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公开(公告)号:JPH11228984A
公开(公告)日:1999-08-24
申请号:JP31144598
申请日:1998-10-30
Applicant: LUBRIZOL CORP
Inventor: DICK DIANE L , MALONE G RAYMOND , VINCI JAMES N
IPC: C09K5/04 , C10M169/04 , C10M171/00 , C10N30/02 , C10N30/06 , C10N40/30
Abstract: PROBLEM TO BE SOLVED: To obtain excellent compatibility with lubricants and cooling agents by comprising a fluorine-containing hydrocarbon having a specific number of carbon atoms, an ester of a carboxylic acid with a polyhydric hydroxy com pound and an alkoxylated alcohol or phenol or an alkoxylated glycol at a specific ratio. SOLUTION: A composition comprises 10-90 wt.% fluorinecontaining 1-2C hydrocarbon; 5-90 wt.% ester of a carboxylic acid represented by the formula: R[OC(O)R ]n (wherein R is hydrocarbyl; R is H, 1-7C hydrocarbyl or the like; and n is 2-10) with a polyhydric hydroxy compound; and 0.1-5 wt.% alkoxylated alcohol or phenol represented by formula I (wherein R is 1-20C aliphatic, 6-24C aromatic or the like; R is H, methyl or ethyl; y is 1-3; and x is 2-50) or alkoxylated glycol represented by formula II (wherein R is 2-8C hydroxyalkyl; and R, y and x are the same as defined above).
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公开(公告)号:CA2251388A1
公开(公告)日:1999-04-30
申请号:CA2251388
申请日:1998-10-23
Applicant: LUBRIZOL CORP
Inventor: DICK DIANE L , MALONE G RAYMOND , VINCI JAMES N
IPC: C09K5/04 , C10M169/04 , C10M171/00 , C10N30/02 , C10N30/06 , C10N40/30
Abstract: A liquid refrigeration composition is disclosed which comprises (A) at least one-fluorine containing hydrocarbon containing 1 or 2 carbon atoms, further wherein fluorine is the only halogen in said fluorine-containing hydrocarbon; and an effective amount of at least one miscible organic lubricant comprising (B) at least one ester of a carboxylic acid and a polyhydroxy compound characterized by the general formula R¢OC(O)R1!n (I) wherein R is a hydrocarbyl group; each R1 is independently (a) hydrogen, (b) a straight chain hydrocarbyl group having from 1 to about 7 carbon atoms, (c) branched chain hydrocarbyl group having from 4 to about 20 carbon atoms, or (d) a straight chain hydrocarbyl group having from 8 to about 14 carbon atoms, provide d that when at least one R1 is (d), at least one other R1 is either (a) or (b); n is at least 2; and (C) a performance additive comprising (1) an alkoxylated alcohol or phenol of the formula or (2) an alkoxylated glycol of the formula wherein R2 is an aliphatic group containing from 1 to 20 carbon atoms or an aromatic or aliphatic substituted aromatic group containing from 6 to 24 carbon atoms, R3 is hydrogen, methyl or ethyl, R13 is a hydroxy alkyl group wherein the alkyl group contains from 2 to 8 carbon atoms, y is an integer of from 1 to 3 an d x is an integer of from 2 to 50.
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