VINYLIC COPOLYMER, ITS COMPOSITION, AND COATING MATERIAL AND HARDENED PRODUCT BY USING SAME

    公开(公告)号:JPH11246632A

    公开(公告)日:1999-09-14

    申请号:JP5397598

    申请日:1998-03-05

    Applicant: KYOWA YUKA KK

    Abstract: PROBLEM TO BE SOLVED: To obtain the subject copolymer having a rapid hardening rate, manifesting high hardness, water resistance, chemical resistance or the like and useful for uses such as a coating material by allowing the copolymer to include a specified 5-membered cyclic dithiocarbonate group and a specific group. SOLUTION: The objective copolymer contains a 5-membered cyclic dithiocarbonate group of formula I (R to R are each H or a lower alkyl) and a group of formula II (R to R are each H, an alkyl, an aralkyl, a halogen, an alkoxy, an amino or the like). The copolymer is obtained, for example, by copolymerizing (A) 0.1-50 wt.% vinyl-based monomer having the group of formula I, (B) 0.1-30 wt.% vinyl-based monomer having the group of formula II and (C) a vinyl-based monomer copolymerizable with these monomers. The component A is preferably a monomer of formula III [R is H, methy] or ethyl; (n) is 1-6]. Preferably, γ-methacryloxypropyltrimethoxysilane or the like is used as the component B.

    ULTRAVIOLET-CURING CROSS-LINKER
    5.
    发明专利

    公开(公告)号:JPH10110084A

    公开(公告)日:1998-04-28

    申请号:JP26722196

    申请日:1996-10-08

    Applicant: KYOWA YUKA KK

    Abstract: PROBLEM TO BE SOLVED: To provide an ultraviolet-curing cross-linker which contains a compd. having two 5-member-cyclic dithiocarbonate groups and obtd. by reacting a corresponding oxirane compd. with carbon disulfide and which is useful for coating materials, adhesives, and ink. SOLUTION: This cross-linker contains a compd. having two 5-member-cyclic dithiocarbonate groups represented by the formula (wherein R1 and R2 are each a lower alkyl group provided they may combine with each other to form a satd. hydrocarbon ring). This compd. is obtd. by reacting a polyhydroxy compd., such as a polyhydric phenol (e.g. bisphenol A) or a low-mol.-wt. alcohol (e.g. glycerin), with epichlorohydrin and reacting the resultant oxirane compd., such as a polyvalent glycidyl ether or glycidyl methacrylate, with carbon disulfide in the presence of LiBr, etc. An acrylic monomer having a 5-member-cyclic dithiocarbonate group can form a copolymer with other copolymerizable monomers. This cross-linker is used jointly with a photosensitizer, a pigment, a thickener, etc., in accordance with the purpose.

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