Abstract:
The present invention relates to (1) a water-based ink for ink-jet printing having excellent storage stability and anti-curling property which includes particles of a crosslinked water-insoluble polymer containing a colorant wherein a content of water in the ink is 60% by weight or less, and the crosslinked polymer contains an anionic group neutralized with a base in an amount of from 0.5 mmol or more per 1 g of the crosslinked polymer; (2) a process for producing the water-based ink; and (3) a method of reducing curling of a print wherein the print is obtained by printing characters or images thereon with the water-based ink using an ink-jet printer.
Abstract:
The present invention relates to [1] a process for producing pigment-containing modified polymer particles, including the step of reacting pigment-containing polymer particles (A) containing a functional group and a compound (B) containing a reactive group capable of reacting with the functional group of the polymer particles (A) in a medium under such a condition that a ratio [(B)/(A)] of total moles of the reactive group of the compound (B) to total moles of the functional group of the polymer particles (A) is from 0.10 to 0.62; [2] a pigment water dispersion including an aqueous medium and the modified polymer particles produced by the aforementioned process which are dispersed in the aqueous medium; and [3] an ink including the aforementioned pigment water dispersion and an organic solvent. The modified polymer particles are free from formation of coarse particles upon production of pigment particles, so that an ink obtained by using the modified polymer particles can be prevented from suffering from increase in viscosity thereof when the ink is being concentrated by evaporation of water from the ink, and is excellent in rub fastness when printed on a low-water absorbing recording medium.
Abstract:
The present invention provides a process for producing a fine organic pigment which is capable of efficiently atomizing a raw material organic pigment, and excellent in productivity of the fine organic pigment. The present invention relates to a process for producing a fine organic pigment which includes the step of kneading a mixture prepared by compounding a raw material organic pigment, a water-soluble inorganic salt, a water-soluble organic solvent and a resin, in which the resin is a copolymer produced by copolymerizing an aromatic ring-containing ethylenically unsaturated monomer (A), a carboxy group-containing ethylenically unsaturated monomer (B) and an ethylenically unsaturated monomer (C) containing a polyethyleneoxide chain having an average molar number of addition of ethyleneoxide of not less than 1 and not more than 50.
Abstract:
The present invention provides [1] a process for producing a fine organic pigment having a very small primary particle size, and a fine organic pigment produced by the process; a process for producing a dispersion using the fine organic pigment, and a dispersion produced by the process; and a process for producing an ink using the dispersion. The present invention relates to [1] a process for producing a fine organic pigment, including step 1 of kneading a mixture prepared by blending (A) a raw material organic pigment containing an oxygen atom and a nitrogen atom bonded to a hydrogen atom in a molecule thereof, (B) a water-soluble inorganic salt, (C) a water-soluble organic solvent, (D) water and (E) a water-soluble basic compound with each other, in which the water (D) is blended in an amount of not less than 0.6 part by mass and not more than 7.0 parts by mass on the basis of 100 parts by mass of the water-soluble inorganic salt, and the water-soluble basic compound (E) is blended in an amount of not less than 1.5 parts by mass and not more than 35 parts by mass on the basis of 100 parts by mass of the raw material organic pigment.
Abstract:
The present invention relates to (1) a water dispersion for ink-jet printing including a polymer and a pigment mixture of C.I. Pigment Yellow 74 (A) and an azo compound (B) represented by the following formula (1) which is dispersed with the polymer, wherein a total pigment solid content of the components (A) and (B) in the water dispersion is from 15 to 35% by weight; and (2) a water-based ink for ink-jet printing including a polymer and a pigment mixture of C.I. Pigment Yellow 74 (A) and the azo compound (B) which is dispersed with the polymer, wherein a total pigment solid content of the components (A) and (B) in the water-based ink is from 3 to 20% by weight, wherein R 10 and R 20 are respectively an aryl group with the proviso that at least one of R 10 and R 20 has a sulfonic acid group and a sulfonic acid amide group. The water dispersion and the water-based ink according to the present invention are excellent in optical density and storage stability.
Abstract:
The present invention provides a process for producing a fine organic pigment having a very small primary particle size, and a fine organic pigment produced by the process; a process for producing a dispersion using the fine organic pigment, and a dispersion produced by the process; and a process for producing an ink using the dispersion. The present invention relates to [1] a process for producing a fine organic pigment, including step 1 of kneading a mixture prepared by blending a raw material organic pigment, a water-soluble inorganic salt, a water-soluble organic solvent and water with each other, the water being blended in an amount of not less than 0.6 part by mass and not more than 4.0 parts by mass on the basis of 100 parts by mass of the water-soluble inorganic salt; [2] a fine organic pigment produced by the process described in the above [1]; [3] a dispersion produced using the fine organic pigment described in the above [2]; [4] a process for producing a paste of a fine organic pigment, including step 2 of cleaning the kneaded mixture obtained in the step 1; [5] a process for producing a dispersion, including step 3 of subjecting the paste of the fine organic pigment produced by the process described in the above [4], an organic solvent and water to dispersing treatment; and [6] a process for producing an ink, including step 4 of mixing the dispersion produced by the process described in the above [5], with at least one material selected from the group consisting of water and an organic solvent.
Abstract:
The present invention provides the following process for producing a fine organic pigment which is capable of producing the fine organic pigment that has a very small primary particle size and is excellent in filtering property even in a cleaning step, and a fine organic pigment produced by the process; a process for producing a dispersion using the fine organic pigment, and a dispersion produced by the process; and a process for producing an ink using the dispersion. The present invention relates to [1] a process for producing a fine organic pigment, including steps 1 and 2: step 1: kneading a mixture prepared by compounding a raw material organic pigment, a water-soluble inorganic salt, a water-soluble organic solvent and a compound represented by the following formula (1) with each other, the compound being compounded in an amount of not less than 0.8 part by mass and not more than 18.0 parts by mass on the basis of 100 parts by mass of the raw material organic pigment: R 1 O(PO) m (EO) n A (1); and step 2: subjecting the mixture obtained in the step 1 to cleaning treatment with an aqueous solvent and then to filtration, [2] a fine organic pigment produced by the process according to the above aspect [1], [3] a dispersion produced using the fine organic pigment according to the above aspect [2], [4] a process for producing a paste of a fine organic pigment, including the above step 1 and 2, [5] a process for producing a dispersion, including step 3 of subjecting the paste of the fine organic pigment produced by the process according to the above aspect [4], an organic solvent and water to dispersing treatment, and [6] a process for producing an ink, including step 4 of mixing the dispersion produced by the process according to the above aspect [5] with at least one material selected from the group consisting of water and an organic solvent.
Abstract:
The first invention relates to a water-based ink for ink-jet printing which includes colorant-containing polymer particles (A) obtained by dispersing a colorant with a water-soluble polymer (x) and a water-insoluble polymer (y), a water-soluble organic solvent (B) and water, wherein a weight ratio of the water-insoluble polymer (y) to the water-soluble polymer (x) [(y)/(x)] is from 2.0 to 5.0, and a content of the water-soluble organic solvent (B) in the ink is from 10 to 70% by weight. The water-based ink for ink-jet printing according to the first invention is excellent in ejection property and optical density and exhibits a low viscosity. The second invention relates to a process for producing a water dispersion for ink-jet printing, which includes a step (I) of mixing a dispersion of a colorant with an emulsion of a water-insoluble polymer containing an organic solvent; a step (II) of subjecting the resulting mixture to dispersing treatment to obtain a dispersion of the colorant onto which the water-insoluble polymer is deposited; and a step (III) of removing the organic solvent from the resulting dispersion. The water dispersion produced by the process of the second invention is capable of exhibiting a high optical density suitable for high-speed printing.
Abstract:
Dispersante para composición hidráulica que comprende un polímero a base de ácido policarboxílico A quetiene un grupo ácido carboxílico y un grupo seleccionado de un grupo oxialquileno y/o un grupo oxiestireno;y un polímero B obtenido mediante copolimerización de un monómero 1 representado por la siguiente fórmula(1), **Fórmula** un monómero 3 representado por la siguiente fórmula (3) y un monómero 4 representado por lasiguiente fórmula (4):en la que R1 y R2 representan respectivamente un átomo de hidrógeno o un grupo metilo, R3 representa un átomo de hidrógeno o -(CH2)q(CO)pO(AO)rR4 en la que AO representa un grupo oxialquileno que tiene de 2a 4 átomos de carbono o un grupo oxiestireno, p indica un número de 0 ó 1, q indica un número de 0 a 2, rindica un número promedio de las unidades de AO totales e indica un número de 3 a 300 y R4 representaun grupo alquilo que tiene de 1 a 18 átomos de carbono;**Fórmula** en la que R11 representa un átomo de hidrógeno o un grupo metilo, R12 representa un grupo alquileno quetiene de 2 a 12 átomos de carbono, m1 indica un número de 1 a 30, M3 y M4 representan respectivamenteun átomo de hidrógeno, un metal alcalino o un metal alcalinotérreo;**Fórmula** en la que R13 y R15 representan respectivamente un átomo de hidrógeno o un grupo metilo, R14 y R16representan respectivamente un grupo alquileno que tiene de 2 a 12 átomos de carbono, m2 y m3 indicanrespectivamente un número de 1 a 30 y M5 representa un átomo de hidrógeno, un metal alcalino o un metalalcalinotérreo.
Abstract:
La presente invención se refiere a una dispersión de partículas de resina que contiene una partícula de resina de tipo núcleo-capa (A) y agua, en donde la resina de la porción de capa de la partícula de resina de tipo núcleo-capa (A) incluye una unidad estructural derivada de un éster de ácido (met)acrílico (a-1) que tiene un grupo hidrocarburo C4-C8, la resina de la porción de núcleo de la partícula de resina de tipo núcleo-capa (A) incluye al menos un 5 % en masa de una unidad estructural derivada de un monómero a base de (met)acrilamida (b-1) que tiene un parámetro de solubilidad de 17,0-21,0 (J/cm3)0,5, la temperatura de transición vítrea de la resina de núcleo es de 50 °C como máximo, y el valor ácido de la partícula de resina de tipo núcleo-capa (A) es de 50-100 mgKOH/g; un método para producir dicha dispersión de partículas de resina; y un método para imprimir utilizando dicha dispersión de partículas de resina. (Traducción automática con Google Translate, sin valor legal)