公开(公告)号：US3899446A

公开(公告)日：1975-08-12

申请号：US43846774

申请日：1974-01-31

Applicant: KAO CORP

Inventor： MIYA BUNJI ,  KASUTANI KATSUJI ,  MATSUDA MORIO ,  HASHIMOTO AKIO ,  NISIGAWA SHIYOZO ,  SAWAMOTO YOUZI

IPC: C07C29/136 ,  B01J23/86 ,  B01J37/16 ,  C07B61/00 ,  C07C27/00 ,  C07C29/149 ,  C07C31/125 ,  C07C67/00 ,  B01J23/16 ,  B01J23/64 ,  B01J23/84

CPC classification number: B01J37/16 ,  B01J23/868 ,  C07C29/149 ,  C07C31/125 ,  C07C33/025

Abstract: A process for preparing copper-chromium catalysts is provided, in which 0.5-3 moles of chromic acid anhydride are dissolved in water, the resulting solution is added and reacted with 1 mole of cupric oxide, 0.1-1 mole (as formaldehyde) of a reducing agent which will be converted into carbon dioxide and water by oxidation is added thereto and reacted, further 0.9-8.0 moles of ammonia are added thereto and reacted, and the resulting product is dried by evaporation and calcined to obtain the desired catalyst.

公开(公告)号：FR2682303B1

公开(公告)日：1995-04-28

申请号：FR9211798

申请日：1992-10-05

Applicant: KAO CORP

Inventor： MATSUDA MORIO ,  HORIO MASAMITSU

IPC: B01J23/78 ,  B01J23/80 ,  B01J29/06 ,  B01J29/072 ,  B01J37/03 ,  C07B61/00 ,  C07C29/149 ,  C07C31/125 ,  B01J21/04 ,  B01J21/06 ,  B01J21/10

Abstract: A catalyst for hydrogenation use in which the carrier of the catalyst comprises at least one compound from oxides and hydroxides of aluminum, silicon, titanium, zirconium, magnesium and iron, zeolites or silica-alumina, and the catalyst has an atomic ratio (the atomic ratio of the entire catalyst including the carrier, in the case of the use of an aluminum atom-containing substance as the carrier) of Cu/Fe/Al/(an alkali metal and/or an alkaline earth metal)/Zn=1/0.4 to 2.5/0.5 to 5.0/0.001 to 0.4/0 to 1.0. According to the present invention, a copper-iron-aluminum catalyst having markedly high activity and selectivity can be obtained, and, when the catalyst is used, higher alcohols having high purity can be obtained easily.

公开(公告)号：FR2665090B1

公开(公告)日：1995-03-10

申请号：FR9107463

申请日：1991-06-18

Applicant: KAO CORP

Inventor： MATSUDA MORIO ,  MORIO MATSUDA ,  HORIO MASAMITSU ,  MASAMITSU HORIO ,  TSUKADA KIYOSHI ,  KIYOSHI TSUKADA

IPC: B01J23/72 ,  B01J23/745 ,  B01J23/80 ,  C07B61/00 ,  B01J23/74 ,  C07C29/149 ,  C07C29/153 ,  C07C31/00 ,  C07C31/125 ,  B01J23/70 ,  B01J21/02 ,  B01J37/04

Abstract: La présente invention a pour objet un catalyseur d'hydrogénation, caractérisé en ce qu'il comprend du cuivre, du fer, de l'aluminium et éventuellement du zinc, ainsi qu'un support choisi parmi l'hydroxyde d'aluminium, l'oxyde d'aluminium et un mélange d'hydroxyde d'aluminium et d'oxyde d'aluminium, ayant un rapport atomique Cu/Fe/Al/Zn de 1/(0,4 à 2,5)/(0,5 à 5,0)/(0 à 1,0).

公开(公告)号：DE4234091A1

公开(公告)日：1993-04-15

申请号：DE4234091

申请日：1992-10-09

Applicant: KAO CORP

Inventor： MATSUDA MORIO ,  HORIO MASAMITSU

IPC: B01J23/78 ,  B01J23/80 ,  B01J29/06 ,  B01J29/072 ,  B01J37/03 ,  C07B61/00 ,  C07C29/149 ,  C07C31/125

Abstract: A catalyst for hydrogenation use in which the carrier of the catalyst comprises at least one compound from oxides and hydroxides of aluminum, silicon, titanium, zirconium, magnesium and iron, zeolites or silica-alumina, and the catalyst has an atomic ratio (the atomic ratio of the entire catalyst including the carrier, in the case of the use of an aluminum atom-containing substance as the carrier) of Cu/Fe/Al/(an alkali metal and/or an alkaline earth metal)/Zn=1/0.4 to 2.5/0.5 to 5.0/0.001 to 0.4/0 to 1.0. According to the present invention, a copper-iron-aluminum catalyst having markedly high activity and selectivity can be obtained, and, when the catalyst is used, higher alcohols having high purity can be obtained easily.

公开(公告)号：CA1064975A

公开(公告)日：1979-10-23

申请号：CA271257

申请日：1977-02-07

Applicant: KAO CORP

Inventor： OHTANI NAOTERU ,  KOYAMA TUTOMU ,  TAKEUCHI TAKASHI ,  AZUMA TOSHIHIRO ,  MATSUDA MORIO

IPC: C04B24/10 ,  C04B24/38 ,  C04B7/02

Abstract: HYDRAULIC CEMENT COMPOSITION A hydraulic cement composition containing a hydrogenation product of an oligosaccharide, such as a hydrolyzate of starch, cellulose or hemicellulose, having an average molecular weight of 300 to 3,500, as an agent for improving the properties of the cement.

公开(公告)号：DE2708968A1

公开(公告)日：1977-09-15

申请号：DE2708968

申请日：1977-03-02

Applicant: KAO CORP

Inventor： OHTANI NAOTERU ,  KOYAMA TUTOMU ,  TAKEUCHI TAKASHI ,  AZUMA TOSHIHIRO ,  MATSUDA MORIO

IPC: C04B24/38 ,  C04B7/352 ,  C04B13/24

公开(公告)号：DE2707677A1

公开(公告)日：1977-09-15

申请号：DE2707677

申请日：1977-02-23

Applicant: KAO CORP

Inventor： OHTANI NAOTERU ,  KOYAMA TUTOMU ,  TAKEUCHI TAKASHI ,  AZUMA TOSHIHIRO ,  MATSUDA MORIO

IPC: C04B24/10 ,  C04B24/38 ,  C04B7/352 ,  C04B13/24

公开(公告)号：DE2404757A1

公开(公告)日：1974-08-15

申请号：DE2404757

申请日：1974-02-01

Applicant: KAO CORP

Inventor： MIYA BUNJI ,  KASUTANI KATSUJI ,  MATSUDA MORIO ,  HASHIMOTO AKIO ,  NISIGAWA SHIYOZO ,  SAWAMOTO YOUZI

IPC: C07C29/136 ,  B01J23/86 ,  B01J37/16 ,  C07B61/00 ,  C07C27/00 ,  C07C29/149 ,  C07C31/125 ,  C07C67/00 ,  B01J11/22

公开(公告)号：DE4120536C2

公开(公告)日：2003-05-08

申请号：DE4120536

申请日：1991-06-21

Applicant: KAO CORP

Inventor： MATSUDA MORIO ,  HORIO MASAMITSU ,  TSUKADA KIYOSHI

IPC: B01J23/74 ,  B01J23/72 ,  B01J23/745 ,  B01J23/80 ,  C07B61/00 ,  C07C29/149 ,  C07C29/153 ,  C07C31/00 ,  C07C31/125 ,  B01J23/70 ,  B01J21/04

Abstract: The hydrogenation catalyst comprises copper, iron, aluminum and optionally zine and a support selected from aluminum hydroxide, aluminum oxide and a mixture of aluminum hydroxide and aluminum oxide, having an atomic ratio of Cu/Fe/Al/Zn in the range of 1/(0.4 to 2.5)/(0.5 to 5.0)/(0 to 1.0). It is produced by dispersing a material for the support in an aqueous medium, depositing cupper and iron on the dispersant, further depositing thereon aluminum and sintering it. It is a catalyst for production of a higher alcohol from its methyl ester, effecting hydrogenation with an improved selectivity and activity.

公开(公告)号：BR9102621A

公开(公告)日：1992-01-21

申请号：BR9102621

申请日：1991-06-21

Applicant: KAO CORP

Inventor： MATSUDA MORIO ,  HORIO MASAMITSU ,  TSUKADA KIYOSHI

IPC: B01J23/74 ,  B01J23/72 ,  B01J23/745 ,  B01J23/80 ,  C07B61/00 ,  C07C29/149 ,  C07C29/153 ,  C07C31/00 ,  C07C31/125 ,  B01J23/70 ,  B01J23/06 ,  B01J21/02

Abstract: The hydrogenation catalyst comprises copper, iron, aluminum and optionally zine and a support selected from aluminum hydroxide, aluminum oxide and a mixture of aluminum hydroxide and aluminum oxide, having an atomic ratio of Cu/Fe/Al/Zn in the range of 1/(0.4 to 2.5)/(0.5 to 5.0)/(0 to 1.0). It is produced by dispersing a material for the support in an aqueous medium, depositing cupper and iron on the dispersant, further depositing thereon aluminum and sintering it. It is a catalyst for production of a higher alcohol from its methyl ester, effecting hydrogenation with an improved selectivity and activity.