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    N-hydroxyalkyl acrylamides
    1.
    发明授权
    N-hydroxyalkyl acrylamides 失效
    N-羟烷基丙烯酰胺

    公开(公告)号：US3898279A

    公开(公告)日：1975-08-05

    申请号：US29953972

    申请日：1972-10-20

    Applicant: LUBRIZOL CORP

    Inventor： HOKE DONALD IRVIN

    IPC: B01D71/40 ,  C08F20/58 ,  C08G18/62 ,  C07C103/30

    CPC classification number: C08G18/6266 ,  B01D71/40 ,  C08F20/58

    Abstract: N-3-Hydroxyalkyl acrylamides, and substituted derivatives thereof, are prepared by (1) reduction of an N-3-oxohydrocarbonsubstituted acrylamide, (2) addition of an alcohol to the N-3oxohydrocarbon-substituted acrylamide, followed by hydrogenation of the carbonyl group and elimination of the alcohol, or (3) hydrolysis of a 2-vinyl-5,6-dihydro-1,3-oxazine. The acrylamides are useful as monomers for conversion to polymers (which may also be prepared by reduction of the corresponding oxohydrocarbonsubstituted acrylamide polymers) with a number of interesting properties, including utility as membranes for desalination of water by hyperfiltration. The polymers may be crosslinked by the action of such reagents as diisocyanates, dicarboxylic acid halides, and aldehydes in acidic solution.

    Abstract translation: N-3-羟烷基丙烯酰胺及其取代的衍生物通过以下方法制备：（1）还原N-3-氧代烃取代的丙烯酰胺，（2）向N-3-氧代烃取代的丙烯酰胺中加入醇， 羰基的氢化和醇的消除，或（3）2-乙烯基-5,6-二氢-1,3-恶嗪的水解。 丙烯酰胺可用作用于转化为聚合物的单体（其也可通过还原相应的氧代烃取代的丙烯酰胺聚合物制备），其具有许多有趣的性质，包括用作通过超滤脱盐水的膜。 聚合物可以通过这样的试剂如二异氰酸酯，二羧酸卤化物和醛在酸性溶液中的作用而交联。

    Dyeable polypropylene compositions containing polymers of N-aminoalkyl acrylamides
    2.
    发明授权
    Dyeable polypropylene compositions containing polymers of N-aminoalkyl acrylamides 失效
    含有N-氨基烷基丙烯酰胺聚合物的可染色聚丙烯组合物

    公开(公告)号：US3873646A

    公开(公告)日：1975-03-25

    申请号：US29256572

    申请日：1972-09-27

    Applicant: LUBRIZOL CORP

    Inventor： HOKE DONALD IRVIN

    IPC: C02F1/54 ,  C07D295/13 ,  C08L23/02 ,  D21H17/45 ,  G03F7/027 ,  C08F29/12

    CPC classification number: C07D295/13 ,  C02F1/54 ,  C08K5/20 ,  C08L23/02 ,  C08L23/06 ,  C08L23/10 ,  D21H17/455 ,  G03F7/027 ,  C08L33/24 ,  C08L2666/04 ,  C08L77/00

    Abstract: N-3-Aminoalkyl propionamides with an ether substituent on the beta carbon atom are prepared by the reaction of analogous N-3oxohydrocarbon-substituted amides with an amine in the presence of a reducing agent, preferably hydrogen and a hydrogenation catalyst. The resulting compounds can be converted to acrylamides by pyrolysis in the presence of a strong base. The latter compounds may also be prepared by the reaction of a Beta , gamma -unsaturated amine with an acrylonitrile in the presence of sulfuric acid. They are useful for improving dyeability of fiberforming polymers and may be polymerized to form compositions which are useful in paper manufacture and (in their quaternized form) are excellent flocculants.

    Abstract translation: 通过在还原剂，优选氢和氢化催化剂的存在下，类似的N-3-氧代烃取代的酰胺与胺反应制备在β碳原子上具有醚取代基的N-3-氨基烷基丙酰胺。 所得化合物可以在强碱存在下通过热解转化为丙烯酰胺。 后一种化合物也可以通过β硫，γ-不饱和胺与丙烯腈在硫酸存在下的反应来制备。 它们可用于改善纤维形成聚合物的可染性，并且可以聚合以形成可用于纸制造的组合物（其季铵化形式）是优​​异的絮凝剂。

    N-3-Aminoalkyl amides
    3.
    发明授权
    N-3-Aminoalkyl amides 失效
    N-3-氨基烷基酰胺

    公开(公告)号：US3917594A

    公开(公告)日：1975-11-04

    申请号：US39469773

    申请日：1973-09-06

    Applicant: LUBRIZOL CORP

    Inventor： HOKE DONALD IRVIN

    IPC: C02F1/54 ,  C07D295/13 ,  C08F20/60 ,  D21H17/45 ,  C07D295/14

    CPC classification number: C07D295/13 ,  C02F1/54 ,  C08F20/60 ,  D21H17/455

    Abstract: N-3-Aminoalkyl propionamides with an ether substituent on the beta carbon atom are prepared by the reaction of analogous N-3oxohydrocarbon-substituted amides with an amine in the presence of a reducing agent, preferably hydrogen and a hydrogenation catalyst. The resulting compounds can be converted to acrylamides by pyrolysis in the presence of a strong base. The latter compounds may also be prepared by the reaction of an Alpha , Beta -unsaturated amine with an acrylonitrile in the presence of sulfuric acid. They are useful for improving dyeability of fiberforming polymers and may be polymerized to form compositions which improve paper strength and (in their quaternized form) are excellent flocculants.

    Abstract translation: 通过在还原剂，优选氢和氢化催化剂的存在下，类似的N-3-氧代烃取代的酰胺与胺反应制备在β碳原子上具有醚取代基的N-3-氨基烷基丙酰胺。 所得化合物可以在强碱存在下通过热解转化为丙烯酰胺。 后一种化合物也可以通过在硫酸存在下α，β-不饱和胺与丙烯腈的反应来制备。 它们可用于改善纤维形成聚合物的可染性，并且可以聚合形成提高纸张强度并且（其季铵化形式）是优​​异的絮凝剂的组合物。

    Halogen-substituted derivatives of n-3-oxohydrocarbonsubstituted acrylamides
    5.
    发明授权
    Halogen-substituted derivatives of n-3-oxohydrocarbonsubstituted acrylamides 失效
    N-3-氧代硫代丙烯酰胺的卤素取代衍生物

    公开(公告)号：US3686306A

    公开(公告)日：1972-08-22

    申请号：US3686306D

    申请日：1970-12-10

    Applicant: LUBRIZOL CORP

    Inventor： HOKE DONALD IRVIN

    IPC: C07C233/00 ,  C07C233/16 ,  C07C103/30

    CPC classification number: C07C233/00 ,  C07C233/16

    Abstract: Halogenation of N-3-oxohydrocarbon-substituted acrylamides, such as diacetone acrylamide, produces the corresponding substituted 2,3-dihalopropionamides. These can in turn be dehydrohalogenated to give the corresponding substituted 2-haloacrylamides. The latter compounds may also be prepared by the reaction of two moles of an aldehyde or ketone, or one mole of a Beta -hydroxy aldehyde or ketone or an Alpha , Beta -unsubstituted aldehyde or ketone, with 2-chloroacrylonitrile in the presence of sulfuric acid. The substituted 2-chloroacrylamides are useful as monomers for the preparation of fire-resistant polymers.

    Abstract translation: N-3-氧代烃取代的丙烯酰胺如双丙酮丙烯酰胺的卤化产生相应的取代的2,3-二卤丙酰胺。 这些可以依次进行脱卤化氢，得到相应的取代的2-卤代丙烯酰胺。 后一种化合物也可以通过在硫酸存在下将两摩尔醛或酮或1摩尔β-羟基醛或酮或α，β-取代的醛或酮与2-氯丙烯腈反应来制备 酸。 取代的2-氯丙烯酰胺可用作制备耐火聚合物的单体。

    Polymers of substd (meth)acrylamides - for use as flocculants
    6.
    发明专利
    Polymers of substd (meth)acrylamides - for use as flocculants 未知

    公开(公告)号：DE2233337A1

    公开(公告)日：1974-01-10

    申请号：DE2233337

    申请日：1972-03-23

    Applicant: LUBRIZOL CORP

    Inventor： HOKE DONALD IRVIN ,  SURBEY DONALD LEE

    IPC: C02F1/54 ,  C08F20/60 ,  C08F3/90

    Abstract: (Co)polymers are derived from substd. (meth)acrylamides of formula (I): (where R', R2 and R3 are H or hydrocarbon, and R4 and R5 are hydrocarbons, R6 is -C(R7)=CH2 where R7 is H or lower alkyl, and R8 (sic) is hydrocarbon, Y is -NZ'Z2 or - circled positive NZ'Z2Z3X circled negative X is a salt-forming anion, Z' is H or hydrocarbon, and Z2 is H or (cyclo)alkyl, or -NZ'Z2 may be a heterocycle, and Z3 is H or lower alkyl), e.g. N-(1,1-dimethyl-3-dimethylaminopropyl)acrylamide.

    WATER-SOLUBLE SULFONATE POLYMERS AS FLOCCULANTS
    9.
    发明专利
    WATER-SOLUBLE SULFONATE POLYMERS AS FLOCCULANTS 未知

    公开(公告)号：AU3650071A

    公开(公告)日：1973-06-14

    申请号：AU3650071

    申请日：1971-12-06

    Applicant: LUBRIZOL CORP

    Inventor： HOKE DONALD IRVIN

    IPC: C02F1/54 ,  C08F28/00 ,  B01D21/01 ,  C02B1/20 ,  B01D51/02

    Abstract: 1380807 Flocculating LUBRIZOL CORP 8 Feb 1972 [12 Feb 1971] 5862/72 Heading C1C Solids in aqueous suspension (e.g. kaolin suspensions or sewage) are flocculated by adding thereto a water-soluble polymer or copolymer containing units of the formula wherein R = H, lower (up to 7 C atoms) alkyl or substituted lower alkyl, R 3 = H or lower alkyl ; R 4 = lower alkyl; M = H or one equivalent of a cation (e.g. Na, K, NH 4 ). An inorganic flocculant, e.g. Fe 2 (SO 4 ) 3 , Al 2 (SO 4 ) 3 or Ca(OH) 2 may be added. The copolymer may comprise acrylic acid, methacrylic acid, methacrylamide, N- methylacrylamide, or N-(1,1-dimethyl-3-dimethylaminobutyl) acrylamide. The copolymer may be quaternized. The substituted radical may include halide, hydroxy, alkoxy, keto, carboxy, carbalkoxy, amide, amino, nitro, cyano, hydrocarbylthio, sulphoxy, sulphone and sulphonic acid and amide groups.

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