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公开(公告)号:CA1073587A
公开(公告)日:1980-03-11
申请号:CA263483
申请日:1976-10-15
Applicant: MITSUI PETROCHEMICAL IND
Inventor: TOMOSHIGE TORU , NAGANO RIICHIRO , IMAMURA TETSUO
IPC: C08L23/00 , C08F8/00 , C08F8/46 , C08F255/00 , C08F255/02 , C08F255/04 , C08K5/09 , C08L7/00 , C08L21/00 , C08L51/00 , C08L51/02 , C08L101/00
Abstract: A process for preparing thermoplastic olefin elastomers which comprises mixing and extruding in a screw extruder (A) an olefin rubber having a number average molecular weight of about 10,000 to 100,000 and composed of a copolymer of ethylene with an .alpha.-olefin containing at least 3 carbon atoms and (B) about 1 to 15 parts by weight, per 100 parts by weight of the olefin rubber (A)? of a specified dicarboxylic acid monomer at about 200 to 320.degree.C in the presence of (C) 0.02 to 3 miliequivalents, per 100 grams of the olefin rubber (A), of an alkyl peroxide, and in the absence of molecular oxygen. The thermoplastic olefin elastomers have superior mechanical properties, thermal stability, processability and adhesiveness, and find a wide range of applications, for example, as extrusion or injection molding materials, adhesives, coating agents, and modifiers for plastics and rubbers.
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公开(公告)号:DE2646480A1
公开(公告)日:1977-04-28
申请号:DE2646480
申请日:1976-10-14
Applicant: MITSUI PETROCHEMICAL IND
Inventor: TOMOSHIGE TORU , NAGANO RIICHIRO , IMAMURA TETSUO
IPC: C08L23/00 , C08F8/00 , C08F8/46 , C08F255/00 , C08F255/02 , C08F255/04 , C08K5/09 , C08L7/00 , C08L21/00 , C08L51/00 , C08L51/02 , C08L101/00 , C08L23/26
Abstract: A process for preparing thermoplastic olefin elastomers which comprises mixing and extruding in a screw extruder (A) an olefin rubber having a number average molecular weight of about 10,000 to 100,000 and composed of a copolymer of ethylene with an alpha -olefin containing at least 3 carbon atoms and (B) about 1 to 15 parts by weight, per 100 parts by weight of the olefin rubber (A), of a specified dicarboxylic acid monomer at about 200 to 320 DEG C in the presence of (C) 0.02 to 3 milliequivalents, per 100 grams of the olefin rubber (A), of an alkyl peroxide, and in the absence of molecular oxygen. The thermoplastic olefin elastomers have superior mechanical properties, thermal stability, processability and adhesiveness, and find a wide range of applications, for example, as extrusion or injection molding materials, adhesives, coating agents, and modifiers for plastics and rubbers.
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公开(公告)号:EP0208789A4
公开(公告)日:1987-06-15
申请号:EP86900837
申请日:1986-01-16
Applicant: MITSUI PETROCHEMICAL IND
Inventor: NAGANO RIICHIRO
CPC classification number: C08F8/20 , Y10T428/31507 , Y10T428/31797 , Y10T428/31913 , Y10T428/3192 , C08F210/00
Abstract: A chlorinated olefin polymer containing 15 to 35 wt % of chlorine is obtained by chlorinating an olefinic polymer containing propylene units and C4-6 alpha-olefin units in a specified proportion and having a crystallinity of 10 to 50 % and a limiting viscosity of 0.80 to 6.0 dl/g. This chlorinated olefin polymer is used as an adhesive upon laminating a chlorine-containing polymer such as polyvinylidene chloride or an aromatic polymer such as polystyrene on polyolefin, showing excellent adhesiveness in a high-temperature atmosphere.
Abstract translation: 通过将含有丙烯单元和C4-6α-烯烃单元的烯烃聚合物以特定比例氯化并获得结晶度为10-50%,极限粘度为0.80-0.90克的氯化烯烃聚合物,得到含有15-35wt%氯的氯化烯烃聚合物 6.0 dl / g。 该氯化烯烃聚合物在将聚偏二氯乙烯等含氯聚合物或聚苯乙烯等芳香族聚合物层压在聚烯烃上时作为粘合剂使用,在高温气氛下显示优异的粘合性。
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公开(公告)号:EP0022871A4
公开(公告)日:1981-03-24
申请号:EP79901541
申请日:1980-05-20
Applicant: MITSUI PETROCHEMICAL IND
Inventor: NAGANO RIICHIRO , KANESHIGE RYOSUKA
IPC: C08F255/00 , C08F257/02 , C08F279/02 , C10M143/02 , C10M145/02 , C10M1/28 , C08F289/00 , C08L51/00 , C08L51/06 , C10M3/22
CPC classification number: C08F279/02 , C08F255/00 , C08F257/02 , C10M143/02 , C10M145/02 , C10M2209/04 , C10M2209/06 , C10M2209/062 , C10M2209/08 , C10M2209/082 , C10M2209/084 , C10N2270/02
Abstract: A lubricating oil composition composed of an oil-soluble graft copolymer, prepared by grafting a small amount of graft monomer selected from the group consisting of unsaturated monocarboxylic acid saturated esters, saturated carboxylic acid unsaturated esters, and unsaturated epoxy compounds to a copolymer having substantially no carbon-to-carbon double bonds expressed in terms of iodine value, having substantially no oxygen-containing functional groups, and having a number-average molecular weight of about 5,000 - about 100,000, selected from the group consisting of hydrogenation products of copolymers of (Alpha)-olefins containing 2 -20 carbon atoms, copolymers between styrene and (Alpha)-olefin containing 2 -20 carbon atoms, and copolymers between styrene and diolefin; and a process for producing same.
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公开(公告)号:DE3367405D1
公开(公告)日:1986-12-11
申请号:DE3367405
申请日:1983-12-23
Applicant: MITSUI PETROCHEMICAL IND
Inventor: NAGANO RIICHIRO , KIGA HIROSHI , IWATA TADAO
IPC: C08L23/00 , C08F255/00 , C08F255/08 , C08K7/00 , C08K7/14 , C08L7/00 , C08L21/00 , C08L23/18 , C08L23/20 , C08L51/00 , C08L51/02 , C08L101/00
Abstract: A glass-reinforced polymer composition of the invention contains 80 to 99.99 parts by weight, of a 4-methyl-1-pentene polymer, 0.01 to 20 parts by weight of a graft-modified polymer of 4-methyl-1-pentene having graft units of an unsaturated carboxylic acid or an acid anhydride thereof in an amount of 0.5 to 15% by weight and having a limiting viscosity of 0.3 to 10 dl/g, and 1 to 300 parts by weight of glass fibers based on 100 parts by weight of the sum of the 4-methyl-1-pentene polymer and the graft-modified polymer. The composition has overall standards of mechanical strength, heat resistance and water resistance.
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公开(公告)号:CA1195447A
公开(公告)日:1985-10-15
申请号:CA444016
申请日:1983-12-22
Applicant: MITSUI PETROCHEMICAL IND
Inventor: NAGANO RIICHIRO , KIGA HIROSHI , IWATA TADAO
IPC: C08L23/00 , C08F255/00 , C08F255/08 , C08K7/00 , C08K7/14 , C08L7/00 , C08L21/00 , C08L23/18 , C08L23/20 , C08L51/00 , C08L51/02 , C08L101/00
Abstract: A glass-reinforced polymer composition of the invention contains 80 to 99.99 parts by weight, of a 4-methyl-1-pentene polymer, 0.01 to 20 parts by weight of a graft-modified polymer of 4-methyl-1-pentene having graft units of an unsaturated carboxylic acid or an acid anhydride thereof in an amount of 0.5 to 15% by weight and having a limiting viscosity of 0.3 to 10 d?/g, and 1 to 300 parts by weight of glass fibers based on 100 parts by weight of the sum of the 4-methyl-1-pentene polymer and the graft-modified polymer. The composition has overall standards of mechanical strength, heat resistance and water resistance.
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公开(公告)号:DE2966681D1
公开(公告)日:1984-03-22
申请号:DE2966681
申请日:1979-11-13
Applicant: MITSUI PETROCHEMICAL IND
Inventor: NAGANO RIICHIRO , KANESHIGE RYOSUKA
IPC: C08F255/00 , C08F257/02 , C08F279/02 , C10M143/02 , C10M145/02 , C10M1/28 , C10M3/22 , C08F289/00 , C08L51/00 , C08L51/06
Abstract: PCT No. PCT/JP79/00289 Sec. 371 Date Jul. 14, 1980 Sec. 102(e) Date Jul. 14, 1980 PCT Filed Nov. 13, 1979 PCT Pub. No. WO80/00976 PCT Pub. Date May 15, 1980.A lubricating oil composition comprising a major proportion of a lubricating oil, and an oil-soluble graft copolymer, said graft copolymer being prepared by grafting a small amount of a grafting monomer selected from saturated esters of unsaturated monocarboxylic acids, unsaturated esters of saturated carboxylic acids and unsaturated epoxy compounds to a trunk copolymer which is substantially free from an oxygen-containing functional group and a carbon-carbon double bond determined from its iodine value and has a number average molecular weight of about 5,000 to about 100,000, said trunk copolymer being selected from copolymers of alpha-olefins having 2 to 20 carbon atoms, copolymers of styrene and alpha-olefins having 2 to 20 carbon atoms and hydrogenated products of copolymers of styrene and diolefins. A process for preparation of said composition is also provided.
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公开(公告)号:DE3382712T2
公开(公告)日:1994-05-05
申请号:DE3382712
申请日:1983-03-29
Applicant: MITSUI PETROCHEMICAL IND
Inventor: NAGANO RIICHIRO , SAGANE TOSHIHIRO
IPC: C08F255/00 , C08F255/02 , C08F255/04 , C08L7/00 , C08L21/00 , C08L23/00 , C08L25/00 , C08L25/04 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L51/04 , C08L51/06 , C08L101/00 , C08F255/06
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公开(公告)号:DE3371914D1
公开(公告)日:1987-07-09
申请号:DE3371914
申请日:1983-07-15
Applicant: MITSUI PETROCHEMICAL IND
Inventor: NAGANO RIICHIRO , SAGANE TOSHIHIRO
IPC: C08F255/00 , C09J151/06 , C09J3/14 , C08L51/06
Abstract: This invention relates to a hot-melt adhesive composition comprising a styrene-type hydrocarbon-modified polyolefin composed of 100 parts by weight of a crystalline polyolefin having a degree of crystallinity of at least 10% and 0.15 to 50 parts by weight of a styrene-type hydrocarbon bound thereto by graft-copolymerization, said modified polyolefin having an intrinsic viscosity [ eta ] of 0.5 to 5 dl/g, a degree of crystallinity of at least 10% and a weight average molecular weight Mw/number average molecular weight Mn ratio of from 1 to 15. This invention also relates to the use of the hot-melt composition and to a laminated article comprising the holt-melt composition.
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公开(公告)号:DE2966647D1
公开(公告)日:1984-03-15
申请号:DE2966647
申请日:1979-11-13
Applicant: MITSUI PETROCHEMICAL IND
Inventor: TAKEDA MASAMI , NAGANO RIICHIRO
IPC: C08L51/00 , C08F255/02 , C08F255/06 , C08L23/00 , C08L51/02 , C08L51/06 , C08L57/00 , C08L57/02 , C08L101/00 , C09J123/26 , C09J151/00 , C09J151/06 , C09J159/00 , C09J3/14
Abstract: The composition comprises a tackifier and a polymer having a melt index at 230 DEG C not exceeding 500, the polymer being formed by reacting an unsaturated carboxylic acid, or derivative thereof, with an ethylene - alpha olefin copolymer rubber, and, optionally, partially esterifying the resulting polymer. The polymer forms 30 to 70% of the composition, based on the weight of the polymer plus tackifier. … The compositions, which are useful as hot melt adhesives, are also pressure-sensitive.
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