公开(公告)号：TWI448326B

公开(公告)日：2014-08-11

申请号：TW095112759

申请日：2006-04-07

Applicant: 三井化學股份有限公司 ,  MITSUI CHEMICALS, INC.

Inventor： 中山康 ,  NAKAYAMA YASUSHI ,  松川直人 ,  MATSUKAWA NAOTO ,  齋藤純治 ,  SAITO JUNJI ,  村田進 ,  MURATA SUSUMU ,  三谷誠 ,  MITANI MAKOTO ,  藤田照典 ,  FUJITA TERUNORI

IPC: B01J13/02

CPC classification number: B01J13/14 ,  B01J13/02 ,  Y10T428/2982 ,  Y10T428/2985 ,  Y10T428/2987 ,  Y10T428/2989

公开(公告)号：DE602006018112D1

公开(公告)日：2010-12-23

申请号：DE602006018112

申请日：2006-01-31

Applicant: MITSUI CHEMICALS INC

Inventor： SATOH YASUO ,  BANDO HIDEKI ,  SONOBE YOSHIHO ,  SUZUKI MASAO ,  TANIFUJI DAISUKE ,  TOMATA CHIAKI ,  MITANI MAKOTO

IPC: C08F10/02 ,  C08F4/6592

公开(公告)号：CA2596314C

公开(公告)日：2010-09-21

申请号：CA2596314

申请日：2006-01-31

Applicant: MITSUI CHEMICALS INC

Inventor： SATOH YASUO ,  BANDO HIDEKI ,  SONOBE YOSHIHO ,  SUZUKI MASAO ,  TANIFUJI DAISUKE ,  TOMATA CHIAKI ,  MITANI MAKOTO

IPC: C08F10/02 ,  C08F4/6592

Abstract: Ethylene-based resin, which exhibits a satisfactorily high melt tension and can provide a molded object excellent in mechanical strength, the ethylene-based resin characterized in simultaneously satisfying the requirements [1] to [5] described below: [1] melt flow rate (MFR) under a loading of 2.16 kg at 190°C is in the range of 0.1 to 100 g/10 minutes; [2] density (d) is in the range of 875 to 970 kg/m3; [3] ratio [MT/.eta.* (g/P) ] of melt tension [MT (g) ] at 190°C to shearing viscosity [.eta.* (P) ] at 200°C at an angular velocity of 1.0 rad/sec. is in the range of 1.50x10 -4 to 9.00x10 -4; [4] sum [(A+B)(/1000C)] of the number of methyl branches [A(/1000C)] and the number of ethyl branches [B(/1000C)] per 1000 carbon atoms measured by 13C-NMR is 1.8 or less; and [5] zero shear viscosity [.eta.0(P)] at 200°C and weight-average molecular weight(Mw)measured by GPC-viscosity detector method (GPC-VISCO) satisfy the following relational expression (Eq-1): 0.01 x 10 -13 x Mw3.4

公开(公告)号：CA2235905C

公开(公告)日：2003-10-21

申请号：CA2235905

申请日：1998-04-24

Applicant: MITSUI CHEMICALS INC

Inventor： TOHI YASUSHI ,  FUJITA TERUNORI ,  SUGI KIYOAKI ,  NITABARU MASATOSHI ,  MATSUI SHIGEKAZU ,  TSUTSUI TOSHIYUKI ,  SAITO JUNJI ,  MITANI MAKOTO ,  MAKIO HARUYUKI

IPC: C08F210/04 ,  C07F7/00 ,  C07F7/08 ,  C07F9/00 ,  C08F4/602 ,  C08F110/02 ,  C08F110/06 ,  C08F210/02 ,  C08F210/12 ,  C08F210/16 ,  C07F7/28 ,  C08F4/655 ,  C08F4/68 ,  C08F4/70

Abstract: The invention provides olefin polymerization catalyst exhibiting excellent polymerization activities, a process for olefin polymerization using the catalyst, a novel transition metal. compound useful for the catalyst, and an .alpha.-olefin/conjugated diene copolymer having specific properties. The olefin polymerization catalyst of the invention comprises (A) a transition metal compound of formula (I) or (II), and (B) an organometallic compound, an oranoaluminum oxy-compound or an ionizing ionic compound. The novel transition metal compound of the invention is a compound of formula (I) wherein M is a transition meal atom of Group 3 or 4 of the periodic table; m is an integer of 1 to 3; R1 is a hydrocarbon group, etc.; R2 to R5 are each H, a halogen, a hydrocarbon group, etc.; R6 is a halogen, a hydrocarbon group, etc.; n is a number satisfying a valence of M; and X is a halogen, a hydrocarbon group, etc. (see fig. I) (see fig. II)

公开(公告)号：SG173234A1

公开(公告)日：2011-08-29

申请号：SG2010006435

申请日：2006-01-31

Applicant: MITSUI CHEMICALS INC

Inventor： SATOH YASUO ,  BANDO HIDEKI ,  SONOBE YOSHIHO ,  SUZUKI MASAO ,  TANIFUJI DAISUKE ,  TOMATA CHIAKI ,  MITANI MAKOTO

Abstract: Ethylene-based resin, which exhibits a satisfactorilyhigh melt tension and can provide a molded object excellentin mechanical strength, the ethylene-based resin characterizedin simultaneously satisfying the requirements [1] to [5]described below:[1] melt flow rate (MFR) under a loading of 2.16 kg at 190°Cis in the range of 0.1 to 100 g/10 minutes;[2] density (d) is in the range of 875 to 970 kg/m3;[3] ratio [MT/r[`(g/P)] of melt tension [MT (g)] at 190°C toshearing viscosity [r; (P) ] at 200°C at an angular velocity of1.0 rad/sec. is in the range of 1.50x10-9 to 9.00x10-4;[4] sum [(A+B)(/100CC)] of the number of methyl branches[A(/1000C)] and the number of ethyl branches [B(/1000C)] per1000 carbon atoms measured by 13C-NMR is 1.8 or less; and[5] zero shear viscosity [no(P)] at 200°C and weight-averagemolecular weight (Mw) measuredby GPC-viscosity detector method(GPC-VISCO) satisfy the following relational expression(Eq-1):0.01xl0-13xMw1_9

公开(公告)号：AT478099T

公开(公告)日：2010-09-15

申请号：AT05806611

申请日：2005-11-18

Applicant: MITSUI CHEMICALS INC

Inventor： NAKAYAMA YASUSHI ,  MATSUKAWA NAOTO ,  SAITO JUNJI ,  BANDO HIDEKI ,  SONOBE YOSHIHO ,  MICHIUE KENJI ,  MITANI MAKOTO ,  FUJITA TERUNORI

IPC: C08F4/655 ,  C08F4/64

Abstract: The present invention provides ethylene-based copolymer microparticles and functional group-containing ethylene-based copolymer microparticles that have particle diameter smaller than that of conventional polyethylene fine-particles, no inter-particle agglomeration, very narrow particle size distribution, and high sphericity, in which requirements (A) to (E) below are satisfied. The invention also provides non-agglomerated spherical magnesium containing microparticles used as magnesium-containing carrier component for olefin-polymerization catalysts that can manufacture the above microparticles. (Requirements) (A) The intrinsic viscosity [·] measured in decalin at 135°C is in the range of 0.1 to 50 dl/g, (B) at least 95 wt% or more of particles pass through a mesh screen with an opening of 37 µm, (C) the median diameter (d 50 ) measured by laser diffraction scattering is 3 µm ‰ d 50 ‰ 25 µm, (D) the circularity coefficient is 0.85 or more, and (E) the variation coefficient of particle diameter (Cv) is 20% or less.

公开(公告)号：DE60036739D1

公开(公告)日：2007-11-22

申请号：DE60036739

申请日：2000-06-16

Applicant: MITSUI CHEMICALS INC

Inventor： TAKAHASHI MAMORU ,  KASAI TETSUJI ,  SAITO JUNJI ,  MATSUKAWA NAOTO ,  TSURU KAZUTAKA ,  MITANI MAKOTO ,  FUJITA TERUNORI ,  OTSUZUKI SHIRO ,  MATSUMOTO TETSUHIRO ,  TSUTSUI TOSHIYUKI

IPC: C08F10/02 ,  C08F4/64 ,  C08F255/00 ,  C08J5/00 ,  C08L23/04

公开(公告)号：DE60022326D1

公开(公告)日：2005-10-06

申请号：DE60022326

申请日：2000-06-16

Applicant: MITSUI CHEMICALS INC

Inventor： TAKAHASHI MAMORU ,  KASAI TETSUJI ,  SAITO JUNJI ,  MATSUKAWA NAOTO ,  TSURU KAZUTAKA ,  MITANI MAKOTO ,  FUJITA TERUNORI ,  OTSUZUKI SHIRO ,  MATSUMOTO TETSUHIRO ,  TSUTSUI TOSHIYUKI

IPC: C08J5/00 ,  C08F4/64 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F255/02 ,  C08L23/04 ,  C08L23/08 ,  C08L51/06 ,  C08L101/00 ,  C08F55/00

Abstract: An ethylene (co)polymer of the present invention is a (co)polymer with excellent moldability and mechanical properties and either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 4 to 20 carbon atoms. The (co)polymer has methyl branches measured by 13 C-NMR less than 0.1 in number per 1,000 carbon atoms and Mw/Mn measured by GPC not lower than 1.8 and lower than 4.5. The (co)polymer is either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 3 to 20 carbon atoms. The melt tension (MT) and the swell ratio (SR) satisfy the relation; log(MT) > 12.9 - 7.15 × SR; and the intrinsic viscosity ([η]) and the melt flow rate (MFR) satisfy the relation; [η] > 1.85 × MFR -0.192 in the case of MFR 1.85 × MFR -0.213 in the case of MFR ≥ 1. Such an ethylene (co)polymer can be usable for various molding applications and especially suitable for pipes.

公开(公告)号：BR0107037A

公开(公告)日：2003-06-10

申请号：BR0107037

申请日：2001-07-26

Applicant: MITSUI CHEMICALS INC

Inventor： KASHIWA NORIO ,  KOJOH SHINICHI ,  MATSUO SHINGO ,  SAITO JUNJI ,  FUJITA TERUNORI ,  MITANI MAKOTO ,  TAKAHASHI MAMORU ,  SATO YASUO

IPC: C08F4/02 ,  C08F4/60 ,  C08F4/658 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F255/00 ,  C08F255/02 ,  C08F290/00 ,  C08F290/04 ,  C08F290/06

Abstract: The present invention relates to a polymer having a melt tension (MT (g)) substantially the same as or lower than that of a conventional polymer which is substantially the same as the polymer in the recurring unit of the main skeleton, the molecular weight, the molecular weight distribution and the crystallinity, and having a flow activation energy (Ea (KJ/mol)) larger than a value obtained by adding 5 KJ/mol to the Ea value of the conventional polymer. A preferred example 'of the polymer is a branched polyolefin comprising 50 to 100 % by mol of recurring units derived from ethylene and 0 to 50 % by mol of recurring units derived from an alpha -olefin of 3 to 20 carbon atoms and having the following properties: the flow activation energy (Ea (KJ/mol)) and the alpha -olefin content (C (% by weight)) satisfy a specific relation, and the melt tension (MT (g)) and the melt flow rate (MFR (g/10 min)) satisfy a specific relation. This branched polyolefin is excellent in moldability and mechanical strength.

公开(公告)号：CA2235905A1

公开(公告)日：1998-10-25

申请号：CA2235905

申请日：1998-04-24

Applicant: MITSUI CHEMICALS INC

Inventor： MITANI MAKOTO ,  TOHI YASUSHI ,  FUJITA TERUNORI ,  TSUTSUI TOSHIYUKI ,  MATSUI SHIGEKAZU ,  SAITO JUNJI ,  MAKIO HARUYUKI ,  SUGI KIYOAKI ,  NITABARU MASATOSHI

IPC: C08F210/04 ,  C07F7/00 ,  C07F7/08 ,  C07F9/00 ,  C08F4/602 ,  C08F110/02 ,  C08F110/06 ,  C08F210/02 ,  C08F210/12 ,  C08F210/16 ,  C07F7/28 ,  C08F4/655 ,  C08F4/68 ,  C08F4/70

Abstract: The invention provides olefin polymerization catalyst exhibiting excellent polymerization activities, a process for olefin polymerization using the catalyst, a novel transition metal. compound useful for the catalyst, and an .alpha.-olefin/conjugated diene copolymer having specific properties. The olefin polymerization catalyst of the invention comprises (A) a transition metal compound of formula (I) or (II), and (B) an organometallic compound, an oranoaluminum oxy-compound or an ionizing ionic compound. The novel transition metal compound of the invention is a compound of formula (I) wherein M is a transition meal atom of Group 3 or 4 of the periodic table; m is an integer of 1 to 3; R1 is a hydrocarbon group, etc.; R2 to R5 are each H, a halogen, a hydrocarbon group, etc.; R6 is a halogen, a hydrocarbon group, etc.; n is a number satisfying a valence of M; and X is a halogen, a hydrocarbon group, etc. (see fig. I) (see fig. II)