公开(公告)号：JP2012092163A

公开(公告)日：2012-05-17

申请号：JP2010238436

申请日：2010-10-25

Applicant: Kao Corp ,  花王株式会社

Inventor： MITSUTA YOSHINORI ,  KONO JUN

IPC: C11D1/14 ,  A61K8/19 ,  A61K8/34 ,  A61K8/46 ,  A61Q5/02 ,  C11D3/04 ,  C11D3/10 ,  C11D3/20

Abstract: PROBLEM TO BE SOLVED: To provide an anionic surfactant composition that contains a high concentration of a higher alcohol sulfuric ester salt and is excellent in fluidity and storage stability.SOLUTION: The anionic surfactant composition comprises: 55-70 mass% of the higher alcohol sulfuric ester salt (a); 0.10-4.0 mass% of 10-22C higher alcohol (b); 0.10-3.9 mass% of alkali metal carbonate (c); 0.10-1.9 mass% of alkali metal hydroxide (d); and water.

Abstract translation: 待解决的问题：提供含有高浓度高级醇硫酸酯盐的阴离子表面活性剂组合物，并且流动性和储存稳定性优异。 阴离子表面活性剂组合物包含：55-70质量％的高级醇硫酸酯盐（a）; 0.10-4.0质量％的10-22C高级醇（b）; 0.10-3.9质量％的碱金属碳酸盐（c）; 0.10-1.9质量％碱金属氢氧化物（d）; 和水。 版权所有（C）2012，JPO＆INPIT

公开(公告)号：JP2011153068A

公开(公告)日：2011-08-11

申请号：JP2010289286

申请日：2010-12-27

Applicant: Kao Corp ,  花王株式会社

Inventor： HAMAI TOSHIMASA ,  YOSHIKAWA YOHEI ,  MITSUTA YOSHINORI ,  FUKUSHIMA TETSURO ,  YOSHINAMI YUSUKE ,  KAWAKAMI HIROYUKI

IPC: C04B24/02 ,  C04B22/14 ,  C04B24/12 ,  C04B28/02 ,  C04B103/10

Abstract: PROBLEM TO BE SOLVED: To provide a hardening accelerator for a hydraulic composition improving short term strength and initial strength without curing after kneading.
SOLUTION: Provided is the hardening accelerator for the hydraulic composition, which comprises a specific compound (1) such as glycerin and one or more inorganic salts A selected from alkali metal sulfates and alkali metal thiosulfates, wherein the molar ratio of the compound (1) and the inorganic salt A is 5/95 to 45/55 by compound (1)/inorganic salt A.
COPYRIGHT: (C)2011,JPO&INPIT

Abstract translation: 要解决的问题：提供一种改善短时强度和初始强度的水硬性组合物的硬化促进剂，而不是在捏合后固化。 解决方案：提供了一种水硬性组合物的硬化促进剂，其包含特定的化合物（1）如甘油和一种或多种选自碱金属硫酸盐和碱金属硫代硫酸盐的无机盐A，其中化合物 （1），无机盐A为化合物（1）/无机盐A的5/95至45/55。版权所有（C）2011，JPO＆INPIT

公开(公告)号：JP2006316265A

公开(公告)日：2006-11-24

申请号：JP2006112379

申请日：2006-04-14

Applicant: Kao Corp ,  花王株式会社

Inventor： IITAKA KAZUHIRO ,  TOMIFUJI TAKESHI ,  KUSUMI TOMOKATSU ,  MITSUTA YOSHINORI ,  KONO JUN

IPC: C11D1/86 ,  C11D1/29 ,  C11D1/62 ,  C11D1/68 ,  C11D1/90 ,  C11D1/92

Abstract: PROBLEM TO BE SOLVED: To provide an additive useful as an agent for fluidizing alkyl sulfate and/or alkyl ether sulfate compositions, and to provide an anionic surfactant composition which contains the additive and has such good flowability that the alkyl sulfate and/or alkyl ether sulfate may be contained in high concentrations.
SOLUTION: This additive for high concentration anionic surfactants, comprising a nitrogen-containing compound, is characterized in that the nitrogen-containing compound is at least one compound selected from the group consisting of amide alcohol compounds, amide amine type compounds, betaine type compounds, and imidazoline type compounds. The anionic surfactant composition contains the additive for high concentration anionic surfactants.
COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：提供可用作流化烷基硫酸盐和/或烷基醚硫酸盐组合物的试剂的添加剂，并提供含有添加剂并具有如此良好的流动性的阴离子表面活性剂组合物，使烷基硫酸盐和/ 或烷基醚硫酸盐可以以高浓度包含。 解决方案：该含氮化合物的高浓度阴离子表面活性剂添加剂的特征在于含氮化合物是至少一种选自酰胺醇化合物，酰胺胺型化合物，甜菜碱 型化合物和咪唑啉型化合物。 阴离子表面活性剂组合物含有用于高浓度阴离子表面活性剂的添加剂。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2006117769A

公开(公告)日：2006-05-11

申请号：JP2004306015

申请日：2004-10-20

Applicant: Kao Corp ,  花王株式会社

Inventor： IITAKA KAZUHIRO ,  KUSUMI TOMOKATSU ,  MITSUTA YOSHINORI ,  KONO JUN

IPC: C09K3/00 ,  C07C303/24 ,  C07C305/10 ,  C11D1/02 ,  C11D3/34 ,  C11D17/08

Abstract: PROBLEM TO BE SOLVED: To provide a novel additive for an anionic surface active agent useful as a fluidizing agent for an alkyl ether sulfate composition and an anionic surface active agent composition containing the additive.
SOLUTION: The additive for an anionic surface active agent comprises at least one or more compounds represented by formula (1): ZO(A
1 O)nSO
3 M
1 [wherein M
1 is an alkali metal or NH
4 ; Z is hydrogen or SO
3 M
2 (wherein M
2 is an alkali metal, NH
4 or hydrogen); A
1 is a 2-4C alkylene group; n is a number of 1.0-12 on averages; and the molecular weight of -(A
1 O)
n - is 100-550], and the anionic surface active agent composition comprises one or more compounds represented by above formula (1) as component A, one or more compounds represented by formula (2): RO(A
2 O)
m SO
3 M
3 (wherein R is a 9-24C straight chain or branched chain alkyl group or an alkenyl group; A
2 is a 2-4C alkylene group; M
3 is hydrogen, an alkali metal or NH
4 ; and m is a number of 0-100) as component B, and water.
COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供用作用作烷基醚硫酸盐组合物的流化剂的阴离子表面活性剂和含有该添加剂的阴离子表面活性剂组合物的新型添加剂。 解决方案：阴离子表面活性剂的添加剂包含至少一种或多种由式（1）表示的化合物：ZO（A 1 O）nSO 3 SB 1 其中M 1 是碱金属或NH 4 ; Z是氢或SO 3，其中M 2 是碱金属，NH 4 SB 4或氢） ; A 1 是2-4C亚烷基; n是平均值的1.0-12; 并且 - （A 1）的分子量为100-550]，阴离子表面活性剂组合物包含一种或多种由上式（ 1）作为组分A，一种或多种由式（2）表示的化合物：RO（A 2 O） > 3 （其中R是9-24C直链或支链烷基或烯基; A 2 是2-4C亚烷基; M < SP>是氢，碱金属或NH 4 SB;且m是0-100的数量）作为组分B和水。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2000256548A

公开(公告)日：2000-09-19

申请号：JP5712899

申请日：1999-03-04

Applicant: KAO CORP

Inventor： IKENAGA NAOYUKI ,  MORI ATSUTO ,  AIZAWA HIROYUKI ,  SAWADA HIROKI ,  ISHII YASUO ,  MITSUTA YOSHINORI

IPC: B01F17/00 ,  B01F17/04 ,  B01F17/42 ,  C08F2/26 ,  C08F220/18 ,  C08G65/32 ,  C08L71/02 ,  C08G65/334

Abstract: PROBLEM TO BE SOLVED: To obtain a surfactant composition for emulsion polymerization which is excellent in stability at the time of polymerization and in the mechanical stability of emulsion and has small particle diameter and low viscosity. SOLUTION: This surfactant composition for emulsion polymerization is obtained by including, as the essential components, (a) a compound shown by general formula I [R1O-(A1O)m-SO3M1] with a critical micell concentration(CMC) in the range of 0.007 molL-1 to 0.1 molL-1 and (b) a compound shown by general formula II [R2O-(A2O)n-SO3M2] with a CMC in the range of 1×10-5 molL-1 to

公开(公告)号：JP2014077126A

公开(公告)日：2014-05-01

申请号：JP2013192793

申请日：2013-09-18

Applicant: Kao Corp ,  花王株式会社

Inventor： YOSHIKAWA YOHEI ,  MITSUTA YOSHINORI ,  HORI HIROSHI ,  NISHIMOTO YOSHIFUMI ,  DOI YASUHIRO

IPC: C11D1/14 ,  A61K8/46 ,  A61Q19/10 ,  C07C309/08 ,  C11D3/04

CPC classification number: A61Q5/02 ,  A61K8/466 ,  A61K2800/596 ,  A61Q19/10 ,  C07C309/08 ,  C07C309/20 ,  C11D1/143 ,  C11D1/37 ,  C11D3/0094

Abstract: PROBLEM TO BE SOLVED: To provide an internal olefin sulfonate composition exhibiting good foamability, foam volume, rapidly foaming properties, foam cutting properties, foam quality, retentivity of foam in the presence of sebum, and foam volume in the presence of sebum in high level, and to provide a detergent composition containing the same.SOLUTION: An internal olefin sulfonate composition contains (A) an internal olefin sulfonate having 16 carbon atoms and/or (B) an internal olefin sulfonate having 18 carbon atoms, and the total content of the component (A) and the component (B) is 50 to 100 mass%, the content ratio of the component (A) and the component (B) (A/B) is 91/9 to 100/0, the content of the internal olefin sulfonate having a sulfonate group at 2-position is 25 mass% or less, and the mass ratio of the content of a hydroxy body in the internal olefin sulfonates of the component (A) and the component (B) and the content of an olefin body in the internal olefin sulfonates of the component (A) and the component (B) (hydroxy body/olefin body) is 75/25 to 100/0.

Abstract translation: 要解决的问题：提供在高水平皮脂存在下表现出良好的起泡性，泡沫体积，快速发泡性能，泡沫切割性能，泡沫质量，泡沫存在下的皮脂保留性和泡沫体积的内烯烃磺酸盐组合物 ，并提供含有该组合物的洗涤剂组合物。溶液：含有（A）具有16个碳原子的内部烯烃磺酸盐和/或（B）具有18个碳原子的内部烯烃磺酸盐的内部烯烃磺酸盐组合物， 成分（A）和成分（B）为50〜100质量％，成分（A）和成分（B）（A / B）的含有比例为91/9〜100 / 在2位上具有磺酸酯基的内部烯烃磺酸酯的含量为25质量％以下，成分（A）和成分（B）的内部烯烃磺酸酯中的羟基的含量与成分（B）的质量比 的烯烃体在t的内部烯烃磺酸盐中 组分（A）和组分（B）（羟基/烯烃体）为75/25至100/0。

公开(公告)号：JP2013082855A

公开(公告)日：2013-05-09

申请号：JP2011225368

申请日：2011-10-12

Applicant: Kao Corp ,  花王株式会社

Inventor： MITSUTA YOSHINORI ,  NISHIMOTO YOSHIFUMI ,  CHIBA KEISUKE

IPC: C11D1/29

Abstract: PROBLEM TO BE SOLVED: To provide an anionic surfactant composition containing a polyoxyalkylenealkyl or an alkenyl ether sulfate ester salt excellent in both foamability and defaomabity in a high concentration, and being excellent in flowability.SOLUTION: The anionic surfactant composition contains (a) a mixture of compounds represented by formula (1): RO-(EO)-(PO)-SOM and (b) water. The average value of m and n in the mixture are each in a predetermined range. The proportion of a compound of 0 in m in the formula (1) and 0 in n therein in the mixture is ≥40 mass%. The total of a compound of ≥2 in m in the formula (1), a compound of ≥2 in n therein, and a compound of ≥2 in m+n therein in the mixture is ≤25 mass%. In the formula (1), R is an 8-12C linear or branched alkyl group or alkenyl group; EO is an ethyleneoxy group; PO is a propyleneoxy group; m and n are each an integer of ≥0; and M is an alkaline metal or NH.

Abstract translation: 待解决的问题：提供含有高浓度发泡性和脱泡性优异的聚氧化烯烷基或烯基醚硫酸酯盐的阴离子表面活性剂组合物，流动性优异。 阴离子表面活性剂组合物包含（a）由式（1）表示的化合物的混合物：RO-（EO）（PO） n -SO 3 M和（b）水。 混合物中m和n的平均值各自在预定范围内。 混合物中式（1）中0的化合物与n中的0的比例为≥40质量％。 式（1）中≥2m的化合物，n中的≥2的化合物和m + n中的≥2的化合物的混合物的总量≤25质量％。 在式（1）中，R为8-12C直链或支链烷基或烯基; EO是乙烯氧基; PO是丙烯氧基; m和n各自为≥0的整数; 并且M是碱金属或NH 4 。 版权所有（C）2013，JPO＆INPIT

公开(公告)号：JP2009143980A

公开(公告)日：2009-07-02

申请号：JP2007319701

申请日：2007-12-11

Applicant: Kao Corp ,  花王株式会社

Inventor： MITSUTA YOSHINORI ,  KONO JUN ,  CHIBA KEISUKE

IPC: C09K3/00 ,  C11D1/29

Abstract: PROBLEM TO BE SOLVED: To provide a liquid surfactant composition that contains a polyoxyalkylene alkyl ether sulfate ester salt with a predetermined branching fraction in high concentration and is excellent in stability.
SOLUTION: The surfactant composition contains (a) 40-58 mass% mixture of a compound represented by general formula (1): RO-(PO)
m (EO)
n SO
3 M, in the mixture the ratio of a compound, of which R in general formula (1) is a hydrocarbon group having a branched chain, is 0 mass% or higher and not higher than 50 mass%, (b) 13-20 mass% at least one of a 1-6C lower alcohol, and (c) 22-47 mass% water. In general formula (1), R is a 8-24C hydrocarbon group; PO and EO are a propyleneoxy group and an ethyleneoxy group, respectively; m and n show the addition numbers of moles of PO and EO, respectively, and are such numbers that their mean values in the mixture of the compounds represented by general formula (1) are 0

Abstract translation: 待解决的问题：提供含有高浓度的预定支化级分的聚氧化烯烷基醚硫酸酯盐的液体表面活性剂组合物，并且稳定性优异。 表面活性剂组合物含有（a）40-58质量％的通式（1）表示的化合物的混合物：RO-（PO）（EO） 在混合物中，通式（1）中的R为具有支链的烃基的化合物的比例为0质量％以上且不高于 （b）13-20质量％的1-6C低级醇和（c）22-47质量％水中的至少一种。 在通式（1）中，R为8-24C烃基; PO和EO分别是丙烯氧基和乙烯氧基; m和n分别表示PO和EO的摩尔数的加成数，是通式（1）表示的化合物的混合物的平均值为0

公开(公告)号：JP2007176894A

公开(公告)日：2007-07-12

申请号：JP2005379806

申请日：2005-12-28

Applicant: Kao Corp ,  花王株式会社

Inventor： MITSUTA YOSHINORI ,  KUSUMI TOMOKATSU ,  KONO JUN ,  TOMIFUJI TAKESHI

IPC: C07C303/24 ,  C07C305/10 ,  C11D1/29 ,  C11D17/08

Abstract: PROBLEM TO BE SOLVED: To provide an efficient production method for an anionic surfactant composition containing an alkyl ether sulfate salt of high concentration and a light color. SOLUTION: In the production method for a composition containing as the main component an anionic surfactant comprising an alkyl ether sulfate salt represented by following general formula (1) by means of sulfating a higher alcohol or its alkylene oxide adduct followed by neutralization, the first neutralization is conducted keeping the pH at 2 to 5 and the second neutralization is conducted until a pH of 10 or higher is attained. The above formula is: RO(AO) n SO 3 M (1), wherein R indicates an alkyl group or an alkenyl group; A indicates an alkylene group; M indicates a hydrogen atom or an alkali metal; and n indicates a number of 0 to 100 on average. COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：提供一种含有高浓度和浅色的烷基醚硫酸盐的阴离子表面活性剂组合物的有效制备方法。 解决方案：在含有由以下通式（1）表示的烷基醚硫酸盐通过硫酸化高级醇或其氧化烯加合物进行中和的作为主要组分的阴离子表面活性剂的组合物的制备方法中， 进行第一中和，将pH保持在2〜5，进行第二次中和直到达到10以上的pH。 上述式为：RO（AO）-S（S）SO（SB）3 M（1）其中R表示烷基或烯基; A表示亚烷基; M表示氢原子或碱金属; n表示平均为0〜100的数。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2006117770A

公开(公告)日：2006-05-11

申请号：JP2004306017

申请日：2004-10-20

Applicant: Kao Corp ,  花王株式会社

Inventor： IITAKA KAZUHIRO ,  MITSUTA YOSHINORI ,  KONO JUN

IPC: C11D11/04 ,  C07C305/10 ,  C11D1/29

Abstract: PROBLEM TO BE SOLVED: To provide an anionic surface active agent composition comprising an alkyl ether sulfate and a fluidizing agent of an alkylene ether glycol sulfate ester salt. SOLUTION: The method for manufacturing an anionic surface active agent comprising compounds represented by the formula: RO(A 1 O) m SO 3 M 1 (wherein R is a 9-24C straight chain or branched chain alkyl group or an alkenyl group; A 1 is a 2-4C alkylene group; and m is 0-100 on averages; M 1 is an alkali metal or NH 4 ) and the formula: ZO(A 2 O) n SO 3 M 2 [wherein Z is hydrogen or SO 3 M 3 (wherein M 3 is an alkali metal, NH 4 or hydrogen); A 2 is a 2-4C alkylene group; n is 0.1-100 on averages; M 2 is an alkali metal or NH 4 ] and water comprises (A) mixing a compound of the formula: RO(A 1 O) m H (wherein R, A 1 , and m are the same as defined above) and having a carbonyl value of ≤2 μmol/g with a compound of the formula: HO(A 2 O) n H (wherein A 2 and n are the same as defined above) at 0-50°C, (B) sulfating the mixture of step (A) with a sulfur trioxide gas, and (C) neutralizing the sulfated products with an alkali metal compound and ammonia water. COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 待解决的问题：提供一种包含烷基醚硫酸盐和亚烷基醚二醇硫酸酯盐的流化剂的阴离子表面活性剂组合物。 解决方案：制备阴离子表面活性剂的方法，其包含由下式表示的化合物：RO（A 1 O） SO 3 其中R是9-24C直链或支链烷基或烯基; A 1 是2-4C亚烷基; m是 0-100平均值; M 1 是碱金属或NH 3 SB 4）和式：ZO（A 2 O） 其中Z是氢或SO 3 S 3（其中M是3或3） 3 是碱金属，NH 4 SB 4或氢）; A 2 是2-4C亚烷基; n平均为0.1-100; M 2 是碱金属或NH 3 SB 4]，水包含（A）将下式化合物RO（A 1 O） 具有下式的化合物的羰基值为≤2μmol/ g的H（其中R，A 1，和SP与上述定义相同） 在0-50℃，HO（A 2 O） H（其中A 2 和n与上述相同） B）将步骤（A）的混合物与三氧化硫气体硫酸化，（C）用碱金属化合物和氨水中和硫酸化产物。 版权所有（C）2006，JPO＆NCIPI