公开(公告)号：FR2665090B1

公开(公告)日：1995-03-10

申请号：FR9107463

申请日：1991-06-18

Applicant: KAO CORP

Inventor： MATSUDA MORIO ,  MORIO MATSUDA ,  HORIO MASAMITSU ,  MASAMITSU HORIO ,  TSUKADA KIYOSHI ,  KIYOSHI TSUKADA

IPC: B01J23/72 ,  B01J23/745 ,  B01J23/80 ,  C07B61/00 ,  B01J23/74 ,  C07C29/149 ,  C07C29/153 ,  C07C31/00 ,  C07C31/125 ,  B01J23/70 ,  B01J21/02 ,  B01J37/04

Abstract: La présente invention a pour objet un catalyseur d'hydrogénation, caractérisé en ce qu'il comprend du cuivre, du fer, de l'aluminium et éventuellement du zinc, ainsi qu'un support choisi parmi l'hydroxyde d'aluminium, l'oxyde d'aluminium et un mélange d'hydroxyde d'aluminium et d'oxyde d'aluminium, ayant un rapport atomique Cu/Fe/Al/Zn de 1/(0,4 à 2,5)/(0,5 à 5,0)/(0 à 1,0).

公开(公告)号：MY107980A

公开(公告)日：1996-07-15

申请号：MYPI19921784

申请日：1992-10-02

Applicant: KAO CORP

Inventor： MORIO MATSUDA ,  MASAMITSU HORIO

IPC: B01J23/78 ,  B01J23/72 ,  B01J23/80 ,  B01J29/06 ,  B01J29/072 ,  B01J37/03 ,  C07B61/00 ,  C07C29/149 ,  C07C31/125

Abstract: A CATALYST FOR HYDROGENATION USE IN WHICH THE CARRIER OF THE CATALYST COMPRISES AT LEAST ONE COMPOUND FROM OXIDES AND HYDROXIDES OF ALUMINUM, SILICON, TITANIUM, ZIRCONIUM, MAGNESIUM AND IRON, ZEOLITES OR SILICA-ALUMINA, AND THE CATALYST HAS AN ATOMIC RATIO (THE ATOMIC RATIO OF THE ENTIRE CATALYST INCLUDING THE CARRIER, IN THE CASE OF THE USE OF AN ALUMINUM ATOM-CONTAINING SUBSTANCE AS THE CARRIER) OF CU/FE/AI/ (AN ALKALI METAL AND/OR AN ALKALINE EARTH METAL) /ZN=1/0.4 TO 2.5/0.5 TO 5.0/0.001 TO 0.4/0 TO 1.0. ACCORDING TO THE PRESENT INVENTION, A COPPER - IRON-ALUMINIUM CATALYST HAVING MARKEDLY HIGH ACTIVITY AND SELECTIVITY CAN BE OBTAINED, AND, WHEN THE CATALYST IS USED, HIGHER ALCOHOLS HAVING HIGH PURITY CAN BE OBTAINED EASILY.

公开(公告)号：MY106379A

公开(公告)日：1995-05-30

申请号：MYPI19911104

申请日：1991-06-19

Applicant: KAO CORP

Inventor： MORIO MATSUDA ,  MASAMITSU HORIO ,  KIYOSHI TSUKADA

IPC: B01J21/02 ,  B01J37/03 ,  B01J23/72 ,  B01J23/80

Abstract: THE HYDROGENATION CATALYST COMPRISES COPPER, IRON, ALUMINUM AND OPTIONALLY ZINC AND A SUPPORT SELECTED FROM ALUMINUM HYDROXIDE, ALUMINUM OXIDE AND A MIXTURE OF ALUMINUM HYDROXIDE AND ALUMINUM OXIDE, HAVING AN ATOMIC RATIO OF Cu/ Fe/ Al/ Zn IN THE RANGE OF 1/(0.4 TO 2.5)/ (0.5 TO 5.0)/ (0 TO 1.0). IT IS PRODUCED BY DISPERSING A MATERIAL FOR THE SUPPORT IN AN AQUEOUS MEDIUM,DEPOSITING COPPER AND IRON ON THE DISPERSANT, FURTHER DEPOSITING THEREON ALUMINUM AND SINTERING IT. IT IS A CATALYST FOR PRODUCTION OF A HIGHER ALCOHOL FROM ITS METHYL ESTER, EFFECTING HYDROGENATION WITH AN IMPROVED SELECTIVITY AND ACTIVITY.

公开(公告)号：FR2682303A1

公开(公告)日：1993-04-16

申请号：FR9211798

申请日：1992-10-05

Applicant: KAO CORP

Inventor： MORIO MATSUDA ,  MASAMITSU HORIO

IPC: B01J23/78 ,  B01J23/80 ,  B01J29/06 ,  B01J29/072 ,  B01J37/03 ,  C07B61/00 ,  C07C29/149 ,  C07C31/125 ,  B01J21/04 ,  B01J21/06 ,  B01J21/10

Abstract: A catalyst for hydrogenation use in which the carrier of the catalyst comprises at least one compound from oxides and hydroxides of aluminum, silicon, titanium, zirconium, magnesium and iron, zeolites or silica-alumina, and the catalyst has an atomic ratio (the atomic ratio of the entire catalyst including the carrier, in the case of the use of an aluminum atom-containing substance as the carrier) of Cu/Fe/Al/(an alkali metal and/or an alkaline earth metal)/Zn=1/0.4 to 2.5/0.5 to 5.0/0.001 to 0.4/0 to 1.0. According to the present invention, a copper-iron-aluminum catalyst having markedly high activity and selectivity can be obtained, and, when the catalyst is used, higher alcohols having high purity can be obtained easily.

公开(公告)号：FR2665090A1

公开(公告)日：1992-01-31

申请号：FR9107463

申请日：1991-06-18

Applicant: KAO CORP

Inventor： MORIO MATSUDA ,  MASAMITSU HORIO ,  KIYOSHI TSUKADA

IPC: B01J23/74 ,  B01J23/72 ,  B01J23/745 ,  B01J23/80 ,  C07B61/00 ,  C07C29/149 ,  C07C29/153 ,  C07C31/00 ,  C07C31/125 ,  B01J23/70 ,  B01J21/02 ,  B01J37/04

Abstract: The hydrogenation catalyst comprises copper, iron, aluminum and optionally zine and a support selected from aluminum hydroxide, aluminum oxide and a mixture of aluminum hydroxide and aluminum oxide, having an atomic ratio of Cu/Fe/Al/Zn in the range of 1/(0.4 to 2.5)/(0.5 to 5.0)/(0 to 1.0). It is produced by dispersing a material for the support in an aqueous medium, depositing cupper and iron on the dispersant, further depositing thereon aluminum and sintering it. It is a catalyst for production of a higher alcohol from its methyl ester, effecting hydrogenation with an improved selectivity and activity.