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    COATING RESIN COMPOSITION CURABLE WITH ACTINIC IRRADIATION
    2.
    发明专利
    COATING RESIN COMPOSITION CURABLE WITH ACTINIC IRRADIATION 失效

    公开(公告)号：JPS5565211A

    公开(公告)日：1980-05-16

    申请号：JP13869878

    申请日：1978-11-10

    Applicant: KAO CORP

    Inventor： TSUNODA YUTAKA ,  MEIWA YOSHIHEI ,  NAMIKATA MASAAKI

    IPC: C08F2/00 ,  C08F2/46 ,  C08F2/48 ,  C08F290/00 ,  C08F299/00 ,  C08F299/06 ,  C09D5/00 ,  C09D11/00 ,  C09D11/10 ,  C09D175/14

    Abstract: PURPOSE:To prepare coating resin composition curable with actinic irradiation and having an increased curing rate and excellent adhesibity to bases, e.g. metals, glass, etc., by compounding a specific (meth)acryl-urethane resin having or more (meth)acryloyl groups with a specific copolymerizable monomer, etc. CONSTITUTION:A coating resin composition comprising (A) a (meth)acryl-urethane resin having two or more (meth)acryloyl groups and prepared by reacting (a) a (meth)acrylic ester derivative having an acid value of 0-10 and hydroxyl groups partially (meth)acrylated and prepared by condensing (meth)acrylic acid with a mixed glycol consisting of 5-85mol% of a 2-12C aliphatic glycol and 95- 15mol% of a terminal hydroxyl group-containing polyoxyalkylenebisphenol derivative expressed by the formula, with (b) a diisocyanate compound and (c) a hydroxyl group-containing (meth) acrylate compound, (B) a monomer having a double bond copolymerizable with (meth) acryloyl group of the component (A), and (C) a photosensitizer.

    ACTINIC RADIATIONNCURING RESIN COMPOSITION
    3.
    发明专利
    ACTINIC RADIATIONNCURING RESIN COMPOSITION 失效

    公开(公告)号：JPS5516063A

    公开(公告)日：1980-02-04

    申请号：JP9011878

    申请日：1978-07-24

    Applicant: KAO CORP

    Inventor： TSUNODA YUUZOU ,  MEIWA YOSHIHEI ,  NAMIKATA MASAAKI

    IPC: C08F2/00 ,  C08F2/46 ,  C08F2/50 ,  C08F2/54 ,  C08F290/00 ,  C08F299/00 ,  C08F299/06 ,  C08G18/00 ,  C08G18/67 ,  C09D5/00 ,  C09D11/00 ,  C09D11/10 ,  C09D175/14

    Abstract: PURPOSE:To provide the title composition having excellent adhesivity to substrate, useful as printing ink, etc., and composed of a (meth)acrylic urethane resin having two or more (meth)acryloyl groups in a molecule, a monomer having a polymerizable double bond, and a photo-sensitizer, as main components. CONSTITUTION:A composition composed of (A) a (meth)acrylic urethane resin having two or more (meth)acryloyl goups in a molecule and derived from the compound I or II (R is 2-4C alkylene; R is -CH2-, etc.; X is halogen, methyl; a is 1-2; m and n are >=1, and m+n is 2-10), (B) a monomer having a double bond copolymerizable with terminal unsaturated groups introduced in the above resin, and (C) a photosensitizer such as benzophenone, etc. The weight ratio of A:B is 20:80-95:5, and the amount of (C) component in the whole composition is 0.5-20 wt%.

    PHOTOSENSITIVE ADHESIVE COMPOSITION
    4.
    发明专利
    PHOTOSENSITIVE ADHESIVE COMPOSITION 失效

    公开(公告)号：JPS54133527A

    公开(公告)日：1979-10-17

    申请号：JP4197678

    申请日：1978-04-10

    Applicant: KAO CORP

    Inventor： TSUNODA YUUZOU ,  MEIWA YOSHIHEI ,  NAMIKATA MASAAKI

    IPC: C08F299/00 ,  C08F2/50 ,  C08F290/00 ,  C08F299/06 ,  C09J4/00

    Abstract: PURPOSE:To provide a photosensitive adhesive composition rapidly curable with UV-irradiation, having excellent adhesivity, and composed mainly of a (meth) acrylurethane resin, an OH-containing (meth)acrylate and a photosensitizer. CONSTITUTION:A photosensitive adhesive composition composed of (A) an acrylurethane resin obtained by the reaction of (a) a polyoxyalkylene bisphenol A derivative of formula I or II (R is 2-4C alkylene; X is halogen, methyl; a is 1,2; m, n >= 1; and m+n is an integer of 2-8), (b) a polyisocyanate, and (c) an OH- containing (meth)acrylate, (B) an OH-containing (meth)acrylate, and (C) a photosensitizer.

    WHITE PHOTOOSETTING PAINT COMPOSITION
    8.
    发明专利
    WHITE PHOTOOSETTING PAINT COMPOSITION 失效

    公开(公告)号：JPS5523139A

    公开(公告)日：1980-02-19

    申请号：JP9593278

    申请日：1978-08-07

    Applicant: KAO CORP

    Inventor： TSUNODA YUUZOU ,  NAMIKATA MASAAKI

    IPC: C08F299/00 ,  C08F2/50 ,  C08F290/00 ,  C08F299/06 ,  C08G18/00 ,  C08G18/04 ,  C08G18/34 ,  C08G18/42 ,  C09D5/00 ,  C09D133/04 ,  C09D175/08 ,  C09D175/14

    Abstract: PURPOSE:To provide a white paint composition having excellent adhesivity to a non-absorbent polar surface and giving high surface gloss, composed of a (meth) acrylurethane resin having specific structure, a monomer having a polymerizable double bond, a photo-sensitizer, and anatase-type titanium dioxide. CONSTITUTION:A paint composition composed of (A) a (meth)acrylurethane resin having one or more bisphenol skeletons and two or more urethane bonds in the main chain, and terminal (meth)acryloyl groups, and prepared by the reaction of (a) a polyoxyalkylene bisphenol derivative of formula (R is 2-4C alkylene; R is -CH2-, etc.; R is 2-8C aliphatic, aromatic, hydrocarbon etc.; X is halogen, methyl; a is 0-2; m and n are >=1; m+n is 2-10; l is 0-2), (b) a diisocyanate compound, and (c) an OH- containing (meth)acrylate compound, and if necessary, (d) a carboxyl-containing (meth)acrylate, (B) a monomer having a polymerizable double bond and copolymerizable with the terminal unsaturated group of the (A) resin, (C) a photo-sensitizer, and (D) anatase-type TiO2.

    ACTINIC RADIATIONNCURING RESIN COMPOSITION
    9.
    发明专利
    ACTINIC RADIATIONNCURING RESIN COMPOSITION 失效

    公开(公告)号：JPS5516064A

    公开(公告)日：1980-02-04

    申请号：JP9011978

    申请日：1978-07-24

    Applicant: KAO CORP

    Inventor： TSUNODA YUUZOU ,  MEIWA YOSHIHEI ,  NAMIKATA MASAAKI

    IPC: C08F2/00 ,  C08F2/46 ,  C08F2/54 ,  C08F290/00 ,  C08F299/00 ,  C08F299/06 ,  C08G18/00 ,  C08G18/67 ,  C09D5/00 ,  C09D11/00 ,  C09D11/10 ,  C09D175/14

    Abstract: PURPOSE:To provide the title composition having excellent adhesivity to a non- adsorbent polar surface, useful as printing ink, paint, etc., and composed of a (meth)acrylic urethane resin having two or more (meth)acryloyl groups in a molecule, a vinyl compound, and a photosensitizer. CONSTITUTION:A composition composed of (A) a (meth)acrylic urethane resin having two or more (meth)acryloyl groups in a molecule and derived from the compound I or II (R is 2-4C alkylne; X is halogen, methyl; a is 1-2; m and n are >=1, m+n is 2-8), (B) a vinyl compound copolymerizable with the terminal unsaturated groups introduced into the resin, and (C) a photosensitizer such as benzophenone, benzoin, etc. The weight ratio of A:B is 20:80-95:5, and the amount of (C) in the whole composition is 0.5-20 wt%.

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