least one additive selected from among carboxylic acids or esters (2), alkyl phosphates (3), polyphosphoric acids (4), amide and like compounds (6), carbonic ester compounds (7), and hydroxylic compounds (8). The process enables acyloxybenzenesulfonic acids with good hues to be produced industrially in high yields at a high selectivity and a low cost as compared with the conventional processes.

    2.
    发明专利
    未知

    公开(公告)号:DE69513114D1

    公开(公告)日:1999-12-09

    申请号:DE69513114

    申请日:1995-01-20

    Applicant: KAO CORP

    Abstract: A process for producing an acyloxybenzenesulfonic acid or a salt thereof by sulfonating an acyloxybenzene (1) with the use of at least one additive selected from among carboxylic acids or esters (2), alkyl phosphates (3), polyphosphoric acids (4), amide and like compounds (6), carbonic ester compounds (7), and hydroxylic compounds (8). The process enables acyloxybenzenesulfonic acids with good hues to be produced industrially in high yields at a high selectivity and a low cost as compared with the conventional processes.

    PRODUCTION OF ALPHA-SULFOACYLOXYBENZENESULFONIC ACID OR ITS SALT

    公开(公告)号:JPH0959246A

    公开(公告)日:1997-03-04

    申请号:JP21432495

    申请日:1995-08-23

    Applicant: KAO CORP

    Abstract: PROBLEM TO BE SOLVED: To industrially produce the subject compound useful as a bleaching activator in high selectivity and yield by sulfonating an acyloxybenzenie in the coexistence of a specific carboxylic acid ester with a sulfonating agent. SOLUTION: (A) An acyloxybenzene of formula I [R is a 1-35C straight-chain or branched chain alkyl or alkenyl which may be substituted with a halogen or an ester, an ether, etc., may be inserted thereinto; R is a 1-20C straight-chain or branched chain alkyl, methoxy or ethoxy; (n) is an integer of 0-2] is sulfonated in the coexistence of (B) a carboxylic acid ester of formula II [R is a 1-34C straight-chain or branched chain alkyl or alkenyl which may be substituted with a halogen or an ester, an ester, etc., may be inserted thereinto; R is a 1-4C straight-chain or branched chain lower alkyl, etc.] with a sulfonating agent and, as necessary, the resultant product is neutralized with an alkaline agent to afford (C) an α-sulfoacyloxybenzenesulfonic acid of formula III [R is same as H and R ; M is H, an alkali(ne earth) metal, etc.] or its salt.

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