公开(公告)号：WO2007049880A1

公开(公告)日：2007-05-03

申请号：PCT/KR2006/004278

申请日：2006-10-20

Applicant: KOREA BASIC SCIENCE INSTITUTE ,  KIM, Hae Jin ,  LEE, Jin Bae

Inventor： KIM, Hae Jin ,  LEE, Jin Bae

IPC: B82B3/00 ,  B82B1/00

CPC classification number: C01G45/02 ,  B82Y30/00 ,  C01P2002/72 ,  C01P2004/02 ,  C01P2004/04 ,  C01P2004/13 ,  C01P2004/16 ,  C01P2004/60 ,  C01P2006/40 ,  C01P2006/60 ,  C04B35/053 ,  C04B35/111 ,  C04B38/00 ,  C04B2111/00008 ,  C30B7/00 ,  C30B29/16 ,  C30B29/602 ,  H01M4/0404 ,  H01M4/043 ,  H01M4/505 ,  H01M4/621 ,  H01M4/625 ,  H01M10/052 ,  Y02E60/122 ,  Y02P70/54 ,  C04B38/0054

Abstract: The present invention relates to methods for manufacturing manganese oxide nanotubes/nanorods using an anodic aluminum oxide (AAO) template. In the inventive methods, the manganese oxide nanotubes/nanorods are manufactured in mild conditions using only a manganese oxide precursor and an anodic aluminum oxide template without using any solvent. The nanotubes/nanorods having uniform size can be easily obtained by adsorbing the manganese oxide precursor onto the surface of the anodic aluminum oxide template by a vacuum forming process using a vacuum filtration apparatus so as to maintain the shape of nanotubes/nanorods and drying the manganese oxide nanotubes. The manganese oxide nanotubes/nanorods made according to the inventive methods can be used as economic hydrogen reservoirs, the electrode of lithium secondary batteries, or the energy reservoirs of vehicles or other transport means.

Abstract translation: 本发明涉及使用阳极氧化铝（AAO）模板制造氧化锰纳米管/纳米棒的方法。 在本发明的方法中，仅使用锰氧化物前体和阳极氧化铝模板，而不使用任何溶剂，在温和条件下制造氧化锰纳米管/纳米棒。 通过使用真空过滤装置的真空成型方法将锰氧化物前体吸附到阳极氧化铝模板的表面上，以保持纳米管/纳米棒的形状并干燥锰，可以容易地获得具有均匀尺寸的纳米管/纳米棒 氧化物纳米管。 根据本发明方法制备的氧化锰纳米管/纳米棒可以用作经济氢气储存器，锂二次电池的电极，或车辆的能量储存器或其他运输工具。

公开(公告)号：WO2008056891A1

公开(公告)日：2008-05-15

申请号：PCT/KR2007/004971

申请日：2007-10-11

Applicant: KOREA BASIC SCIENCE INSTITUTE ,  KIM, Hae Jin ,  LEE, Jin Bae ,  LEE, Soon Chang

Inventor： KIM, Hae Jin ,  LEE, Jin Bae ,  LEE, Soon Chang

IPC: B82B3/00

CPC classification number: H01M4/485 ,  C01B3/001 ,  C01B33/12 ,  C01B33/18 ,  C04B35/14 ,  C04B35/62227 ,  C04B35/6224 ,  H01M8/04216 ,  Y02E60/324 ,  Y02P70/56

Abstract: Disclosed herein are a method of preparing Li-doped silica nanotubes using an anodic aluminum oxide (AAO) template, and a method of storing energy using the prepared Li-doped silica nanotubes. Unlike prior methods for preparing metal nanotubes, according to the disclosed preparation method, the Li-doped silica nanotubes having a uniform size can be easily obtained in mild conditions using a lithium precursor, a silica sol and an anodic aluminum oxide template. The preparation method comprises adsorbing the lithium precursor and the silica sol on the surface of the AAO template, drying the lithium precursor and the silica sol, adsorbed onto the AAO template, in a vacuum, to form nanotubes, and then drying the nanotubes. The Li-doped silica nanotubes prepared according to the disclosed method can be used as economical hydrogen storage materials, electrode materials for lithium secondary batteries, or energy storage sources for automobiles or other transportation means.

Abstract translation: 本文公开了使用阳极氧化铝（AAO）模板制备掺杂锂的二氧化硅纳米管的方法，以及使用制备的Li掺杂的二氧化硅纳米管来储存能量的方法。 与现有的制备金属纳米管的方法不同，根据所公开的制备方法，可以使用锂前体，二氧化硅溶胶和阳极氧化铝模板在温和条件下容易地获得具有均匀尺寸的Li掺杂二氧化硅纳米管。 该制备方法包括将锂前体和二氧化硅溶胶吸附在AAO模板的表面上，在真空中干燥吸附在AAO模板上的锂前体和二氧化硅溶胶，形成纳米管，然后干燥纳米管。 根据所公开的方法制备的掺杂Li的二氧化硅纳米管可以用作经济的储氢材料，锂二次电池的电极材料，或用于汽车或其他运输工具的储能源。

公开(公告)号：EP1951613A1

公开(公告)日：2008-08-06

申请号：EP06799352.7

申请日：2006-10-20

Applicant: Korea Basic Science Institute

Inventor： KIM, Hae Jin ,  LEE, Jin Bae

IPC: B82B3/00 ,  B82B1/00

CPC classification number: C01G45/02 ,  B82Y30/00 ,  C01P2002/72 ,  C01P2004/02 ,  C01P2004/04 ,  C01P2004/13 ,  C01P2004/16 ,  C01P2004/60 ,  C01P2006/40 ,  C01P2006/60 ,  C04B35/053 ,  C04B35/111 ,  C04B38/00 ,  C04B2111/00008 ,  C30B7/00 ,  C30B29/16 ,  C30B29/602 ,  H01M4/0404 ,  H01M4/043 ,  H01M4/505 ,  H01M4/621 ,  H01M4/625 ,  H01M10/052 ,  Y02E60/122 ,  Y02P70/54 ,  C04B38/0054

Abstract: The present invention relates to methods for manufacturing manganese oxide nanotubes/nanorods using an anodic aluminum oxide (AAO) template. In the inventive methods, the manganese oxide nanotubes/nanorods are manufactured in mild conditions using only a manganese oxide precursor and an anodic aluminum oxide template without using any solvent. The nanotubes/nanorods having uniform size can be easily obtained by adsorbing the manganese oxide precursor onto the surface of the anodic aluminum oxide template by a vacuum forming process using a vacuum filtration apparatus so as to maintain the shape of nanotubes/nanorods and drying the manganese oxide nanotubes. The manganese oxide nanotubes/nanorods made according to the inventive methods can be used as economic hydrogen reservoirs, the electrode of lithium secondary batteries, or the energy reservoirs of vehicles or other transport means.

公开(公告)号：EP2328215A2

公开(公告)日：2011-06-01

申请号：EP09816343.9

申请日：2009-07-27

Applicant: Korea Basic Science Institute

Inventor： KIM, Yang Soo ,  JEONG, Euh Duck ,  KIM, Hae Jin ,  KIM, Young Min ,  BAE, Jong Seong ,  HONG, Kyong Soo ,  KIM, Hee Jin ,  BAE, Kyeong Seo

IPC: H01M4/48

CPC classification number: H01M4/485

Abstract: This invention relates to a negative active material for a lithium secondary battery, a method of preparing the same and a lithium secondary battery including the same. This negative active material exhibits high capacity and superior cycle-life characteristics and is thus usefully employed in a lithium secondary battery which shows high capacity during high-rate charge · discharge.

Abstract translation: 本发明涉及的负极活性物质的锂二次电池，制备方法及包括其的锂二次电池的方法。 该负极活性物质显示出高的容量和优异的循环寿命特性，并因此有效地在锂二次电池，其示出了在高速率充放电·高容量使用。