公开(公告)号：CA2060282C

公开(公告)日：1997-11-25

申请号：CA2060282

申请日：1992-01-29

Applicant: MITSUI TOATSU CHEMICALS

Inventor： MITA RYUICHI ,  MAEDA SUNAO ,  SHIMOTORI HITOSHI ,  YANASE YUJI ,  ISHII TSUTOMU ,  YOSHIKAWA YUKIHIRO ,  KAWASHIMA HIDEO ,  ISHIKAWA KATSUTOSHI ,  TANIKAWA HIROHARU

IPC: A01N43/54 ,  C07D215/18 ,  C07D239/40 ,  C07D401/12

Abstract: Disclosed are pyrimidinyloxy(or thioxy)quinoline derivatives represented by the formula (I) (I) (wherein X is oxygen or sulfur, Y is hydrogen or halogen, Z is hydrogen or methyl, R1 and R2 are methoxy or methyl and n is an integer of 1 or 2} which exhibit an excellent controlling effect for plant diseases and are also safe for crop plants, preparation processes of the derivatives, and agri-horticultural fungicides comprising the derivatives as an active ingredient.

公开(公告)号：DE3009726A1

公开(公告)日：1980-09-25

申请号：DE3009726

申请日：1980-03-13

Applicant: MITSUI TOATSU CHEMICALS

Inventor： EMA KENJI ,  HARA JUNJI ,  IKADO SHUHEI ,  KAWASHIMA HIDEO ,  YOKOO TOMOHIDE

IPC: C08L61/06 ,  C08L61/10 ,  C08L63/08 ,  C08L61/34 ,  C08L21/00 ,  C08L9/00 ,  C08L11/00 ,  C08L75/04 ,  C08L33/00

Abstract: Phenolic resin compositions comprising a polymeric substance having a phenolic OH group such as phenol resins, and a rubber having an epoxy group and an epoxy equivalent of 500 to 30,000 such as butadiene copolymers, acrylic copolymers, chloroprene copolymers and urethane copolymers are provided. These resin compositions exhibit improved properties having overcome the drawback of brittle properties intrinsic of conventional phenolic resins, and also exhibit cold resistance; hence they are used as molding materials, laminating materials, casting materials, binders, etc. Further, molding resin compositions having improved solvent-resistance and metal insert properties are provided.

公开(公告)号：CA2213111C

公开(公告)日：2001-03-20

申请号：CA2213111

申请日：1997-08-14

Applicant: MITSUI TOATSU CHEMICALS

Inventor： KISHI JUNRO ,  KAWASHIMA HIDEO ,  YANASE YUJI ,  TAKAHASHI OSAMU ,  YOSHIKAWA YUKIHIRO ,  KATSUTA HIROYUKI ,  TOMURA NAOFUMI ,  INAMI SHUNICHI ,  TOMIYA KANJI

IPC: C07D231/14 ,  A01N43/26 ,  A01N43/56 ,  A01N43/78 ,  C07C211/45 ,  C07D213/82 ,  C07D231/16 ,  C07D241/14 ,  C07D263/34 ,  C07D277/20 ,  C07D277/30 ,  C07D277/56 ,  C07D307/68 ,  C07D309/28 ,  C07D327/06 ,  C07D333/24 ,  C07C211/52

Abstract: A substituted carboxanilide derivative provided by the invention and represented by the formula (1): (see formula I) wherein A is is a hydrogen atom or methyl. B is a methyl or ethyl, and Het is 1-methyl-3-substituted-4-pyrazolyl or 2-methyl-4-substituted-5- thiazolyl group, exhibits a disease control effect against Botrytis cinerea. Powdery mildew, Pyricularia oryzae of rice plant and other various plant diseases, is excellent in residual effect, has also activity against resistant strain for conventional chemicals. particularly exerts control effect against Botrytis cinerea at a lower dosage as compared with a prior art, is also safe for crops, and thus is useful as a plant disease control agent.

公开(公告)号：CA2213111A1

公开(公告)日：1998-02-15

申请号：CA2213111

申请日：1997-08-14

Applicant: MITSUI TOATSU CHEMICALS

Inventor： TOMIYA KANJI ,  INAMI SHUNICHI ,  KAWASHIMA HIDEO ,  KISHI JUNRO ,  TOMURA NAOFUMI ,  YOSHIKAWA YUKIHIRO ,  TAKAHASHI OSAMU ,  KATSUTA HIROYUKI ,  YANASE YUJI

IPC: C07D231/14 ,  A01N43/26 ,  A01N43/56 ,  A01N43/78 ,  C07C211/45 ,  C07D213/82 ,  C07D231/16 ,  C07D241/14 ,  C07D263/34 ,  C07D277/20 ,  C07D277/30 ,  C07D277/56 ,  C07D307/68 ,  C07D309/28 ,  C07D327/06 ,  C07D333/24 ,  C07C211/52

Abstract: A substituted carboxanilide derivative provided by the invention and represented by the formula (1): (see formula I) wherein A is is a hydrogen atom or methyl. B is a methyl or ethyl, and Het is 1-methyl-3-substituted-4-pyrazolyl or 2-methyl-4-substituted-5-thiazolyl group, exhibits a disease control effect against Botrytis cinerea. Powdery mildew, Pyricularia oryzae of rice plant and other various plant diseases, is excellent in residual effect, has also activity against resistant strain for conventional chemicals. particularly exerts control effect against Botrytis cinerea at a lower dosage as compared with a prior art, is also safe for crops, and thus is useful as a plant disease control agent.

公开(公告)号：CA2173788A1

公开(公告)日：1996-10-12

申请号：CA2173788

申请日：1996-04-10

Applicant: MITSUI TOATSU CHEMICALS

Inventor： YOSHIKAWA YUKIHIRO ,  TOMIYA KANJI ,  KATSUTA HIROYUKI ,  KAWASHIMA HIDEO ,  TAKAHASHI OSAMU ,  INAMI SHUNICHI ,  YANASE YUJI ,  KISHI JUNRO ,  SHIMOTORI HITOSHI ,  TOMURA NAOFUMI

IPC: A01N43/10 ,  A01N43/40 ,  A01N43/56 ,  A01N43/78 ,  C07D333/36 ,  C07D333/42 ,  C07D333/44 ,  C07D401/12 ,  C07D403/12 ,  C07D409/12 ,  C07D417/12 ,  C07D333/26 ,  A01N43/48

Abstract: The substituted thiophene derivative of the invention which is represented by the general formula (1) has a broad disease spectrum for a pathogenic fungus of various crops, exhibits an excellent controlling effect on disease such as gray mold, powdery mildew and rust in particular, and is also effective for a resistant fungus of conventional fungicides which has become a serious problem, and consequently is useful for an agricultural and horticultural fungicide.

公开(公告)号：DE2702500A1

公开(公告)日：1977-07-28

申请号：DE2702500

申请日：1977-01-21

Applicant: MITSUI TOATSU CHEMICALS

Inventor： KANEMARU MUNEAKI ,  KIMURA TETSUO ,  ISHII NORIMICHI ,  KAWASHIMA HIDEO

IPC: B01J27/00 ,  C07B61/00 ,  C07C27/00 ,  C07C29/08 ,  C07C31/02 ,  C07C67/00

Abstract: A process for preparing alcohols which comprises hydrating lower olefins in liquid phase with an aqueous 0.1 to 20.0 wt % phosphoric acid solution containing 0.001 to 1.0 wt % of an oxyacid of chromium or a salt thereof to give corresponding alcohols.

公开(公告)号：CA2060282A1

公开(公告)日：1992-08-01

申请号：CA2060282

申请日：1992-01-29

Applicant: MITSUI TOATSU CHEMICALS

Inventor： ISHIKAWA KATSUTOSHI ,  YOSHIKAWA YUKIHIRO ,  ISHII TSUTOMU ,  TANIKAWA HIROHARU ,  MAEDA SUNAO ,  KAWASHIMA HIDEO ,  YANASE YUJI ,  SHIMOTORI HITOSHI ,  MITA RYUICHI

IPC: A01N43/54 ,  C07D215/18 ,  C07D239/40 ,  C07D401/12

公开(公告)号：JPH09301974A

公开(公告)日：1997-11-25

申请号：JP12138796

申请日：1996-05-16

Applicant: MITSUI TOATSU CHEMICALS

Inventor： YOSHIKAWA YUKIHIRO ,  TOMITANI KANJI ,  KATSUTA HIROYUKI ,  KAWASHIMA HIDEO ,  TAKAHASHI KAN ,  INAMI SHUNICHI ,  YANASE YUJI ,  KISHI JUNRO ,  SHIMOTORI HITOSHI ,  TOMURA NAOFUMI

IPC: C07D409/12 ,  A01N43/56

Abstract: PROBLEM TO BE SOLVED: To obtain a new substituted thiophene derivative exhibiting excellent controle effect on disease injury of gray rust, powdery mildew, rust, etc., of various kinds of crops, exhibiting effects also on medicine-resistant fungi and useful as a germicide for agriculture and horticulture. SOLUTION: This compound is represented by formula I [Q is H, a halogen, (trifluoro)methyl, methylthio, etc.; R is a 1-12C (branched) (halogeno)alkyl, a 2-10C (branched)(halogeno)alkyl, a 2-10C alkylthioalkyl, etc.; Ar is a group of formula II (R is CF3 , CHF2 , CH3 , ethyl, Cl, Br or I); R and a group of the formula NHCOAr are mutually adjacent], e.g. N- 2-[3-(4-tolyl)]thienyl}-3- trifluoromethyl-1-methylpyrazole-4-carboxylic amide. The compound of formula I is obtained by reacting a compound of formula III with a compound of the formula ArCO-X (X is Cl, Br or I) in a melted state or in a solvent.

公开(公告)号：JPH0656823A

公开(公告)日：1994-03-01

申请号：JP20653992

申请日：1992-08-03

Applicant: MITSUI TOATSU CHEMICALS

Inventor： YOSHIKAWA YUKIHIRO ,  ISHII TSUTOMU ,  TANIGAWA HIROHARU ,  MAEDA SUNAO ,  KAWASHIMA HIDEO ,  ISHIKAWA KATSUTOSHI ,  YANASE YUJI ,  SHIMOTORI HITOSHI ,  TOMURA NAOFUMI

IPC: A01N43/54 ,  C07D401/12

Abstract: PURPOSE:To provide a new quinoline derivative having more excellent control effects than conventional compounds and also exhibiting excellent safety to crops. CONSTITUTION:A pyrimidinyloxy(thio)quinoline derivative of formula I [X is O or S; Y is a halogen; Z is H or methyl; R and R are each 1-3C alkyl or H; (n) is 0-2], e.g. 7-chloro-4-(4,6-dimethylthio-2-pyrimidinyloxy)quinoline. This compound is obtained by mixing 4-chloroquinolines of formula II with pyrimidines of formula III and reacting these components in a melted state or in an inactive solvent, preferably in the presence of a base or reacting a metal salt of 4-hydroxy(or mercapto)quinolines with 2-chloropyrimidines or reacting 4-hydroxy(or mercapto)quinolines with 2-chloropyrimidines of formula V in the presence of a base.

公开(公告)号：JPH0656822A

公开(公告)日：1994-03-01

申请号：JP20653892

申请日：1992-08-03

Applicant: MITSUI TOATSU CHEMICALS

Inventor： YOSHIKAWA YUKIHIRO ,  ISHII TSUTOMU ,  TANIGAWA HIROHARU ,  MAEDA SUNAO ,  KAWASHIMA HIDEO ,  ISHIKAWA KATSUTOSHI ,  YANASE YUJI ,  SHIMOTORI HITOSHI ,  TOMURA NAOFUMI

IPC: A01N43/54 ,  C07D401/12

Abstract: PURPOSE:To obtain a new pyrimidinylthioquinoline derivative having a more excellent germicidal effects than conventional compounds and also exhibiting excellent safety to crops. CONSTITUTION:A compound of formula I [Y is a halogen; Z is H or methyl; R and R are each a 1-3C alkyl; (n) is 0-2], e.g. 7-chloro-4-(4-methoxy-6-methyl-2- pyrimidinylthio)quinoline. This compound is obtained by mixing 4- chloroquinolines of formula II with pyrimidines of formula III and reacting these components in a melted state or in an inactive solvent, preferably in the presence of a base, preferably in the presence of a base or reacting a metal salt of 4-mercaptoquinolines of formula IV with 2-chloropyrimidines of formula V or reacting 4-mercaptoquinolines of formula IV with 2-chloropyrimidines of formula II in the presence of a base.